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Citation: WANG Hui-Sheng. Synthesis, Crystal Structure and Magnetic Properties of a Double-Cuboidal [Mn4] Cluster Containing Mixed Multidentate Chelating Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 522-528. doi: 10.11862/CJIC.2014.111 shu

Synthesis, Crystal Structure and Magnetic Properties of a Double-Cuboidal [Mn4] Cluster Containing Mixed Multidentate Chelating Ligands

  • 1.

    Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology, Wuhan 430074, China

  • Received Date: 28 August 2013
    Available Online: 18 November 2013

    Fund Project: 国家自然科学基金(No.21201136) (No.21201136)武汉工程大学科学研究基金(No.10122012)资助。 (No.10122012)

  • In this paper, a tetranuclear Mn cluster containing mixed multidentate chelating ligands, Na2[Mn2ⅢMn2Ⅱ(pdmH)2(L)2(N3)2]·2CH3OH·2H2O(1·2CH3OH·2H2O, pdmH2 is 2, 6-pyridinedimethanol and H2L is the production of dehydration condensation between pdmH2 and the gem-diol form of di-2-pyridylketone) has been reported. The obtained complex was fully characterized by X-ray single crystal structural diffraction, IR, elemental analysis and magnetic investigation. The structural analysis indicates that the complex crystallizes in the triclinic system, P1 space group, and in the complex, two Mn2+ ions, two Mn3+ ions and six O atoms from pdmH- or L2- ligands comprise a double-cuboidal core. Magnetic studies indicate that within the cluster, while the magnetic coupling interactions between Mn2+ and Mn3+ are weak antiferromagnetic with the values being J1=-0.89 cm-1 and J2=-1.13 cm-1, the magnetic interaction between Mn3+ ions is slightly strong ferromagnetic with the value being J3=3.20 cm-1. The value of the ground state S is 2, and from ac magnetic susceptibility investigation, the complex do not possess frequency-dependent that the single molecule magnets possess. CCDC: 957203.
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