Citation: YAN Zheng-Yu, ZHAO Na, LIU Zhen, LÜ Hua, CHEN Jian-Qiu. Biomass-Based Carbon Dots：Synthesis and Application in Oxytetracycline Hydrochloride Determination[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 937-944. doi: 10.11862/CJIC.2014.097 shu

Biomass-Based Carbon Dots：Synthesis and Application in Oxytetracycline Hydrochloride Determination

YAN Zheng-Yu ^1,2 ,
ZHAO Na ^1,2 ,
LIU Zhen ^1,2 ,
LÜ Hua ^1,2 ,
CHEN Jian-Qiu ^1,2,,

1.
1 State Key Laboratory of Natural Medicines, China Pharmaceutical University, Nanjing 210009, China;

Corresponding author: CHEN Jian-Qiu,
Received Date: 27 August 2013
Available Online: 23 November 2013
Fund Project: 江苏省环境工程重点实验室开放基金(No.KF2012008)；江苏省自然科学基金青年基金(No.BK20130646)；中央高校基本科研业务费专项资金(No.JKQZ2013009,No.JKPZ2013017)；中国药科大学大学生创新训练计划(No.02640556、JKY2011083)资助项目。 (No.KF2012008)；江苏省自然科学基金青年基金(No.BK20130646)；中央高校基本科研业务费专项资金(No.JKQZ2013009,No.JKPZ2013017)；中国药科大学大学生创新训练计划(No.02640556、JKY2011083)

Carbon dots (CDs) were prepared via a simple chemical oxidation route using activated carbon as the carbon precursor and a mixture of hydrogen peroxide and acetic acid as the oxidant. The obtained CDs were further purified by diethyl ether and passivated by polyethylene glycol 2000 (PEG₂₀₀₀). When excited at 316 nm, the maximum emission wavelength of the CDs is about 435 nm, with a quantum yield of 19.6%. Based on fluorescence quenching, a novel method for assay of oxytetracycline hydrochloride (OTC) was developed with PEG₂₀₀₀-passivated CDs. Alinear relationship between the change of fluorescence intensity and the concentration of OTC (1.66~49.69 μg·mL^-1) was obtained with a relation coefficient of 0.9986. The recovery was in the range of 98.0% to 102.0% with a relative standard deviation of 1.7%, and the limit of detection was 1.4×10^-3 μg·mL^-1.
- carbon dots;polyethylene glycol 2000;oxytetracycline hydrochloride;fluorescence quenching
1. [1]
  [1] Xu X, Ray R, Gu Y, et al. J. Am. Chem. Soc., 2004, 126(40): 12736-12737
2. [2]
  [2] Yang S T, Wang X, Wang H, et al. J. Phys. Chem. C, 2009, 113(42):18110-18114
3. [3]
  [3] Zhao Q L, Zhang Z L, Huang B H, et al. Chem. Commun., 2008(41):5116-5118
4. [4]
  [4] Esteves da Silva J C, Gonalves H M. Trends Anal. Chem., 2011, 30(8):1327-1336
5. [5]
  [5] Yang S T, Cao L, Luo P G, et al. J. Am. Chem. Soc., 2009, 131(32):11308-11309
6. [6]
  [6] Zhou Y, Xing G, Chen H, et al. Talanta, 2012, 99:471-477
7. [7]
  [7] Zhang J, Shen W, Pan D, et al. New J. Chem., 2010, 34(4): 591-593
8. [8]
  [8] Zheng L, Chi Y, Dong Y, et al. J. Am. Chem. Soc., 2009, 131(13):4564-4565
9. [9]
  [9] Pan D, Zhang J, Li Z, et al. Adv. Mater., 2010, 22(6):734-738
10. [10]
  [10] Hu S L, Niu K Y, Sun J, et al. J. Mater. Chem., 2009, 19(4): 484-488
11. [11]
  [11] Zhu H, Wang X, Li Y, et al. Chem. Commun., 2009(34): 5118-5120
12. [12]
  [12] Liu C, Zhang P, Zhai X, et al. Biomaterials, 2012, 33(13): 3604-3613
13. [13]
  [13] Liu H, Ye T, Mao C. Angew. Chem.-Int. Ed., 2007, 46(34): 6473-6475
14. [14]
  [14] Liu R, Wu D, Liu S, et al. Angew. Chem., 2009, 121(25): 4668-4671
15. [15]
  [15] Han B, Wang W, Wu H, et al. Colloids Surf. B: Biointerfaces, 2012, 100:209-214
16. [16]
  [16] Cao L, Wang X, Meziani M J, et al. J. Am. Chem. Soc., 2007, 129(37):11318-11319
17. [17]
  [17] Gonalves H, Jorge P A, Fernandes J, et al. Sens. Actuators B: Chem., 2010, 145(2):702-707
18. [18]
  [18] Gonalves H, da Silva J C E. J. Fluoresc., 2010, 20(5):1023-1028
19. [19]
  [19] Zhao H X, Liu L Q, De Liu Z, et al. Chem. Commun., 2011, 47(9):2604-2606
20. [20]
  [20] Wang X, Cao L, Lu F, et al. Chem. Commun., 2009(25):3774 -3776
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