Citation: ZHANG Jie, TENG Ming-Yu, DAI Guo-Liang, ZHAO Song-Lin, WANG Jia-Li, ZHANG Ping, SONG Tong-Tong. Synthesis, Characterization, Linear and Nonlinear Optical Effects of Nonsymmetrical Bipolar (D-π-A) Pyridyl Metallo Salophen Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 499-505. doi: 10.11862/CJIC.2014.059 shu

Synthesis, Characterization, Linear and Nonlinear Optical Effects of Nonsymmetrical Bipolar (D-π-A) Pyridyl Metallo Salophen Complexes

1.
1 School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, Zhejiang 318000, China;

Received Date: 29 July 2013
Available Online: 26 September 2013
Fund Project: 浙江省自然科学基金(No.LQ13B010001) (No.LQ13B010001)国家自然科学基金(No.21203135) (No.21203135)浙江省教育厅科研基金(No.Y201016505)资助项目。 (No.Y201016505)

The pyridine substituent vanillins (1a and 1b) were synthesized by still coupling reaction. New unsymmetrical metallo Salophen complexes (3a, 3b and 3c) derived from the condensation of monoamine 2 and pyridine substituent salicylaldehyde in the presence of transition metal ions (Zn²⁺, Ni²⁺) as template have been synthesized and characterized. The linear and third-order non-linear optical (two photon absorption, TPA) properties of the complexes have been measured. The emission of (3a and 3c) were in the visible range(504~516 nm) with lifetime between 4.51 to 5.18 ns and quantum yields (Φ_em) between 4.3% to 5.3%. Decay times with nano-second scale indicate the emissions come from the singlet states. Complexes 3a, 3b and 3c are thermally stable with onset decomposition temperatures (T_d) within the range of 333 to 374 ℃. 100 fs laser pulses with the open-aperture Z-scan method was used to measure the TPA cross-sections σ⁽²⁾ of 3a, 3b and 3c at 800 nm. The σ⁽²⁾ could reach to 1 403 GM, which is among the largest value known for metalloSalophen complexes to date. In general, these Salophen complexes show moderate fluorescence quantum yields, larger σ⁽²⁾, low cytotoxicity of zinc complexes and thermal stability. Hence, they are potentially good TPA candidates for tissue imaging work and excitation by NIR or longer-wavelength radiation is possible to increase penetration depth and reduce cell damage.
- Salophen complexes;bipolar molecular;linear optical properties;two photon absorption cross-sections;Z-scan
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