Citation: YANG Shi-Feng, DUAN Hua-Ling, LIN Ji-Jun, ZHU Jian-Ying, GONG Zhen-Bin. A New Method for the Measurement of Complexation Stability Constant and Average Coordination Number of Metallic Element with Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 853-859. doi: 10.11862/CJIC.2014.102 shu

A New Method for the Measurement of Complexation Stability Constant and Average Coordination Number of Metallic Element with Polymer

1.
1 State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen, Fujiang 361102, China;

Corresponding author: GONG Zhen-Bin,
Received Date: 15 September 2013
Available Online: 5 November 2013
Fund Project: 厦门大学近海海洋环境科学国家重点实验室自主创新项目(MELRI0703)资助项目。 (MELRI0703)

Anew method using gel filtration chromatography (GFC) and inductively coupled plasma mass spectrometry (ICPMS) was developed for the measurement of complexation stability constant and average coordination number of the complex of metallic ion with polymer. As an example, the binding of PEI with Cu²⁺ was shown and investigated. The macromolecular PEI-Cu complex and micromolecular species of Cu(Ⅱ) were firstly separated by a low efficiency GFC column with a mobile phase of 0.02 mol·L^-1 HAc-NaAc buffer, and then directly introduced into ICPMS for elemental analysis. The results of complexation stability constant and average coordination number characterized by putting the concentration of different species of metallic element into the equations of the novel chemical equilibrium model which was developed in this study. The results shown that the complexation stability constants (KPEI-Cu) were between 10^9.6 and 10^10.7 and the average coordination numbers (n) were in the range of 1.0~1.3 when pHwas changed from 4.1 to 5.3 at 25 ℃. This online, rapid and accurate method of GFC-ICPMS is a novel technique for the research of polymer-metallic complex.
- gel filtration chromatography;inductively coupled plasma mass spectrometry;PEI-Cu complex;complexation stability constant;average coordination number
1. [1]
  [1] Rumeau M, Persin F, Sciers V, et al. J. Membr. Sci., 1992, 73(2/3):313-322
2. [2]
  [2] Juang R S, Liang J F. J. Membr. Sci., 1993, 82(1):163-174
3. [3]
  [3] Juang R S, Chen M N. Ind. Eng. Chem. Res., 1996, 35(6): 1935-1943
4. [4]
  [4] Geckeler K, Lange G, Eberhardt H, et al. Pure Appl. Chem., 1980, 52(7):1883-1905
5. [5]
  [5] Rivas B L, Pereira E D, Moreno-Villoslada I. Prog. Polym. Sci., 2003, 28(2):173-208
6. [6]
  [6] Geckeler K E, Volchek K. Environ. Sci. Technol., 1996, 30 (3):725-734
7. [7]
  [7] Uludag Y, Özbelge H Ö, Yilmaz L. J. Membr. Sci., 1997, 129 (1):93-99
8. [8]
  [8] Juang R S, Chiou C H. J. Membr. Sci., 2000, 177(1):207-214
9. [9]
  [9] Molinari R, Argurio P, Poerio T. Desalination, 2004, 162: 217-228
10. [10]
  [10] Rivas B L, Geckeler K E. Polymer Synthesis Oxidation Processes. Berlin Heidelberg: Springer, 1992:171-188
11. [11]
  [11] Cañizares P, Pérez Á, Camarillo R. Desalination, 2002, 144 (1):279-285
12. [12]
  [12] Molinari R, Poerio T, Argurio P. J. Membr. Sci., 2007, 295 (1):139-147
13. [13]
  [13] LIN Ji-Jun(林继军), DUAN Hua-Ling(段华玲), GONG Zhen-Bin(弓振斌). Chinese J. Anal. Chem.(分析化学), 2011, 39(6):906-910
14. [14]
  [14] Kobayashi S, Hiroishi K, Tokunoh M, et al. Macromolecules, 1987, 20(7):1496-1500
15. [15]
  [15] Jarvis N V, Wagener J M. Talanta, 1995, 42(2):219-226
16. [16]
  [16] LUO Qin-Hui(罗勤慧), SHEN Meng-Chang(沈孟长), DING Yi(丁益), et al. Acta Chim. Sinica(化学学报), 1982, 40(2): 125-133
17. [17]
  [17] Çaykara T, İnam R, Öztürk Z, et al. Colloid Polym. Sci., 2004, 282(11):1282-1285
18. [18]
  [18] Leyte J C, Zuiderweg L H, Van Reisen M. J. Phys. Chem., 1968, 72(4):1127-1132
19. [19]
  [19] Yamaoka K, Masujima T. Bull. Chem. Soc. Jpn., 1979, 52(2): 1286-1296
20. [20]
  [20] Tomida T, Hamaguchi K, Tunashima S, et al. Ind. Eng. Chem. Res., 2001, 40(16):3557-3562
21. [21]
  [21] Islamoglu Kadioglu S, Yilmaz L, Onder Ozbelge H. Sep. Sci. Technol., 2009, 44(11):2559-2581
22. [22]
  [22] HUANG Jia-Hua(黄佳华), GONG Zhen-Bin(弓振斌), LIN Ji-Jun(林继军), et al. Chem. J. Chinese U.(高等学校化学学报), 2012, 33(12):2633-2637
23. [23]
  [23] HUANG Jia-Hua(黄佳华). Thesis for the Master Degree of Xiamen University(厦门大学硕士学位论文). 2012.
24. [24]
  [24] Striegel A, Yau W W, Kirkland J J, et al. Modern Size-ex Clusion Liquid Chromatography: Practice of Gel Permeation and Gel Filtration Chromatography. New York: Wiley, 2009.
25. [25]
  [25] Yeung B, Marecak D. J. Chromatogr., A, 1999, 852(2):573-581
26. [26]
  [26] Rojas E E G, Reis Coimbra dos JS, Minim L A, et al. Process Biochem., 2004, 39(11):1751-1759
27. [27]
  [27] Vasudevan P T, Palekar A A, Yan S. Biocatal. Biotransform., 2002, 20(3):189-199
28. [28]
  [28] Achterberg E P, Holland T W, Bowie A R, et al. Anal. Chim. Acta, 2001, 442(1):1-14
29. [29]
  [29] Liu M, Xie C, Xu W, et al. J. Chromatogr., A, 2004, 1046 (1):121-126
30. [30]
  [30] Cutié S S, Martin S J. J. Appl. Polym. Sci., 1995, 55(4):605 -609
31. [31]
  [31] ZHANG Han-Qi(张寒琦), TIE Yuan(铁元), WANG Da-Ning (王大宁), et al. Brief Handbook of Analytical Chemistry (分析化学简明教程). Changchun: Jilin University Press, 1996.
32. [32]
  [32] Thiele H, Gronau K H. Makromol. Chem., 1963, 59:207-221
33. [33]
  [33] Molinari R, Poerio T, Argurio P. Chemosphere, 2008, 70(3): 341-348
34. [34]
  [34] Bekturov E A, Bakauova Z K. Synthetic Water-soluble Polymers in Solution. Basel, Heidelberg, New York: Hüthig & Wepf Verlag, 1986.
1. [1]
  Runze Xu , Rui Liu . U-Pb Dating in the Age of Dinosaurs. University Chemistry, 2024, 39(9): 243-247. doi: 10.12461/PKU.DXHX202404083
2. [2]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
3. [3]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
4. [4]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
5. [5]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
6. [6]
  Wenjing ZHANG , Xiaoqing WANG , Zhipeng LIU . Recent developments of inorganic metal complex-based photothermal materials and their applications in photothermal therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2356-2372. doi: 10.11862/CJIC.20240254
7. [7]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
8. [8]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
9. [9]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
10. [10]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
11. [11]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
12. [12]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
13. [13]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
14. [14]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
15. [15]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
16. [16]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
17. [17]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
18. [18]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
19. [19]
  Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365
20. [20]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(576)
HTML views(126)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142