Citation: DENG Long-Zheng, WU Feng, GAO Xu-Guang, XIE Hai-Ming, YANG Zhi-Wei. Effects of Coating Carbon Aluminum Foil on the Battery Performance[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 770-778. doi: 10.11862/CJIC.2014.047 shu

Effects of Coating Carbon Aluminum Foil on the Battery Performance

1.
1 School of Chemical Engineering and the Environment, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;

Corresponding author: WU Feng,
Received Date: 12 July 2013
Available Online: 25 September 2013
Fund Project: 国家973项目(No.2009CB220100)；动力电池及化学能源材料北京市高等学校工程研究中心开放基金资助课题(2013)；高性能二次动力电池及关键材料；技术的合作研究(No.2010DFB63370)；面向中美清洁能源合作的电动汽车前沿技术研究(No.2010DFA72760) (No.2009CB220100)；动力电池及化学能源材料北京市高等学校工程研究中心开放基金资助课题(2013)；高性能二次动力电池及关键材料；技术的合作研究(No.2010DFB63370)；面向中美清洁能源合作的电动汽车前沿技术研究(No.2010DFA72760)中央高校基本科研业务费(No.12QNJJ013)资助项目。 (No.12QNJJ013)

The LiFePO₄-based battery properties were studied by using aluminum foil current collector coated with a conductive carbon film. The main properties of LiFePO₄ type battery with 10 Ah capacity were also compared by using common aluminum foil and coating carbon aluminum foil (CCAF) from different providers. The results showed that the using of CCAF current collector not only can improve the cohesiveness between the cathode powder and the current collector but can effectively reduce the contact resistance of the cathode material and the current collector, so as to reduce the direct current resistance (DCR) of the battery, and improve the rate performance of the battery. Compared with using common aluminum foil, the DCR is reduced by about 65% with using the CCAF as current collector. But the specific discharge capacity of cathode material is reduced by 5~10 mAh·g^-1. And the 1^st efficiency is also reduced by 4%; At large discharge rate of 15C rate, the discharge capacity of the cell with using CCAF is more than about 15% in contrast to the cell with common aluminum foil as a current collector. And at 10Cdischarge rate, the voltage plateau increased by 0.3~0.4 V with CCAF; But the self-discharge ratio of cell with CCAF is higher at room temperature, and its recovery rate of the capacity is also higher; After 500 cycles, the cyclic capability of the cell with using CCAFcan increase by about 2% in contrast to the cell with the common aluminum foil as current collector. But the discharge property at low temperature is not improved by the use of CCAF as current collector.
- LiFePO₄ battery;coating carbon aluminum foil;current collector;rate performance;cycle performance
1. [1]
  [1] WU Yu-Ping(吴宇平), WAN Chun-Rong(万春荣), JIANG Chang-Yin(姜长印). Lithium Ion Secondary Batteries(锂离子二次电池). Beijing: Chemical Industry Publishing House, 2002.
2. [2]
  [2] Bruce P G. Solid State Ionics, 2008, 179(21/22/23/24/25/26): 752-760
3. [3]
  [3] Armand M, Tarascon J. M. Nature, 2008, 451(2):652-657
4. [4]
  [4] Ohzuku T, Brodd R. J. Power Sources, 2007, 174(2):449-456
5. [5]
  [5] Padhi A K, Nanjundaswamy K S, Goodenough J B. J. Electr-ochem Soc., 1997, 144(4):1188-1194
6. [6]
  [6] Whittingham M S. Chem. Rev., 2004, 104(10):4271-4301
7. [7]
  [7] Yamada A, Hosoya M, Chung S C, et al. J. Power Source, 2003, 119-121(1/2):232-238
8. [8]
  [8] Chen Z H, Dahn J R. J. Electrochem. Soc., 2002, 149(9): A1184-1189
9. [9]
  [9] Li Xiang-Yuan(李祥元). Thesis for the Masterate of Central South University(中南大学硕士论文). 2008.
10. [10]
  [10] Takahashi M, Tobishima S I, Takei K, et. Solid State Ionics, 2002, 148:283-289
11. [11]
  [11] Gao F, Tang Z Y. Electrochim. Acta, 2008, 53(15):5071-5075
12. [12]
  [12] XU Meng-Qing(许梦清), ZUO Xiao-Xi(左晓希), LI Wei-Shan(李伟善), et al. Chin. J. Power Source(电源技术), 2006, 30(1):14-17
13. [13]
  [13] Zhang S S, Xu K, Jow T R. J. Power Sources, 2006, 159(I): 702-707
14. [14]
  [14] Lian X Z, Ma Z F, Gong Q, et al. Electrochem. Commun., 2008, 10(5):691-694
15. [15]
  [15] XIE Xiao-Hua(谢晓华), CHEN Li-Bao(陈立宝), XIE Jing-Ying(解晶莹). Chin. J. Power Source(电源技术), 2007, 31 (7):576-577
16. [16]
  [16] TONG Hui(童汇), HU Guo-Hua(胡国华), HU Guo-Rong(胡国荣), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006, 22(12):2159-2164
17. [17]
  [17] Delacourt C, Wurm C, Laffont L, et al. Solid State Ionics, 2006, 177(3-4):333-341
18. [18]
  [18] ZHANG Qiu-Ming(张秋明), QIAO Yu-Qing(乔玉卿), ZHAO Min-Shou(赵敏寿), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(1):67-73
19. [19]
  [19] Ravet N, Abouimrane A, Armand M, et al. Nature, 2003, 2 (11):702~703
20. [20]
  [20] Zhuang D G, Zhao X B, Xie J, et al. Acta Physico-Chimica Sinica, 2006, 22(7):840-844
21. [21]
  [21] LIANG Feng(梁风), DAI Yong-Nian(戴永年), YAO Yao-Chun(姚耀春). Chinese J. Inorg. Chem.(无机化学学报), 2010, 26(9):1675-1679
22. [22]
  [22] Ong C W, Lin Y K, Chen J S. J. Electrochem. Soc., 2007, 154(6):A527-A533
23. [23]
  [23] TANG Zhi-Yuan(唐致远), GAO Fei(高飞) XUE Jian-Jun(薛建军). Chinese J. Inorg. Chem.(无机化学学报), 2007, 23(8): 1415-1420
24. [24]
  [24] YANG Shu-Ting(杨书廷), LIU Yu-Xia(刘玉霞), YIN Yan-Hong(尹艳红), et al. Chinese J. Inorg. Chem.(无机化学学报), 2007, 23(7):1165-1168
25. [25]
  [25] Dominko R, Gaber
26. [26]
  šcek M, Drofenik J, et al. J. Power Sources, 2003, 119/121:770-773
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