Citation: ZHANG Jun-Hong, ZHANG Ru-Fen, MA Chun-Lin, WANG Su-Na, WEI Xi-Lian, ZHANG Shao-Liang. Syntheses and Structural Characterization of Triorganotin(Ⅳ) Complexes Containing Pamoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 664-670. doi: 10.11862/CJIC.2014.109 shu

Syntheses and Structural Characterization of Triorganotin(Ⅳ) Complexes Containing Pamoic Acid Ligand

1.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China

Received Date: 17 August 2013
Available Online: 20 November 2013
Fund Project: 国家自然科学基金(No.20971096和21073081) (No.20971096和21073081)山东省教育厅计划(J12LD13) (J12LD13)山东省自然科学基金(ZR2010BL019) (ZR2010BL019)聊城大学博士基金 (31805)资助项目。 (31805)

Three organotin(Ⅳ) complexes {[(Ph₃Sn)(pa)]·Et₃N}_n(1)、 (Bu₃Sn)₂(pa) (2) and [(Me₃Sn)₂(pa)]·CH₂Cl₂(3) were synthesized by the reaction of pamoic acid (H₂pa, 2, 3-diphenyl-propionic acid) and the corresponding triorganotin chloride R3SnCl (R=Ph, Bu, Me). All the complexes were characterized by elemental analysis, FTIR, NMR (¹H, ¹³C, ¹¹⁹Sn) spectroscopy and single crystal X-ray diffraction. Structural analyses have revealed that the complex 1 is an infinite polymeric chain, in which each tin atom is linked by the bidentate bridging pamoic acid ligand, the center tin atom adopts a five-coordinated distorted trigonal bipyramidal geometry. However, the complexes 2 and 3 show dinuclear tin structure, the center tin atoms adopt four-coordinated distorted tetrahedral geometry. CCDC: 727157, 1; 892440, 2; 732076, 3.
- triorganotin(Ⅳ) complex;pamoic acid;synthesis, crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142