Citation: CHENG Xiao-Ning*, ZHANG Wei-Xiong, XUE Wei, CHEN Xiao-Ming*. Syntheses, Structures, and Magnetic Properties of Three Isostructural Coordination Polymers Based on Quinoline-8-oxy-acetate[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 142-148. doi: 10.11862/CJIC.2014.087 shu

Syntheses, Structures, and Magnetic Properties of Three Isostructural Coordination Polymers Based on Quinoline-8-oxy-acetate

1.
1 MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China;

Received Date: 27 September 2013
Available Online: 27 November 2013
Fund Project:

Three isostructural coordination polymers, namely [Ni(8-qoac)Cl]_n (1, 8-Hqoac=quinoline-8-oxy-acetic acid), [Fe(8-qoac)Cl]_n (2), and [Mn(8-qoac)Cl]_n (3) were synthesized under solvothermal reaction conditions. Single-crystal X-ray diffraction studies showed that 1~3 crystallize in the same space group Pbca, in which the octahedral metal ions are first bridged by two chloride ions to form a dinuclear building blocks, and then each dinuclear building block is connected to four adjacent neighbors via four carboxylate groups with the anti-anti coordination mode, giving a two-dimensional layered (4, 4) network considering the dinuclear building blocks as 4-connected nodes and the carboxylate groups as linkers. Magnetic measurements revealed spin-canting-like behaviors for compound 1, while 2 and 3 only exhibit simple antiferromagnetic properties, which can be explained by the different magnetic anisotropic behaviors of the transition metal ions.
- coordination polymer;isostructure;laminate;magnetism;spin canting,
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