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Citation: YIN Ping, JIANG Xiao-Hong*, ZOU Min, LU Lu-De, WANG Xin. Catalytic Effect of SiO2/Co3O4 Core-Shell Catalyst on Thermal Decomposition of AP[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 185-191. doi: 10.11862/CJIC.2014.076 shu

Catalytic Effect of SiO2/Co3O4 Core-Shell Catalyst on Thermal Decomposition of AP

  • 1.

    Key Lab for Soft Chemistry and Functional Materials of Ministry Education, Nanjing University of Science and Technology, Nanjing 210014, China

  • Received Date: 11 November 2013
    Available Online: 9 December 2013

    Fund Project:

  • Highly dispersed SiO2 microspheres with mean diameter of 200 nm were prepared by modified Stöber method. Then the prepared SiO2 nanoparticles were coated with Co3O4 via liquid precipitation method and urea homogeneous precipitation method respectively, thus a new type SiO2/Co3O4 core-shell catalysts with different coating forms were obtained. X-ray diffraction (XRD), transmission electron microscopy (TEM), infrared (IR) spectra, Raman Microscopy and BET specific surface area measurement were used to characterize the SiO2/Co3O4 composite nanoparticles. The catalytic activities of SiO2/Co3O4 composites for thermal decomposition of ammonium perchlorate (AP) were studied by differential scanning calorimetry (DSC). Furthermore, we espescially investigated the influence of different coating forms on its catalytic effect. The results indicate that SiO2/Co3O4 nanocomposites synthesised by different methods possess obvious core-shell structure are with high specific surface area,which are layer-coated and particle-coated respectively. And the catalytic activity of particle-coated SiO2/Co3O4 nanocomposites is best, which reduce the high decomposition temperature of AP by 110 ℃, and increase heat quantity by 662 J·g-1.
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    1. [1]

      [1] CHEN Qing-Ling(陈庆龄). Modern Chem. Ind.(现代化学), 2004, 24(7):20-25

    2. [2]

      [2] FANG Li(范立), DUAN Tao(段涛). Guangzhou Chem. Ind. (广州化工), 2010, 38(12):25-26

    3. [3]

      [3] YAN Zi-Feng(阎子峰). Nanomet. Catal. Technol.(纳米催化 技术). Beijing:Chemical Industry Process, 2003.

    4. [4]

      [4] Aleksandr V D. Propellants, Explos., Pyrotech., 2005, 30:244-249

    5. [5]

      [5] LI Feng-Sheng(李凤生), YANG Yi(杨毅), MA Zhen-Ye (马振叶), et al. Nanomet. Funct. Composit. Mater. Appl. (纳米功能复合材料), Beijing:National Defence Industry Press, 2003.

    6. [6]

      [6] LIU Jian-Xun(刘建勋), LI Feng-Sheng(李凤生), JIANG Wei (姜炜), et al. J. Solid Roket Technol.(固体火箭技术), 2007, 30(3):243-247

    7. [7]

      [7] SHI Li-Hong(石利红), LI Xiao-Feng(李晓峰), LI De-Bao (李德宝), et al. Chin. J. Catal. (催化学报), 2010, 31(12): 1483-1488

    8. [8]

      [8] Stöber W, Fink A. J. Colloid Interf. Sci., 1968, 26:62-69

    9. [9]

      [9] Yang J H, Sasaki T. Cryst. Growth Des., 2010, 10(3):1233-1236

    10. [10]

      [10] Farhadi S, Safabakhsh J, Zaringhadam P. J. Nanostruct. Chem., 2013, 3:69-77

    11. [11]

      [11] Meng Y D, Chen D, Jiao X L. J. Phys. Chem. B, 2006, 110: 15212-15217

    12. [12]

      [12] Chakkalakal G L, Alexandre M, Abetz C, et al. Macromol. Chem. Phys., 2012, 213:513528.

    13. [13]

      [13] MENG Yong-De(孟永德). Thesis for the Doctorate of Shandong University(山东大学博士论文). 2007

    14. [14]

      [14] Farhadi S, Pourzare K, Sadeghinejad S. J. Nanostruct. Chem., 2013, 3:16-22

    15. [15]

      [15] Tripathy S K, Christy M. Mater. Lett., 2008, 62:1006-1009

    16. [16]

      [16] LU Lu-De(陆路德). Quantum Chemistry (量子化学). Beijing: Science Press, 1980

    17. [17]

      [17] Boldyrev V V. Thermochim. Acta, 2006, 443:1-36

    18. [18]

      [18] YE Jian(叶剑), ZHANG Rui-Feng(张瑞丰), HOU Lin-Xi (侯琳熙). Chin. J. Environ.Eng.(环境工程学报), 2011, 5(7): 1598-1600

    19. [19]

      [19] Keenan A G, Siegmund R F. Quart. Rev. Chem. Soc., 1969, 23(3):435-452

    20. [20]

      [20] Rosso L, Tuckerman M E. Solid State Ion, 2003, 161:219-229

    21. [21]

      [21] Chaturvedi S, Pragnesh N D. J. Saudi Chem. Soc., 2013, 17 (2):135-149

    22. [22]

      [22] ZHANG Bo-Sheng(张柏生). Introd. Powder Burning(火药燃 料导论). Nanjing:East China Insttute of Technology, 1988.

    23. [23]

      [23] LIU Jian-Xun(刘建勋), WANG Zuo-Shan(王作山), JIANG Wei(姜炜), et al. Rare Metal Mater. Eng.(稀有金属材料与 工程), 2007, 36(Z3):649-653

  • 加载中
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