Citation: ZHANG Mei-Li, REN Yi-Xia, CHEN Xiao-Li, YAN Hong-Tao. Synthesis and Crystal Structure of Zn(Ⅱ)、Cd(Ⅱ) Two Complexes Constructed from 3,5-Diaminobenzoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 895-900. doi: 10.11862/CJIC.2014.132 shu

Synthesis and Crystal Structure of Zn(Ⅱ)、Cd(Ⅱ) Two Complexes Constructed from 3,5-Diaminobenzoic Acid Ligand

1.
1 College of Chemistry and Materials Science, NorthWest University, Xian 716000, China;

Corresponding author: ZHANG Mei-Li,
Received Date: 2 May 2013
Available Online: 13 November 2013
Fund Project: 陕西省教育厅科研基金(No.11JK0567,11JK0565,12JK0636) (No.11JK0567,11JK0565,12JK0636)延安大学自然基金(No.YDZD2011-07)资助项目。 (No.YDZD2011-07)

The title complexes, [Cd(diaba)(phen)₂] NO₃·H₂O(1) and [Zn(diaba)(2,2'-bipy)₂](2) (diaba=3,5-diaminobenzoic acid; phen=1,10-phenanthroline, 2,2'-bipy=2,2'-bipyridine), has been synthesized by hydrothermal reactions and characterized by IR, TG, fluorescent spectrum and single-crystal X-ray diffraction techniques. The structure indicates that the complex 1 crystallizes in orthorhombic, space group Fddd with a=1.42581(7) nm, b=2.56462(13) nm, c=3.09247(17) nm. The structure indicates that the complex 2 crystallizes in monoclinic, space group C2/c with a=1.27362 nm, b=1.59278 nm, c=1.51935 nm, β=107.334°. The crystal structure of complex 1 consists of one Cd^Ⅱ, one 3,5-diaminobenzoic acid ligand and two phen ligands. The crystal structure of complex 2 consists of one Zn^Ⅱ, one 3,5-diaminobenzoic acid ligand and two 2,2'-bipy ligands. In two complexes, the adjacent mononuclear molecular recognize each other to generate a 3Dsupramolecular structure via the hydrogen bonding or the π-π stacking interaction. In additional, thermal stability and photoluminescence properties of two complexes have also been studied.
- complex;synthesis;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142