Citation: HAO Pei-Pei, CHEN Chang-Long, WEI Yu-Ling, MU Xiao-Hui. Tin Oxide Thin Films：Synthesis and Room Temperature Gas Sensing Properties[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 451-458. doi: 10.11862/CJIC.2014.046 shu

Tin Oxide Thin Films：Synthesis and Room Temperature Gas Sensing Properties

1.
1 School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;

Corresponding author: CHEN Chang-Long,
Received Date: 19 July 2013
Available Online: 15 October 2013
Fund Project:

Dense tin oxide films were solvothermally grown from the tin oxide seed films fabricated on glass substrates by sol-gel technique. The morphology and crystal structure of the tin oxide films were characterized by using scanning electron microscopy and X-ray diffraction techniques. The results reveal that the films are composed of cassiterite-type tin oxide crystals with size of 7~10 nm. The film quality can be improved significantly when the sodium dodecylbenzenesulfonate is used as the surfactant during the solvothermal reaction. The gas sensor, which is directly connected tin oxide films to the test circuits by using tweezers with special gripping surfaces, exhibits good sensing performance to nitrogen dioxide gas under mild testing conditions, i.e. room temperature, ambient pressure, and dry air background. The sensor can achieve a detection limit of 0.5 μL·L^-1.
- thin films;X-ray diffraction;semiconductors;gas sensor
1. [1]
  [1] Vomiero A, Bianchi S, Comini E, et al. Cryst. Growth Des., 2007,7:2500-2504
2. [2]
  [2] Ghimbeu C M, Lumbreras M, Siadat M, et al. Mat. Sci. Semicon. Proc., 2010,13:1-8
3. [3]
  [3] Tamiolakis I, Lykakis I N, Katsoulidis A P, et al. Chem. Mater., 2011,23:4204-4211
4. [4]
  [4] Kim Y J, Kim K H, Kang P, et al. Langmuir., 2012,28: 10620-10626
5. [5]
  [5] Gavagnin R, Biasetto L, Pinna F, et al. Appl. Catal. B: Environ., 2002,38:91-99
6. [6]
  [6] Zhu J J, Lu Z H, Aruna S T, et al. Chem. Mater., 2000,12: 2557-2566
7. [7]
  [7] Gardeshzadeh A R, Raissi B. Mat. Sci. Semicon. Proc., 2010, 13:151-155
8. [8]
  [8] Gong J W, Chen Q F, Fei W F, et al. Sens. Actuators B., 2004,102:117-125.
9. [9]
  [9] Ding J J, Yan X B, Li J, et al. ACS. Appl. Mater. Interfaces, 2011,3:4299-4305
10. [10]
  [10] Fang Y K, Lee J J. Thin Solid Films, 1989,169:51-56
11. [11]
  [11] Chacko S, Philip N S, Gopchandran K G, et al. Appl. Surf. Sci., 2008,254:2179-2186
12. [12]
  [12] Ghosh S, Khan G G, Mandal K. ACS Appl. Mater. Interfaces, 2012,4:2048-2056
13. [13]
  [13] Pan J, Song X F, Zhang J, et al. J. Phys. Chem. C, 2011, 115:22225-22231
14. [14]
  [14] Chen Z W, Pan D Y, Zhao B, et al. ACS Nano., 2010,4: 1202-1208
15. [15]
  [15] da Silva V D L, de Andrade A, Scalvi L V A, et al. Mater. Chem. Phys., 2012,134:994-1000
16. [16]
  [16] Mishra S, Ghanshyam C, Ram N, et al. Bull. Mater. Sci., 2002,25:231-234
17. [17]
  [17] Rella R, Serra A, Siciliano P, et al. Sens. Actuators B, 1997, 44:462-467
18. [18]
  [18] Acciarri M, Canevali C, Mari C M, et al. Chem. Mater., 2003,15:2646-2650
19. [19]
  [19] Gong S P, Xia J, Liu J Q, et al. Sens. Actuators B, 2008, 134:57-61
20. [20]
  [20] Rajpure K Y, Kusumade M N, Neumann-Spallart M N, et al. Mater. Chem. Phys., 2000,64:184-188
21. [21]
  [21] Ramos L, Lubensky T C, Dan N, et al. Science, 1999,286: 2325-2328
22. [22]
  [22] Jang J H, Park J H, Oh S G. J. Ceram. Process. Res., 2009, 10:783-790
23. [23]
  [23] Chen C L, Wei Y L, Sun G X, et al. Chem. Asian J., 2012, 7:1018-1025
24. [24]
  [24] Gyger F, Hübner M, Feldmann C, et al. Chem. Mater., 2010,22:4821-4827
25. [25]
  [25] DArienzo M, Armelao L, Cacciamani A, et al. Chem. Mater., 2010,22:4083-4089
26. [26]
  [26] Chen C L, Wei Y L, Chen D R, et al. Mater. Chem. Phys., 2011,125:299-304
27. [27]
  [27] Tocchetto A, Glisenti A. Langmuir., 2000,16:2642-2650
28. [28]
  [28] Sun C T, Xue D F. J. Phys. Chem C., 2013,117:19146- 19153
29. [29]
  [29] Michiya M, Serizawa, Kishida A, et al. Bioconjugate Chem., 2002,13:23-28
1. [1]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
2. [2]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
3. [3]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
4. [4]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
5. [5]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
6. [6]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
7. [7]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
8. [8]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
9. [9]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
10. [10]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
11. [11]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
12. [12]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
13. [13]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
14. [14]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
15. [15]
  Hongwei Ma , Fang Zhang , Hui Ai , Niu Zhang , Shaochun Peng , Hui Li . Integrated Crystallographic Teaching with X-ray,TEM and STM. University Chemistry, 2024, 39(3): 5-17. doi: 10.3866/PKU.DXHX202308107
16. [16]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
17. [17]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
18. [18]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
19. [19]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
20. [20]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1045)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142