Citation:
XIAN Liang, WANG Hao, LIU Ying, CHEN Sheng-Kai, MA Ya-Juan, ZHANG Jin-Rong. Component Assembly Synthesis, Structure and Electro-Catalysis of Cu4 Cluster Compound[J]. Chinese Journal of Inorganic Chemistry,
;2014, 30(3): 557-562.
doi:
10.11862/CJIC.2014.032
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A Cu4 cluster compound, Cu4(HL)4·2H2O, (H2L=N-ethoxycarbonyl-N'-o-nitrophenylthiourea), was synthesized in the way of component assembly. Structures and chemical compositions of the cluster compound and its corresponding component were determined by single crystal X-ray diffraction analysis, elemental analysis, FTIR, 1H NMR etc., and its electro-catalysis was also characterized. The experimental results show that the core of the cluster compound is composed by four Cu(I) linked with M-M bonds, and the Cu(I) are coordinated by 4 thiourea ligands with thiocarbonyl sulfur atom and nitrogen atom, respectively. DPV Electro-catalysis shows that the cluster compound is of high O2 catalysis activation. CCDC: 945182, Cu(H2L)2Cl·H2O; 602859, Cu4(HL)4·2H2O.
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