Citation: ZHAO Yue, ZHAI Ling-Ling, SUN Wei-Yin*. Synthesis, Crystal Structure and Fluorescence Property of Zn(Ⅱ), Cd(Ⅱ)Coordination Polymers with Benzoimidazol-Containing Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 99-105. doi: 10.11862/CJIC.2014.081 shu

Synthesis, Crystal Structure and Fluorescence Property of Zn(Ⅱ), Cd(Ⅱ)Coordination Polymers with Benzoimidazol-Containing Ligand

1.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 3 September 2013
Available Online: 19 November 2013
Fund Project:

Two new coordination polymers [Zn(L)(m-BDC)] (1) and [Cd(L)(CCA)]·2H₂O (2) were synthesized by solvothermal method using 3,5-di(1H-benzoimidazol-1-yl)pyridine (L), isophthalic acid (m-H₂BDC), 4-(2-carbox-yvinyl)benzoic acid (H₂CCA). And the complexes were characterized by FT-IR, elemental analysis, thermogravimetric analysis (TGA) and power X-ray diffraction (PXRD), meanwhile the crystal structures and fluorescence properties of the complexes have been studied. In complex 1, the ligand Lconnects the metal atoms to give a 1Dchain structure, and the m-BDC^2- coordinates with metal atom to form a M₂(m-BDC)₂ unit (M=metal). Moreover, the adjacent 1D chains are linked by the M₂(m-BDC)₂ to produce a 2D network structure. In complex 2, the ligand joins the metal atoms to generate a 1D chain like that in 1. However, the carboxylate ligand coordinates with metal atoms to form a 1D chain, and two kinds of the 1D chains crosslink each other to produce a 2D structure.
- coordination polymers;fluorescence property;crystal structure,
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沈阳化工大学材料科学与工程学院沈阳 110142