Citation: ZHAO Xiu-Hua, ZHAO Ya-Yun, ZHANG Jie, PAN Jian-Guo, LI Xing. Syntheses, Crystal Structures and Fluorescent Spectra of Two Zn(Ⅱ) Complexes with Sulfonamide Pyrimidine[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 633-639. doi: 10.11862/CJIC.2014.107 shu

Syntheses, Crystal Structures and Fluorescent Spectra of Two Zn(Ⅱ) Complexes with Sulfonamide Pyrimidine

1.
1 Faculty of Science, Ningbo University, Ningbo, Zhejiang 315211, China;

Received Date: 7 June 2013
Available Online: 17 November 2013
Fund Project: 中国国家自然科学基金(No.20971075,61078055) (No.20971075,61078055)浙江省自然科学基金(No.LY12B01005) (No.LY12B01005)结构化学国家重点实验室(No.20110010) (No.20110010)

Two new Zn(Ⅱ) compounds, [Zn(L)₂(bpy)] (1) and {[Zn(L)₂(bpp)]}_n (2) (L=sulfonamide pyrimidine, bpy=2,2'-bipyridine, bpp=1,3-bis(4-pyridyl)propane), have been synthesized and characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermal analysis, elemental analysis, IR, UV-Vis and fluorescence. Single crystal X-ray analysis reveals that complex 1 is a mononuclear structure and the Zn(Ⅱ) ion exhibits a tetragonal pyramidal coordination geometry. Complex 2 is a one-dimensional structure and the Zn(Ⅱ) ion is a tetrahedral coordination geometry. Thermal analyses show that complex 1 and 2 have high thermal stability. CCDC: 935049, 1; 935050, 2.
- sulfonamide pyrimidine;Zn(Ⅱ) complex;crystal structure;fluorescence
1. [1]
  [1] Sun D F, Cao R, Sun Y Q, et al. Inorg. Chem., 2003,42: 7512-7518
2. [2]
  [2] Li X, Wei D Y, Huang S J, et al. J. Solid State Chem., 2009, 182:95-101
3. [3]
  [3] Kremer E, Facchin G, Estévez E, et al. J. Inorg. Biochem., 2006,100:1167-1175
4. [4]
  [4] Supuran C T, Casini A, Scozzafava A, et al. Curr. Cancer Drug Targets, 2002,2:55-75
5. [5]
  [5] Owa T, Nagasu T. Exp. Opin. Ther. Patents, 2000,10:1725-1740
6. [6]
  [6] Supuran C T, Scozzafava A. Exp. Opin. Ther. Patents, 2000, 10:575-600
7. [7]
  [7] Supuran C T, Scozzafava A. Curr. Med. Chem. Immunol. Endocrinol. Metab. Agents, 2001,1:61-97
8. [8]
  [8] Lobb K L, Hipskind P A, Aikins J A, et al. J. Med. Chem., 2004,47:5367-5380
9. [9]
  [9] Medina J C, Roche D, Shan B, et al. Bioorg. Med. Chem. Lett., 1999,9:1843-1846
10. [10]
  [10] Ajibade P A, Kolawole G A, O'Brien P, et al. Inorg. Chim. Acta, 2006,359:3111-3116
11. [11]
  [11] Sorenson J R J. Chem. Br., 1984:1110-1113
12. [12]
  [12] Chufán E E, Pedregosa J C, Borrás J. Vib. Spectrosc., 1997, 15:191-199
13. [13]
  [13] Wong E, Giandomenico C M. Chem. Rev., 1999,99:2451-2466
14. [14]
  [14] Reynolds Martindale E J E F. Extra Pharmacopoeia, 31st Ed. London: Royal Pharmaceutical Society, 1996.
15. [15]
  [15] Sigel H, Sigel A. Metal Ions in Biological Systems. New York: Marcel Dekker, 1983:261-278
16. [16]
  [16] Chaturvedi S C, Mishra S H, Bhargava K L. Sci. Cult., 1980, 46:401-402
17. [17]
  [17] Blasco F, Ortiz R, Perelló L, et al. J. Inorg. Biochem., 1994, 53:117-126
18. [18]
  [18] WANG Xi-Lin(王锡森), HUANG Xue-Feng(黄雪峰), XIONG Ren-Gen(熊仁根). Chinese J. Inorg. Chem.(无机化学学报), 2005,21(8):1279-1280
19. [19]
  [19] Guo Z J, Sadler P J. Angew. Chem. Int. Ed., 1999,38:1512-1531
20. [20]
  [20] Cabaleiro S, Castro J, Romero J, et al. Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2000,56:293-295
21. [21]
  [21] Beloso I, Castro J, Garcia-Vazquez J A, et al. Polyhedron, 2003,22:1099-1111
22. [22]
  [22] Higashi T. ABSCOR, Rigaku Corporation, Tokyo, Japan, 1995.
23. [23]
  [23] Sheldrick G M. SHELXL 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1996.
24. [24]
  [24] Yue Q, Sun Q, Cheng A L, et al. Cryst. Growth Des., 2010, 10:44-47
25. [25]
  [25] Zhou J, Gan N, Li T H, et al. Sensors and Actuators B, 2013,178:494-500
26. [26]
  [26] Zhan C, Zou C, Kong G Q, et al. Cryst. Growth Des., 2013, 13:1429-1437
27. [27]
  [27] CAO Yuan(曹渊), WEN Yi(文毅), LIU Bo-Lin(刘柏林), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(1):190-198
28. [28]
  [28] Li X, Zha M Q, Wang X W, et al. Inorg. Chim. Acta, 2009, 362:3357-3363
29. [29]
  [29] Li X, Wang X W, Zhang Y H. Inorg. Chem. Commun., 2008, 11:832-834
30. [30]
  [30] Wong W Y, Zhou G J, Yu X M, et al. Adv. Funct. Mater., 2007,17:315-323
31. [31]
  [31] Guo H D, Guo X M, Batten S R, et al. Cryst. Growth Des., 2009,9:1394-1401
32. [32]
  [32] Li H, Eddaoudi M, Groy T L, et al. J. Am. Chem. Soc., 1998,120:8571-8572
33. [33]
  [33] Wu C D, Lin W B. Angew. Chem., 2007,119:1093-1096
34. [34]
  [34] Qi J L, Xu W, Zheng Y Q. Z. Naturforsch., 2012,67b:1185-1190
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沈阳化工大学材料科学与工程学院沈阳 110142