Citation: WANG Hui-Sheng. Synthesis, Crystal Structure and Magnetic Properties of a Double-Cuboidal [Mn4] Cluster Containing Mixed Multidentate Chelating Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 522-528. doi: 10.11862/CJIC.2014.111
-
In this paper, a tetranuclear Mn cluster containing mixed multidentate chelating ligands, Na2[Mn2ⅢMn2Ⅱ(pdmH)2(L)2(N3)2]·2CH3OH·2H2O(1·2CH3OH·2H2O, pdmH2 is 2, 6-pyridinedimethanol and H2L is the production of dehydration condensation between pdmH2 and the gem-diol form of di-2-pyridylketone) has been reported. The obtained complex was fully characterized by X-ray single crystal structural diffraction, IR, elemental analysis and magnetic investigation. The structural analysis indicates that the complex crystallizes in the triclinic system, P1 space group, and in the complex, two Mn2+ ions, two Mn3+ ions and six O atoms from pdmH- or L2- ligands comprise a double-cuboidal core. Magnetic studies indicate that within the cluster, while the magnetic coupling interactions between Mn2+ and Mn3+ are weak antiferromagnetic with the values being J1=-0.89 cm-1 and J2=-1.13 cm-1, the magnetic interaction between Mn3+ ions is slightly strong ferromagnetic with the value being J3=3.20 cm-1. The value of the ground state S is 2, and from ac magnetic susceptibility investigation, the complex do not possess frequency-dependent that the single molecule magnets possess. CCDC: 957203.
-
-
[1]
[1] Aromí G, Brechin E K. Struct. Bond., 2006,122:1-67
-
[2]
[2] Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003,42: 268-297
-
[3]
[3] Ako A M, Hewitt I J, Mereacre V, et al. Angew. Chem. Int.Ed., 2006,45:4926-4929
-
[4]
[4] Konar S, Clearfield A. Inorg. Chem., 2008,47:3489-3491
-
[5]
[5] Wang W G, Zhou A J, Zhang W X, et al. J. Am. Chem. Soc., 2007,129:1014-1015
-
[6]
[6] Zhang L, Clrac R, Heijboer P, et al. Angew. Chem. Int. Ed.,2012,51:3007-3011
-
[7]
[7] Stamatatos T C, Abboud K A, Wernsdorfer W, et al. Angew.Chem. Int. Ed., 2006,45:4134-4137
-
[8]
[8] Stamatatos T C, Abboud K A, Wernsdorfer W, et al. Angew.Chem. Int. Ed., 2007,46:884-888
-
[9]
[9] Saudo E C, Wernsdorfer W, Abboud K A, et al. Inorg. Chem., 2004,43:4137-4144
-
[10]
[10] Lecren L, Li Y G, Wernsdorfer W, et al. Inorg. Chem. Commun., 2005,8:626-630
-
[11]
[11] Murugesu M, Habrych M, Wernsdorfer W, et al. J. Am. Chem. Soc., 2004,126:4766-4767
-
[12]
[12] Stamatatos T C, Abboud K A, Wernsdorfer W, et al. Angew. Chem. Int. Ed., 2008,47:6694-6698
-
[13]
[13] Stoumpos C C, Gass I A, Milios C J, et al. Dalton Trans., 2009:307-317
-
[14]
[14] Brechin E K. Chem. Commun., 2005:5141-5153
-
[15]
[15] Stamatatos T C, Foguet-Albiol D, Stoumpos C C, et al. Polyhedron, 2007,26:2165-2167
-
[16]
[16] Stamatatos T C, Foguet-Albiol D, Stoumpos C C, et al. J. Am. Chem. Soc., 2005,127:15380-15381
-
[17]
[17] Stoumpos C C, Stamatatos T C, Sartzi H, et al. Dalton Trans., 2009:1004-1015
-
[18]
[18] Wang H S, Zhang Z C, Song X J, et al. Dalton Trans., 2011,40:2703-2706
-
[19]
[19] Wang H S, Song X J, Zhou H B, et al. Polyhedron, 2011,30: 3206-3210
-
[20]
[20] Wang H S, Song Y. Inorg. Chem. Commun., 2013,35:86-88
-
[21]
[21] Canty A J, Minchin N J, Patrick J M, et al. Dalton Trans.,1983:1253-1259
-
[22]
[22] SAINT-Plus, version 6.02; Bruker Analytical X-ray System: Madison, WI, 1999.
-
[23]
[23] Sheldrick G M. SADABS: An Empirical Absorption Correction Program; Bruker Analytica X-ray Systems: Madison, WI, 1996.
-
[24]
[24] Sheldrick G M. SHELXTL-97; Universität of Göttingen: Göttingen, Germany, 1997.
-
[25]
[25] Liu W, Thorp H H. Inorg. Chem., 1993,32:4102-4105
-
[26]
[26] Brown I D, Shannon R D. Acta Crystallogr., 1973,A29:266-282
-
[27]
[27] Roulhac P L, Palenik G J. Inorg. Chem., 2003,42:118-121
-
[28]
[28] Borras-Almenar J J, Clemente-Juan J M, Coronado E, et al. Inorg. Chem., 1999,38:6081-6088
-
[29]
[29] Shores M P, Sokol J J, Long J R. J. Am. Chem. Soc., 2002,124:2279-2292
-
[1]
-
-
[1]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[2]
Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
-
[3]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[4]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[5]
Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
-
[6]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[7]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[8]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[9]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[10]
Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
-
[11]
Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
-
[12]
Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
-
[13]
Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
-
[14]
Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
-
[15]
Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
-
[16]
Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
-
[17]
Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
-
[18]
Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
-
[19]
Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
-
[20]
Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(326)
- HTML views(40)