Citation: CHEN Zhi-Min, YANG Ying-Qun, YI Zheng-Ji. Crystal Structure, Electrochemical, Fluorescent and Magnetic Properties of a New Manganese (Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid as a Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 659-663. doi: 10.11862/CJIC.2014.055 shu

Crystal Structure, Electrochemical, Fluorescent and Magnetic Properties of a New Manganese (Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid as a Ligand

1.
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 19 February 2013
Available Online: 20 September 2013
Fund Project: 湖南省科学技术厅科技计划项目(No.2012GK3030) (No.2012GK3030)湖南省教育厅科学研究项目(No.11C0186) (No.11C0186)衡阳市科技计划项目(No.2011kG28) (No.2011kG28)

A new complex Mn(L)₂(2,2'-bipy)₂ (1) with 2-(4-methylbenzoyl)benzoic acid (HL) as a ligand has been synthesized. Crystal data for 1 are as follows: monoclinic, space group P2₁/c, a=1.719 8(2) nm, b=1.039 80(14) nm, c=2.346 3(3) nm, β=95.732(3)°, V=4.174 8(9) nm³, D_c=1.346 g·cm^-3, Z=4, μ(Mo Kα)=0.373 mm^-1, F(000)=1 756, final discrepancy factors R₁=0.042 3, wR₂=0.094 9. In 1, Mn(Ⅱ) ion is coordinated by six atoms to give a distorted octahedral coordination geometry. The electrochemical, luminescence and magnetic properties of 1 are studied. The results show that the electron transfer of 1 is quasi reversible in the electrode reaction corresponding to Mn(Ⅲ)/Mn(Ⅱ), and 1 exhibits one relatively strong fluorescent emission band at around 536~556 nm. In addition, 1 displays antiferromagnetic property in temperatures range of 300~2 K. CCDC: 924900.
- manganese(Ⅱ) complex;2-(4-methylbenzoyl)benzoic acid;crystal structure;electrochemical;fluorescent and magnetic properties
1. [1]
  [1] Hargman P J, Hargman D, Zubieta J. Angew. Chem. Int. Ed., 1999,38:2639-2643
2. [2]
  [2] Xiao H P, Hu M L, Shi Q, et al. Acta Crystallogr., Sect. C Cryst. Struct. Commun., 2004,60:16-19
3. [3]
  [3] Majumder A, Gramlich V, Rosair G M, et al. Cryst. Growth Des., 2006,6:2355-2368
4. [4]
  [4] Beko S L, Bats J W, Schmidt M U. Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2009,65:347-351
5. [5]
  [5] Fan S R, Zhu L G. J. Mol. Struct., 2007,827:188-194
6. [6]
  [6] LI Gong-Chun(李公春), WANG Hong-Sheng(王宏胜), ZHULei(朱蕾), et al. Chinese J. Inorg. Chem.(无机化学学报),2012,28(11):2369-2372
7. [7]
  [7] XU Zhan-Lin(徐占林), HE Yu(贺宇), MA Shuai(马帅), et al.Chinese J. Inorg. Chem.(无机化学学报), 2012,28(4):851-855
8. [8]
  [8] Li X J, Cao R, Sun D F, et al. Cryst. Growth Des., 2004,4: 775-780
9. [9]
  [9] Gavrilenko K S, Punin S V, Cador O, et al. J. Am. Chem. Soc., 2005,127:12246-12253
10. [10]
  [10] Yang J M, Zhou Z H, Zhang H, et al. Inorg. Chim. Acta, 2005,358:1841-1849
11. [11]
  [11] He J H, Zhang Y T, Pan Q H, et al. Microporous and Mesoporous Materials, 2006,90:145-152
12. [12]
  [12] Gong Y Q, Chen J T, Yuan D Q, et al. Inorg. Chim. Acta, 2007,360(7):2207-2214
13. [13]
  [13] Jiang H, Liu Y Y, Ma J F, et al. Polyhedron, 2008,27:2595 -2602
14. [14]
  [14] LI Xiu-Mei(李秀梅), WANG Qing-Wei(王庆伟), LIU Bo(刘博), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011, 27(6):1207-1211
15. [15]
  [15] HU Zong-Qiu(胡宗球), YE Xiao-Zhao(叶效昭), SONG Xue-Gang (宋学刚), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011,27(10):1993-1998
16. [16]
  [16] YAN Jing(闫璟), YAO Zhao-Quan(姚兆全), WU Xiu-Mei(吴秀梅), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(12):2674-2680
17. [17]
  [17] SHI Zhi-Qiang(石智强), JI Ning-Ning(季宁宁), HE Guo-Fang(何国芳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(6):1279-1285
18. [18]
  [18] Kang W L, Wu X Y, Huang J B. J. Organomet. Chem., 2009,694:2402-2408
19. [19]
  [19] LI Wei(李薇), LI Chang-Hong(李昶红), YANG Ying-Qun(杨颖群), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010, 26(1):166-170
20. [20]
  [20] Sheldrick G M. SHELXS/L-97, Programs for Crystal Structure Determination, University of Göttingen, Germany, 1997.
21. [21]
  [21] Sheldrick G M. Acta Crystallogr., 1990,A46:467-473
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
8. [8]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
9. [9]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
14. [14]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
15. [15]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
16. [16]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
17. [17]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
18. [18]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
19. [19]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
20. [20]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(189)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142