Advanced Search

Citation: LI Yan, ZHUANG Quan-Chao, WANG Hong-Tao, WU Wen-Wei, ZHAO Yu-Long, QIANG Ying-Huai. Electrode Interface Characteristics of TiO2 Solar Cells with Surface Modification[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 763-769. doi: 10.11862/CJIC.2014.052 shu

Electrode Interface Characteristics of TiO2 Solar Cells with Surface Modification

  • 1.

    1 School of Mechanical and Electrical Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China;

  • Corresponding author: ZHUANG Quan-Chao, 
  • Received Date: 8 July 2013
    Available Online: 25 September 2013

    Fund Project: 学科创新能力提升基金(No.2013XK04)资助项目。 (No.2013XK04)

  • TiO2 nanomaterial with typital anatase was prepared by hydrothermal method. Asurface modification method was carried out by over layer coating on the surface of TiO2 thin film using Cr(NO3)3. The surface phase and morphology of electrodes were characterized by X ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results showed that a layer of chromium oxide with larger particles was coated on TiO2 thin film and the electrode remains homogeneous porous structure. The current-voltage (I-V) curves revealed that short circuit current and photoelectric transfer efficiency of the optimal modified electrode enhanced by 31.1% and 40.4% respectively more than before. Interface characteristics of cells were discussed using EIS. Seen from the results, the resistance of TiO2/dye/electrolyte interface of modified electrode was much larger than before at the same bias. It is indicated that chromium oxide coating on TiO2 thin film suppressed the charge recombination reactions and improved the performance of DSSCs.
  • 加载中
    1. [1]

      [1] O'Regan B, Grtzel M. Nature, 1991, 353:737-740

    2. [2]

      [2] Grtzel M. J. Photochem. Photobiol. C, 2003, 4:145-153

    3. [3]

      [3] Grtzel M. Inorg. Chem., 2005, 44(20):6841-6851

    4. [4]

      [4] Yella A, Lee H W, Tsao H N, et al. Science, 2011, 334:629-634

    5. [5]

      [5] LI Sheng-Jun(李胜军), LIN Yuan(林原), YANG Shi-Wei(杨 世伟), et al. Chinese J. Inorg. Chem.(无机化学学报), 2007, 23(11):1965-1969

    6. [6]

      [6] XU Bo(徐波), Wu Ji-Huai(吴季怀), FAN Le-Qing(范乐庆), et al. Chinese J. Inorg. Chem.(无机化学学报), 2008, 24(11): 1900-1906

    7. [7]

      [7] LI Li(李丽), ZHANG Gui-You(张贵友), CHEN Ren-Jie(陈人 杰), et al. Chem. J. Chinese Universities(高等学校化学学 报), 2009, 30(11):2247-2251

    8. [8]

      [8] Zhang L, Shi Y H, Peng S J, et al. J. Photochem. Photobiol. A: Chem., 2008, 197:260-265

    9. [9]

      [9] Wu S J, Han H W, Tai Q D, et al. J. Power Sources, 2008, 182:119-123

    10. [10]

      [10] Zhang X, Sutanto I, Taguchi T, et al. Sol. Energy Mater. Sol. C, 2003, 80:315-326

    11. [11]

      [11] Kim K E, Jang S R, Park J, et al. Sol. Energy Mater. Sol. C, 2007, 91:366-370

    12. [12]

      [12] Yang S, Kou H, Song S, et al. Colloids. Surf. A: Physicochem. Eng., 2009, 340:182-186

    13. [13]

      [13] Kim J T, Kim S H. Sol. Energy. Mater. Sol. C, 2011, 95:336-339

    14. [14]

      [14] Wang Z S, Yanagida M, Sayama K, et al. Chem. Mater., 2006, 18(12):2912-2916

    15. [15]

      [15] Park K H, Jin E M, Gu H B, et al. Mater. Lett., 2009, 63: 2208-2211

    16. [16]

      [16] Lee B K, Kim J J. Curr. Appl. Phys., 2009, 9:404-408

    17. [17]

      [17] XU Xue-Qing(徐雪青), XU Gang(徐刚). Sci. Sin. Chim.(中 国科学:化学), 2011, 41(1):37-43

    18. [18]

      [18] Morrison S R. Electrochemistry at Semiconductor and Oxid-ized Metal Elecreode. New York: Plenum Press, 1980:401

    19. [19]

      [19] Fabregat-Santiago F, Bisquert J, Garcia-Belmonte G, et al. Sol. Energ. Mater. Sol. C, 2005, 87:117-131

    20. [20]

      [20] Bisquert J. J. Phys. Chem. B, 2002, 106:325-333

    21. [21]

      [21] Bisquert J, Vikhrenko V S. J. Phys. Chem. B, 2004, 108(7): 2313-2322

  • 加载中
    1. [1]

      Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021

    2. [2]

      Yipeng Zhou ,  Chenxin Ran ,  Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096

    3. [3]

      Yixuan Gao ,  Lingxing Zan ,  Wenlin Zhang ,  Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091

    4. [4]

      Yongming Zhu ,  Huili Hu ,  Yuanchun Yu ,  Xudong Li ,  Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086

    5. [5]

      Jizhou Liu ,  Chenbin Ai ,  Chenrui Hu ,  Bei Cheng ,  Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006

    6. [6]

      Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431

    7. [7]

      Yong Zhou ,  Jia Guo ,  Yun Xiong ,  Luying He ,  Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109

    8. [8]

      Jinyao Du ,  Xingchao Zang ,  Ningning Xu ,  Yongjun Liu ,  Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039

    9. [9]

      Fanxin Kong ,  Hongzhi Wang ,  Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287

    10. [10]

      Shengbiao Zheng ,  Liang Li ,  Nini Zhang ,  Ruimin Bao ,  Ruizhang Hu ,  Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096

    11. [11]

      Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

    12. [12]

      Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    13. [13]

      Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO2 catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315

    14. [14]

      Hongye Bai ,  Lihao Yu ,  Jinfu Xu ,  Xuliang Pang ,  Yajie Bai ,  Jianguo Cui ,  Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096

    15. [15]

      Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO2/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193

    16. [16]

      Mengli Xu ,  Zhenmin Xu ,  Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305

    17. [17]

      Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

    18. [18]

      Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi2S4 supported by MnO2 nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170

    19. [19]

      Honglian Liang ,  Xiaozhe Kuang ,  Fuping Wang ,  Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073

    20. [20]

      Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(535)
  • HTML views(82)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return