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Citation: XU Jin-Fang, SHI Wei, NI Zhe-Ming, SUN Zhi-Yin, QIAN Ping-Ping. Surface Characterization for Anionic-Nonionic Surfactant Modified Layered Double Hydroxides[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 977-983. doi: 10.11862/CJIC.2014.144 shu

Surface Characterization for Anionic-Nonionic Surfactant Modified Layered Double Hydroxides

  • 1.

    College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China

  • Received Date: 15 November 2013
    Available Online: 8 January 2014

    Fund Project: 国家自然科学基金资助项目(No.)。 (No.)

  • The surface modification of magnesium-aluminum hydrotalcites was made by sodium dodecyl benzene sulfonate (SDBS), Tween-80 and anionic-nonionic surfactant. Inverse gas chromatography (IGC) was used to investigate the surface properties of the MgAl-LDHs, SDBS-LDHs, Tween-LDHs and SDBS/Tween-LDHs. The surface free energy (ΔG0) and the dispersive component of the surface energy (γsd) were estimated. The results show that the ΔG0 and γsd of the modified LDHs are lower than that of MgAl-LDHs, ΔG0 and γsd of the SDBS/Tween-LDHs are the lowest. This indicates that the chemical stability of SDBS/Tween-LDHs is better than that of other modified LDHs. In addition, the value of γsd decreases with the increasing of temperature, so the compatibility with polymer can be improved by increasing the temperature in the preparation of polymer/hydrotalcite materials.
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