Citation: WANG Pei-Dong, XUE Jue-Jue, HU Qin-Han, QU Ling-Ling, CHEN Qiu-Yun. Cobaltous Complex Containing Pyrrol-2-yl Methanone：A Molecular Catalyst for the Oxidation of Water[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 879-884. doi: 10.11862/CJIC.2014.110 shu

Cobaltous Complex Containing Pyrrol-2-yl Methanone：A Molecular Catalyst for the Oxidation of Water

1.
School of Chemistry and Chemical Engineer, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: CHEN Qiu-Yun,
Received Date: 8 October 2013
Available Online: 10 December 2013
Fund Project: 国家自然基金(No.21271090) (No.21271090)江苏省青年基金(No.BK20130485)资助项目。 (No.BK20130485)

Cobaltous complexes catalyzing the oxidation of water are meaningful to the development of clean energy and new oxidation reaction. Anew ligand of 3-((bis(pyridin-2-ylmethyl)amino)methyl)phenyl)(3,5-dimethyl-1H-pyrrol-2-yl)methanone and the cobaltous complex (Co1) were synthesized and characterized by IR, UV, NMR, ES-MS, et al. methods. The oxidation of water catalyzed by Co1 in aqueous solution was studied. Results show that the complex Co1 can catalyze the oxidation of water to release the O₂ with TON of 15.38. The mechanism of water oxidation with the release of O₂ was explored by CV method. Experimental results demonstrate that Co1 is a new kind of noble free molecule catalyst to the oxidation of water.
- water oxidation;cobaltous complex;pyrrole;methanone
1. [1]
  [1] LI Xiao-Hui(李晓慧), FAN Tong-Xiang(范同祥), et al. Progress in Chemistry(化学进展), 2011, 23(9):1842-1852
2. [2]
  [2] Puntoriero F, Sartorel A, Orlandi M, et al. Coord. Chem. Rev., 2011, 255:2594-2601
3. [3]
  [3] Eckenhoff W T, McNamara W R, Du P W, et al. Biophys. Acta, 2013, 1827:958-973
4. [4]
  [4] Derek J W, Ryan D P, Eduardo S, et al. Chem. Commun., 2012, 48:2107-2109
5. [5]
  [5] Sasaki Y, Kato H, Kudo A. J. Am. Chem. Soc., 2013, 135: 54415449
6. [6]
  [6] Sun Y J, Sun J W, Long J R, et al. Chem. Sci., 2013, 4:118-124
7. [7]
  [7] Leung C, Ng S M, Ko C C, et al. Energy Environ. Sci., 2012, 5:7903-7907
8. [8]
  [8] Li Z, Chen Q Y, Wang P D, et al. RSC Adv., 2013, 3:5524-5528
9. [9]
  [9] MA Zheng-Ping(马正平), YE Ya(叶亚), CHEN Qiu-Yun(陈秋云), et al. Chinese Inorg. Chem.(无机化学学报), 2011, 27 (11):2251-2256
10. [10]
  [10] Thoi V S, Sun Y J, Long J R, et al. Chem. Soc. Rev., 2013, 42:2388-2400
11. [11]
  [11] Bania K K, Deka R C. J. Phys. Chem. C., 2013, 117:11663-11678
12. [12]
  [12] Nakazono T, Parent A R, Sakai K, et al. Chem. Commun., 2013, 49:6325-6327
13. [13]
  [13] Hong D, Jung J, Park J, et al. Energy. Environ. Sci., 2012, 5: 606-7616
14. [14]
  [14] Ou Z P, Lu A X, Meng D Y, et al. Inorg. Chem., 2012, 51: 8890-8896
15. [15]
  [15] Luo J, Nigam P R, Liviu M M. Inorg. Chem., 2011, 50:6152-6157
16. [16]
  [16] Lee C H, Dogutan D K, Nocera D G. J. Am. Chem. Soc., 2011, 133:8775-8777
17. [17]
  [17] Wasylenko D J, Palmer R D, Schott E, et al. Chem. Commun., 2012, 48:2107-2110
1. [1]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
4. [4]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
5. [5]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
6. [6]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
7. [7]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
8. [8]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
9. [9]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
10. [10]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
11. [11]
  Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
12. [12]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
13. [13]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
14. [14]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
15. [15]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
16. [16]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
17. [17]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
18. [18]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
19. [19]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
20. [20]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(299)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142