Citation: CHEN Sheng, HAN Jian-Lin*, LI Gui-Gen, PAN Yi*. K₂CO₃/Ni(OAc)₂ Catalyzed Aminobromination of β-Methyl-β-nitrostyrenes with Benzamide/N, N-Dibromobenzamide as Nitrogen/Bromine Source[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 213-219. doi: 10.11862/CJIC.2014.042 shu

K₂CO₃/Ni(OAc)₂ Catalyzed Aminobromination of β-Methyl-β-nitrostyrenes with Benzamide/N, N-Dibromobenzamide as Nitrogen/Bromine Source

CHEN Sheng ¹ ,
HAN Jian-Lin* ^1,2 ,
LI Gui-Gen ^2,3 ,
PAN Yi* ^1,2

1.
1 School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination, Nanjing University, Nanjing 210093, China;

Received Date: 24 June 2013
Available Online: 24 October 2013
Fund Project:

An efficient and facile aminobromination reaction of β-methyl-β-nitrostyrenes with PhCONH₂/PhCONBr₂ as nitrogen/bromine source has been developed, which could tolerate a wide scope of substrates with good chemical yield and diastereoselectivity. This aminobrominaiton system uses metal salt and base as the co-catalyst, which is different from our previous reported systems.
- aminobromination;benzamide;β-methyl-β-nitrostyrenes;haloamines,
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K2CO3/Ni(OAc)2 Catalyzed Aminobromination of β-Methyl-β-nitrostyrenes with Benzamide/N, N-Dibromobenzamide as Nitrogen/Bromine Source

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通讯作者: 陈斌, bchen63@163.com

K₂CO₃/Ni(OAc)₂ Catalyzed Aminobromination of β-Methyl-β-nitrostyrenes with Benzamide/N, N-Dibromobenzamide as Nitrogen/Bromine Source