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Citation: XIAN Liang, WANG Hao, LIU Ying, CHEN Sheng-Kai, MA Ya-Juan, ZHANG Jin-Rong. Component Assembly Synthesis, Structure and Electro-Catalysis of Cu4 Cluster Compound[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 557-562. doi: 10.11862/CJIC.2014.032 shu

Component Assembly Synthesis, Structure and Electro-Catalysis of Cu4 Cluster Compound

  • 1.

    1 Chemical Engineering Institute, Northwest University for Nationalities, Lanzhou 730030, China;

  • Received Date: 21 June 2013
    Available Online: 23 October 2013

    Fund Project: 甘肃省自然科学基金(No.096RJZA087) (No.096RJZA087)中央高校基本科研业务费专项资金(No.ZYZ2012066) (No.ZYZ2012066)西北民族大学国家大学生创新创业训练 计划(201310742005)资助项目。 (201310742005)

  • A Cu4 cluster compound, Cu4(HL)4·2H2O, (H2L=N-ethoxycarbonyl-N'-o-nitrophenylthiourea), was synthesized in the way of component assembly. Structures and chemical compositions of the cluster compound and its corresponding component were determined by single crystal X-ray diffraction analysis, elemental analysis, FTIR, 1H NMR etc., and its electro-catalysis was also characterized. The experimental results show that the core of the cluster compound is composed by four Cu(I) linked with M-M bonds, and the Cu(I) are coordinated by 4 thiourea ligands with thiocarbonyl sulfur atom and nitrogen atom, respectively. DPV Electro-catalysis shows that the cluster compound is of high O2 catalysis activation. CCDC: 945182, Cu(H2L)2Cl·H2O; 602859, Cu4(HL)4·2H2O.
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