Citation: YAN Qin, XIAO Shou-Jun. In-situ Growth of DNA Nanotubes from Functionalized Patterns of Poly(PEGMA) Brushes on Silicon Surface[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 741-748. doi: 10.11862/CJIC.2014.134 shu

In-situ Growth of DNA Nanotubes from Functionalized Patterns of Poly(PEGMA) Brushes on Silicon Surface

YAN Qin ,
XIAO Shou-Jun ^,

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: XIAO Shou-Jun,
Received Date: 23 July 2013
Available Online: 18 November 2013
Fund Project: 国家自然科学基金(No.91027019)资助项目。 (No.91027019)

Interfacing "top-down" with "bottom-up" methods to fabricate micro-and nano-devices are one target in nano-science and nano-technology presently. Herein we demonstrate the combination of photolithography and self-assembly to grow DNA nanotubes on functionalized patterns of poly(poly(ethylene glycol)monomethacrylate) brushes grafted from a silicon chip surface (Si-g-Poly(PEGMA)). On the silicon surface, first, the bromoisobutyryl group as the polymerization initiator was introduced through hydrosilylation, then poly(PEGMA) brushes were grown in-situ by Surface Initiated Atom Transfer Radical Polymerization (SI-ATRP), NHS(succinimidyl)-ester was generated on photolithographied poly(PEGMA) patterns and finally six-helix DNA tubes were immobilized and grown in-situ on these patterns. Multiple transmission-reflection infrared spectroscopy (MTR-IR), gel electrophoresis, transmission electron microscopy (TEM), and scanning electron microscopy (SEM) were used to monitor the whole process, which confirmed the feasibility of DNA self-assembly on the functionalized patterns of a silicon chip.
- DNA nanotube;self-assembly;photolithography;polymer brushes
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