Citation: WAN Hong-Xiang, JU Wei-Wei, ZHANG Yu, XU Yan*. Synthesis, Structures and Properties of the 3D Compounds Containing L-Chiral Helical Chains[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 85-92. doi: 10.11862/CJIC.2014.074 shu

Synthesis, Structures and Properties of the 3D Compounds Containing L-Chiral Helical Chains

1.
State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

Received Date: 12 July 2013
Available Online: 4 December 2013
Fund Project:

Two compounds with L-Chiral helical chains have been solvothermal synthesized: Sm(HCO₂)(SO₄)(H₂O) (1) and KSm(H₂O)(SO₄)₂ (2). Complex 1 is synthesized without any chiral auxiliary, while complex 2 is the opposite. However, in 2, chiral auxiliaries do not exsit in the inorganic framework but work as the inducer in the formation of the complex. Single-crystal X-ray diffraction (XRD) demonstrates that complex 1 crystallizes in space group P4₁ and complex 2 crystallizes in space group P3₁. Complex 1 is constructed of two types of L-[Sm-O]_n chains, every two different kinds of adjacent helical chains are connected by sharing Sm(Ⅲ) ions to form Intertwined left-handed double helices. Compound 2 is constructed of two L-chiral helical chains: [Sm-O-S₁-O]_n and [Sm-O-S₂-O]_n, the two adjacent helical chains are connected by sharing Sm(Ⅲ) ions to form double helices chains, every two adjacent double helices chains are connected through K⁺ linkages to form Intertwined left-handed double helices. The second-harmonic-generation efficiencies and fluorescence of 1 and 2 were studied.
- solvothermal synthesis;chirality;fluorescence;second-harmonic generation effect,
1. [1]
  [1] Hagrman P J, Hagrman D, Zubieta J. Angew. Chem. Int. Ed., 1999, 38:2638-2684
2. [2]
  [2] Judd D A J, Nettles J H, Nevins N, et al. J. Am. Chem. Soc., 2001, 123:886-897
3. [3]
  [3] Muller A, Peters F, Pope M T, et al. Chem. Rev., 1998, 98: 239-272
4. [4]
  [4] Fang X K, Anderson T M, Hill C L. Angew. Chem. Int. Ed., 2005, 44:3540-3544
5. [5]
  [5] Xin F B, Pope M T. J. Am. Chem. Soc., 1996, 118:7731-7736
6. [6]
  [6] Kumaiga H, Inoue K. Angew. Chem. Int. Ed., 1999, 38:1661-1664
7. [7]
  [7] Long D L, Burkholder E, Cronin L. Chem. Soc. Rev., 2007, 36: 105-121
8. [8]
  [8] Minguet M, Luneau D, Lhotel E, et al. Angew. Chem. Int. Ed., 2002, 41:586-589
9. [9]
  [9] Inoue K, Imai H, Ghalsasi P S, et al. Angew. Chem. Int. Ed., 2001, 40:4242-4245
10. [10]
  [10] Zelewskv A, von Knof U. Angew. Chem. Int. Ed., 1999, 38: 302-322
11. [11]
  [11] Long D L, Kogerler P, Farrugia L J, et al. Chem. Asian J., 2006, 1:352-357
12. [12]
  [12] Kortz U, Savelieff M G, Ghali F Y A, et al. Angew. Chem. Int. Ed., 2002, 41:4070-4073
13. [13]
  [13] Fang X K, Anderson T M, Hou Y, et al. Chem. Commun., 2005:5044-5046
14. [14]
  [14] Cheetham A K, Ferey G, Loiseau T. Angew. Chem. Int. Ed., 1999, 38:3268-3292
15. [15]
  [15] Coronado E, Galan-Mascaros J R, Gomez-García C J, et al. Inorg. Chem., 2001, 40:113-120
16. [16]
  [16] Han S J, Manson J L, Kim J, et al. Inorg. Chem., 2000, 39: 4182-4185
17. [17]
  [17] Katsuki I, Motoda Y, Sunatsuki Y, et al. J. Am. Chem. Soc., 2002, 124:629-640
18. [18]
  [18] Ezuhara T, Endo K, Aoyama Y. J. Am. Chem. Soc., 1999, 121:3279-3282
19. [19]
  [19] Tabellion F M, Seidel S R, Arif A M, et al. Angew. Chem. Int. Ed., 2001, 40:1529-1532
20. [20]
  [20] Perez-García L, Amabilino D B. Chem. Soc. Rev., 2002, 31: 342-356
21. [21]
  [21] Sasa M, Tanaka K, Bu X H, et al. J. Am. Chem. Soc., 2001, 123:10750-10751
22. [22]
  [22] Gao E Q, Bai S Q, Wang Z M, et al. J. Am. Chem. Soc., 2003, 125:4984-4985
23. [23]
  [23] Tan H Q, Li Y G, Zhang Z M, et al. J. Am. Chem. Soc., 2007, 129:10066-10067
24. [24]
  [24] Sporer C, Wurst K, Amabilino D B, et al. Chem. Commun., 2002:2342-2343
25. [25]
  [25] Cheetham A K, Ferey G, Loiseau T. Angew. Chem. Int. Ed., 1999, 38:3268-3292
26. [26]
  [26] Soghomonian V, Chen Q, Haushalter R C, et al. Science, 1993, 259:1596-1599
27. [27]
  [27] Zhang D, Lu Y, Zhu D R, et al. Inorg. Chem., 2013, 52: 3253-3258
28. [28]
  [28] Doran M, Norquist A J, OHare D. Chem. Commun., 2002: 2946-2947
29. [29]
  [29] Wickleder M S. Chem. Rev., 2002, 102:2011-2088
30. [30]
  [30] Wang D, Yu R, Xu Y, et al. Chem. Lett., 2002, 11:1120-1121
31. [31]
  [31] Xing Y, Zhan S, Li G H, et al. Dalton. Trans., 2003, 5:940-943
32. [32]
  [32] Dan M, Behera J N, Rao C N R. J. Mater. Chem., 2004, 14: 1257-1265
33. [33]
  [33] Dolzhenkova E F, Shekhovtsov A N, Tolmachev A V, et al. J. Cryst. Growth, 2001, 233:473-476
34. [34]
  [34] Xing Y, Liu Y L, Shi Z, et al. Solid State Chem., 2003, 174: 381-385
35. [35]
  [35] Perles J, Fortes-Revilla C, Gutierrez-Puebla E, et al. Chem. Mater., 2005, 17:2701-2706
36. [36]
  [36] Xu Y, Ding S H, Zheng X F. J. Solid State Chem., 2007, 180: 2020-2025
37. [37]
  [37] Ye N, Stone-Sundberg J L, Hruschka M A, et al. Chem. Mater., 2005, 17:2687-2692
38. [38]
  [38] Ju W W, Zhang D, Zhu D R, et al. Inorg. Chem., 2012, 51: 13373-13379
39. [39]
  [39] LÜ Yun(吕赟), ZHANG Deng(张登), FAN Xin-Rong (范新蓉), et al. Chinese J. Inorg. Chem. (无机化学学报), 2013, 29:2623-2630
40. [40]
  [40] Zhou W L, Xu Y, Han L J, et al. Dalton Trans., 2010, 39: 3681-3686
1. [1]
  Guilan He , Yaofeng Yuan . 手性二茂铁双膦配体Xyliphos的合成及应用. University Chemistry, 2025, 40(8): 130-137. doi: 10.12461/PKU.DXHX202409122
2. [2]
  Hao YAN , Meng WANG , Chenyi HU , Ming LI , Chuanjun YUAN . Synthesis of europium complex bonded NaYF₄∶Yb, Er micron-materials and their applications in dual-mode fluorescent development of latent fingerprints. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 991-1002. doi: 10.11862/CJIC.20250302
3. [3]
  Qi Liang , Xinxin Wang , Xinmiao Zhao , Mohan Yu , Yue Sun . 电子圆二色谱结合量子化学计算的氨基酸手性解析——介绍一个计算化学综合实验. University Chemistry, 2026, 41(5): 380-390. doi: 10.12461/PKU.DXHX202511096
4. [4]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
5. [5]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
6. [6]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265
7. [7]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
10. [10]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
11. [11]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
12. [12]
  Zehua Zhang , Haitao Yu , Yanyu Qi . Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect. Acta Physico-Chimica Sinica, 2025, 41(1): 100006-0. doi: 10.3866/PKU.WHXB202309042
13. [13]
  Wenwei Zeng , Qingyu Sun , Mengxiang Liang , Lirong Lin , Laiying Zhang . Unveiling Anti-Counterfeiting Secrets: Excitation-Dependent Luminescence in Sb³⁺-Doped Perovskite Materials. University Chemistry, 2026, 41(2): 375-384. doi: 10.12461/PKU.DXHX202503036
14. [14]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
15. [15]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
16. [16]
  Min Hu , Yinghuan Li , Yanhong Bai , Yanping Ren , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Faqiong Zhao , Wenwei Zhang , Mei Shi , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on the Method of Hydrothermal-Solventthermal Synthesis and Their Operation Standards. University Chemistry, 2026, 41(3): 208-215. doi: 10.12461/PKU.DXHX202507034
17. [17]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
18. [18]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
19. [19]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
20. [20]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174

Get Citation

PDF

XML

Metrics

PDF Downloads(454)
Abstract views(1970)
HTML views(192)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142