Citation: ZHANG Ting, CHEN Wen-Jian, ZHANG Yun-Qian, TAO Zhu, ZHU Qian-Jiang. Coordination and Supramolecular Assemblies Based on Interaction of Three Different Cucurbit[6]urils with Sr(Ⅱ) Ion[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 473-480. doi: 10.11862/CJIC.2014.122 shu

Coordination and Supramolecular Assemblies Based on Interaction of Three Different Cucurbit[6]urils with Sr(Ⅱ) Ion

1.
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

Received Date: 27 May 2013
Available Online: 7 November 2013
Fund Project: 国家自然科学基金项目(No.21272045) (No.21272045)教育部“春晖计划”(No.Z2008-1-55001) (No.Z2008-1-55001)贵州省科学技术基金(No.J2009-2024)资助项目。 (No.J2009-2024)

In the present work, three different cucurbit[6]urils (Q[6]s), the unsubstituted cucurbit[6]uril, 1,3,5-hexamethylcucurbit[6]uril, and symmetric tetramethyl cucurbit[6]uril were selected as the building blocks or the construction of Q[6]s-based coordination polymers. Four compounds based on the Q[6]s-Sr(Ⅱ) complexes were synthesized and characterized by single crystal X-ray diffraction. The crystal structures of the obtained compounds show a common feature of Q[6]s-Sr(Ⅱ) complex-based one dimensional supramolecular chain. In the presence of Cl^- anion as a counter ion, the supramolecular chains are typical coordination polymers, while in the presence of NO₃^- anion as a counter ion, the formation of chain is based on share of coordinated water molecules.CCDC: 653909, 1; 977776, 2; 977778 3; 977777, 4.
- cucurbit[6]uri;methyl-substituted cucurbit[6]uri(Q[6]s);strontium(Ⅱ) cation;supramolecular assemblies;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142