Citation: HUANG Zi-Dong, ZHANG Hai-Yan, CHEN Yi-Ming, WANG Wen-Guang, HONG Tian-Xing, YE Yi-Peng, LEI Xing-Ling. Microwave-Assisted Synthesis and Characterization of Graphene/NiO Composites Material[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 609-614. doi: 10.11862/CJIC.2014.114 shu

Microwave-Assisted Synthesis and Characterization of Graphene/NiO Composites Material

1.
School of Materials and energy, Guangdong University of Technology, Guangzhou 510006, China

Received Date: 14 August 2013
Available Online: 5 December 2013
Fund Project: 国家自然科学基金(No.51276044) (No.51276044)“十二五”国家科技支撑计划项目(No.2012BAK26B04) (No.2012BAK26B04)广东省科技计划项目(No.2011B050300017, No.2012B070800015) (No.2011B050300017, No.2012B070800015)广东省高等学校科技创新重点项目(粤财教(2011)473号) (粤财教(2011)473号)广东省自然科学基金(No.S2012040006551)资助项目。 (No.S2012040006551)

Graphene/nickel oxide composites (RG/NiO) were prepared by microwave-assisted in-situ synthesis of nano-particles NiO on the defects of thermal expansion graphene (RG). The structure, morphology and the NiO content of the composites were characterized by X-ray diffraction (XRD), Raman spectra (Raman), Fourier transform infrared (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and thermogravimetry-differential thermal analysis (TGA-DSC). The results show that the number of high-defects graphene layers is about 7~8 and the interlay spacing is around 0.35 nm. After hydrothermal reaction and microwave irradiation, the oxidation resistance of graphene became poor obviously. The nanoparticles NiO with an average diameter of 25 nm evenly and densely coated on the graphene sheet. Simultaneously the weight percentage of NiO in the RG/NiO composites is estimated to be 19.8wt%.
- thermal expansion graphene;nanoparticles NiO;graphene/nickel oxide composites material
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沈阳化工大学材料科学与工程学院沈阳 110142