Advanced Search

Citation: SUN Li-Ping, ZHAO Hui, WANG Wen-Xue, LI Qiang, HUO Li-Hua. Electrochemical Performance of La2CuO4 Nanotube Materials Prepared via Electrospinning Method[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 757-762. doi: 10.11862/CJIC.2014.044 shu

Electrochemical Performance of La2CuO4 Nanotube Materials Prepared via Electrospinning Method

  • 1.

    Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

  • Corresponding author: ZHAO Hui, 
  • Received Date: 11 June 2013
    Available Online: 10 October 2013

    Fund Project: 国家自然科学基金(No.51072048,51102083)；黑龙江省杰出青年科学基金(JC201211) (No.51072048,51102083)；黑龙江省杰出青年科学基金(JC201211)黑龙江省自然科学基金(B201107)资助项目。 (B201107)

  • La2CuO4 nanotubes are successfully synthesized by electro-spinning technology. The structure and morphology of the materials are characterized by XRD, TG-DTA and SEM, respectively. The results show that La2CuO4 nanotubes with an average diameter of 150 nm are obtained after sintering at 700 ℃ for 2 h. The La2CuO4 nanotube forms sufficient connection with each other, and good contact with the electrolyte after sintering at 900 ℃ for 0.5 h. Comparing the results obtained by Electrochemical Impedance Spectroscopy (EIS), it is clearly observed that the nanotube cathode exhibits superior performance than the powder cathode. The area specific resistance (ASR) of the nanotube cathode is 1.03 Ω·cm2 at 700 ℃ in air, whereas for the powder one with the same composition, the ASRis 1.61 Ω·cm2. The oxygen partial pressure measurement indicates that the charge transfer process is the rate-limiting step of the nanotube electrode reactions.
  • 加载中
    1. [1]

      [1] Liu M L, Lynch M E, Blinn K, et al. Materialstoday, 2011, 14(11):534-546

    2. [2]

      [2] Zhou W, Ran R, Shao Z P. J. Power Sources, 2009, 192:231-246

    3. [3]

      [3] Huang J B, Xie F C, Wang C, et al. Int. J. Hydrogen Energy, 2012, 37:877-883

    4. [4]

      [4] Tietz F, Mai A, Stver D. Solid State Ionics, 2008, 179:1509-1515

    5. [5]

      [5] Kivi I, Mller P, Kurig H, et al. Electrochem. Commun., 2008, 10:1455-1458

    6. [6]

      [6] Zhu X B, Ding D, Li Y Q, et al. Int. J. Hydrogen Energy, 2013, 38:5375-5382

    7. [7]

      [7] Gao Z, Mao Z Q, Wang C, et al. Int. J. Hydrogen Energy, 2011, 36:7229-7233

    8. [8]

      [8] Ortiz-Vitoriano N, Ruiz de Larramendi I, Ruiz de Larramendi I J, et al. J. Power Sources, 2009, 192:63-69

    9. [9]

      [9] Suzuki T, Takahashi Y, Hamanoto K, et al. Int. J. Hydrogen Energy, 2011, 36:10998-11003

    10. [10]

      [10] Sun L P, Zhao H, Li Qiang, et al. Int.J. Hydrogen Energy, 2011, 36:12555-12560

    11. [11]

      [11] Li Q, Sun L P, Huo L H, et al. J. Solid State Electrochem., 2012, 16:1169-1174

    12. [12]

      [12] Li Q, Sun L P, Huo L H, et al. J. Power Sources, 2011, 196: 1712-1716

    13. [13]

      [13] Pinedo R, Ruiz de Larramendi I, Jimenez de Aberasturi D, et al. J. Power Sources, 2011, 196:4174-4180

    14. [14]

      [14] Sacanell J, Bellino M G, Lamas D G, et al. Physica B, 2007, 398:341-343

    15. [15]

      [15] Sacanell J, Leyva A G, Bellino M G, et al. J. Power Sources, 2010, 195:1786-1792

    16. [16]

      [16] Zhang N Q, Li J, He Z L, et al. Electrochem. Commun., 2011, 13:570-573

    17. [17]

      [17] Sun L P, Li Q, Zhao H, et al. Int. J. Hydrogen Energy, 2012, 37:11955-11962

    18. [18]

      [18] Gao L Z, Chua H T, Kawi S. J. Solid State Chemistry, 2008, 181:2804-2807

    19. [19]

      [19] Yuan J, Dai H X, Zhang L, et al. Catal. Today, 2011, 175: 209-215

    20. [20]

      [20] Chen L, Dong C, Huang Y Z, et al. Solid State Commun, 2000, 114:107-111

    21. [21]

      [21] Hirayama T, Nakagava M, Oda Y. Solid State Sciences, 2000, 113:121-124

    22. [22]

      [22] Zhao H, Huo L H, Gao S. J. Power Sources, 2004, 125:149-154

    23. [23]

      [23] Bebelis S, Kotsionopoulos N, Mai A, et al. Solid State Ionics, 2006, 177:1843-1848

    24. [24]

      [24] Zhan G, Liu X M, Bergman B, et al. J. Power Sources, 2011, 196:9195-9203

    25. [25]

      [25] Kim J D, Kim G D, Moon J W, et al. Solid State Ionics, 2001, 143:379-389

  • 加载中
    1. [1]

      Doudou Qin ,  Junyang Ding ,  Chu Liang ,  Qian Liu ,  Ligang Feng ,  Yang Luo ,  Guangzhi Hu ,  Jun Luo ,  Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

    2. [2]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    3. [3]

      Xiufang Wang ,  Donglin Zhao ,  Kehua Zhang ,  Xiaojie Song . “Preparation of Carbon Nanotube/SnS2 Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025

    4. [4]

      Ji-Quan Liu ,  Huilin Guo ,  Ying Yang ,  Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031

    5. [5]

      Tong Zhou ,  Jun Li ,  Zitian Wen ,  Yitian Chen ,  Hailing Li ,  Zhonghong Gao ,  Wenyun Wang ,  Fang Liu ,  Qing Feng ,  Zhen Li ,  Jinyi Yang ,  Min Liu ,  Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005

    6. [6]

      Qi Li ,  Pingan Li ,  Zetong Liu ,  Jiahui Zhang ,  Hao Zhang ,  Weilai Yu ,  Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030

    7. [7]

      Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

    8. [8]

      Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023

    9. [9]

      Xin Zhou ,  Zhi Zhang ,  Yun Yang ,  Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi2MoO6 Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008

    10. [10]

      Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402

    11. [11]

      Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    12. [12]

      Zhenming Xu ,  Mingbo Zheng ,  Zhenhui Liu ,  Duo Chen ,  Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO4 Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022

    13. [13]

      Shengbiao Zheng ,  Liang Li ,  Nini Zhang ,  Ruimin Bao ,  Ruizhang Hu ,  Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096

    14. [14]

      Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047

    15. [15]

      Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

    16. [16]

      Jianbao Mei ,  Bei Li ,  Shu Zhang ,  Dongdong Xiao ,  Pu Hu ,  Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na3.5-xMn0.5V1.5-xZrx(PO4)3/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023

    17. [17]

      Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086

    18. [18]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    19. [19]

      Yinyin Qian ,  Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051

    20. [20]

      Fengqiao Bi ,  Jun Wang ,  Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(268)
  • HTML views(15)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return