Citation: WANG Hui-Sheng. Synthesis, Crystal Structure and Magnetic Properties of a Double-Cuboidal [Mn₄] Cluster Containing Mixed Multidentate Chelating Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 522-528. doi: 10.11862/CJIC.2014.111 shu

Synthesis, Crystal Structure and Magnetic Properties of a Double-Cuboidal [Mn₄] Cluster Containing Mixed Multidentate Chelating Ligands

WANG Hui-Sheng

1.
Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology, Wuhan 430074, China

Received Date: 28 August 2013
Available Online: 18 November 2013
Fund Project: 国家自然科学基金(No.21201136) (No.21201136)武汉工程大学科学研究基金(No.10122012)资助。 (No.10122012)

In this paper, a tetranuclear Mn cluster containing mixed multidentate chelating ligands, Na₂[Mn₂^ⅢMn₂^Ⅱ(pdmH)₂(L)₂(N₃)₂]·2CH₃OH·2H₂O(1·2CH₃OH·2H₂O, pdmH₂ is 2, 6-pyridinedimethanol and H₂L is the production of dehydration condensation between pdmH₂ and the gem-diol form of di-2-pyridylketone) has been reported. The obtained complex was fully characterized by X-ray single crystal structural diffraction, IR, elemental analysis and magnetic investigation. The structural analysis indicates that the complex crystallizes in the triclinic system, P1 space group, and in the complex, two Mn²⁺ ions, two Mn³⁺ ions and six O atoms from pdmH^- or L^2- ligands comprise a double-cuboidal core. Magnetic studies indicate that within the cluster, while the magnetic coupling interactions between Mn²⁺ and Mn³⁺ are weak antiferromagnetic with the values being J₁=-0.89 cm^-1 and J₂=-1.13 cm^-1, the magnetic interaction between Mn³⁺ ions is slightly strong ferromagnetic with the value being J₃=3.20 cm^-1. The value of the ground state S is 2, and from ac magnetic susceptibility investigation, the complex do not possess frequency-dependent that the single molecule magnets possess. CCDC: 957203.
- tetranuclear Mn cluster;crystal structure;magnetic property;mixed multidentate chelating ligands;single molecule magnets
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Synthesis, Crystal Structure and Magnetic Properties of a Double-Cuboidal [Mn₄] Cluster Containing Mixed Multidentate Chelating Ligands