Citation: ZHANG Ting, CHEN Wen-Jian, ZHANG Yun-Qian, TAO Zhu, ZHU Qian-Jiang. Coordination and Supramolecular Assemblies Based on Interaction of Three Different Cucurbit[6]urils with Sr(Ⅱ) Ion[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 473-480. doi: 10.11862/CJIC.2014.122 shu

Coordination and Supramolecular Assemblies Based on Interaction of Three Different Cucurbit[6]urils with Sr(Ⅱ) Ion

1.
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

Received Date: 27 May 2013
Available Online: 7 November 2013
Fund Project: 国家自然科学基金项目(No.21272045) (No.21272045)教育部“春晖计划”(No.Z2008-1-55001) (No.Z2008-1-55001)贵州省科学技术基金(No.J2009-2024)资助项目。 (No.J2009-2024)

In the present work, three different cucurbit[6]urils (Q[6]s), the unsubstituted cucurbit[6]uril, 1,3,5-hexamethylcucurbit[6]uril, and symmetric tetramethyl cucurbit[6]uril were selected as the building blocks or the construction of Q[6]s-based coordination polymers. Four compounds based on the Q[6]s-Sr(Ⅱ) complexes were synthesized and characterized by single crystal X-ray diffraction. The crystal structures of the obtained compounds show a common feature of Q[6]s-Sr(Ⅱ) complex-based one dimensional supramolecular chain. In the presence of Cl^- anion as a counter ion, the supramolecular chains are typical coordination polymers, while in the presence of NO₃^- anion as a counter ion, the formation of chain is based on share of coordinated water molecules.CCDC: 653909, 1; 977776, 2; 977778 3; 977777, 4.
- cucurbit[6]uri;methyl-substituted cucurbit[6]uri(Q[6]s);strontium(Ⅱ) cation;supramolecular assemblies;crystal structure
1. [1]
  [1] Fedin V P, Gramlich V, Woerle M. Inorg. Chem., 2001,40 (5):1074-1077
2. [2]
  [2] Kim K. Chem. Soc. Rev., 2002,31(2):96-107
3. [3]
  [3] HAN Bao-Hang(韩宝航), LIU Yu(刘育)． Chin. J. Org. Chem. (有机化学学报), 2003,23:139-149
4. [4]
  [4] Lee J W, Smal S, Selvapalam N, et al． Acc. Chem. Res., 2003,36:621-630
5. [5]
  [5] ZHANG Gui-Ling(张桂玲), XU Zhou-Qing(徐周庆), XU Sai-Feng(薛赛凤),et al． Chin. J. Inorg. Chem. (无机化学学报), 2003,19(6):655-659
6. [6]
  [6] Zhao J Z, Kim H J, Oh J, et al. Angew. Chem. Int. Ed., 2001,22(40):4233-4235
7. [7]
  [7] Isobe H, Sato S, Nakamura E. J. Org. Lett., 2002,4(8):1287-1289
8. [8]
  [8] Lagona J, Fettinger J C, Isaacs L. J. Org. Lett., 2003,5:3745-3747
9. [9]
  [9] Jon S Y, Selvapalam N, Oh D H, et al. J. Am. Chem. Soc., 2003,125(34):10186-10187
10. [10]
  [10] ZHAO Yun-Jie(赵云洁), SHEN Yong-Qiang(申永强), XUE Sai-Feng(薛赛凤), et al. Sci. China Ser. B (中国科学B辑), 2004,49(11):1111-1116
11. [11]
  [11] Ni X L, Lin J X, Zheng Y Y, et al. Cryst. Growth Des., 2008,8(9):3446-3450
12. [12]
  [12] Chen W J, Yu D H, Zhang Y Q, et al. Inorg. Chem., 2011,50,6956-6964
13. [13]
  [13] Liang L L, Ni X L, Zhao Y, et al. Inorg. Chem., 2013, 52,1909-1915
14. [14]
  [14] Day A I, Arnold A P. WO 0068232. 2000-11-16.
15. [15]
  [15] Day A I, Arnold A P, Blanch R. J. Molecules, 2003,8:74-82
16. [16]
  [16] Sheldrick G M. SHELXL-97, University of Göttingen, Germany, 1997.
17. [17]
  [17] Spek A L. PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, 2008.
18. [18]
  [18] Li Z F, Wu F, Zhou F G, et al. Cryst. Growth Des., 2010,10: 5113-5116
19. [19]
  [19] Li Z F, Liang L L, Wu F, et al. CrystEngComm, 2013,15: 1994-2001
20. [20]
  [20] Gerasko O A, Virovets A V, Samsonenko D G, et al. Russ. Chem. Bull., 2003,52(3):1-9
21. [21]
  [21] Zhang Y Q, Zhen L M, Yu D H, et al. J. Mol. Struct., 2008,875:435-441
22. [22]
  [22] Liu J X, Dong C H, Long L S, et al. Dalton Trans., 2009, 7344-7352
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