Citation: LIU Cai-Ming*, HUANG Guang-Xi, XIONG Ming. Ultrasonic Synthesis, Crystal Structure and Magnetic Properties of a Dinuclear Dysprosium(Ⅲ) β-Diketonate Complex[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 93-98. doi: 10.11862/CJIC.2014.080 shu

Ultrasonic Synthesis, Crystal Structure and Magnetic Properties of a Dinuclear Dysprosium(Ⅲ) β-Diketonate Complex

1.
1 Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

Received Date: 13 August 2013
Available Online: 13 November 2013
Fund Project:

Anew dinuclear Dy(Ⅲ) β-diketonate complex, Dy₂(Hpdm)₂(dbm)₄·2EtOH (1, H₂pdm=2,6-pyridinedimethanol, Hdbm=dibenzoylmethane), has been successfully prepared by ultrasonic method. Single crystal X-ray crystallographic analysis revealed that the two Dy(Ⅲ) ions are bridged by the deprotonated alkoxide arm of the pdmH-ligand. Variable-temperature magnetic susceptibility measurements showed that there exists a weak antiferromagnetic interaction between the two Dy(Ⅲ) ions, but no relaxation process of magnetion was observed, even when a 2000 Oe dc field was applied.
- dinuclear dysprosium(Ⅲ) complex;crystal structure;magnetic properties;ultrasonic synthesis,
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沈阳化工大学材料科学与工程学院沈阳 110142