Citation: XU Jin-Fang, SHI Wei, NI Zhe-Ming, SUN Zhi-Yin, QIAN Ping-Ping. Surface Characterization for Anionic-Nonionic Surfactant Modified Layered Double Hydroxides[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 977-983. doi: 10.11862/CJIC.2014.144 shu

Surface Characterization for Anionic-Nonionic Surfactant Modified Layered Double Hydroxides

1.
College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China

Received Date: 15 November 2013
Available Online: 8 January 2014
Fund Project: 国家自然科学基金资助项目(No.)。 (No.)

The surface modification of magnesium-aluminum hydrotalcites was made by sodium dodecyl benzene sulfonate (SDBS), Tween-80 and anionic-nonionic surfactant. Inverse gas chromatography (IGC) was used to investigate the surface properties of the MgAl-LDHs, SDBS-LDHs, Tween-LDHs and SDBS/Tween-LDHs. The surface free energy (ΔG⁰) and the dispersive component of the surface energy (γ_s^d) were estimated. The results show that the ΔG⁰ and γ_s^d of the modified LDHs are lower than that of MgAl-LDHs, ΔG⁰ and γ_s^d of the SDBS/Tween-LDHs are the lowest. This indicates that the chemical stability of SDBS/Tween-LDHs is better than that of other modified LDHs. In addition, the value of γ_s^d decreases with the increasing of temperature, so the compatibility with polymer can be improved by increasing the temperature in the preparation of polymer/hydrotalcite materials.
- hydrotalcite;surfactant;inverse gas chromatography;coumpounding modification
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沈阳化工大学材料科学与工程学院沈阳 110142