Citation: ZHANG Rui, XING Yong-Heng, TIAN Chun-Yan, WANG Xuan, GUAN Qing-Lin, HOU Ya-Nan, WANG Xin-Yu, BAI Feng-Ying. Synthesis, Structures and Spectrum Study of Copper Complexes with Triazine-Pyrazole Derivativ[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 264-270. doi: 10.11862/CJIC.2014.031 shu

Synthesis, Structures and Spectrum Study of Copper Complexes with Triazine-Pyrazole Derivativ

1.
1 College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China;

Corresponding author: XING Yong-Heng, BAI Feng-Ying,
Received Date: 27 April 2013
Available Online: 28 October 2013
Fund Project:

Two copper complexes: Cu₂(mpz^*eaT-EtO)₂(N₃)₂Cl₂ (1) and Cu₂(mpz^*eaT-MeO)₂(N₃)₄ (2) (mpz^*eaT-EtO=2-(3,5-dimethyl pyrazole)-4-ethanol-6-diethylamine-1,3,5-triazine, mpz^*eaT-MeO=2-(3,5-dimethyl pyrazole)-4-methanol-6-diethylamine-1,3,5-triazine) were synthesized with the tridentate chelate triazine-pyrazole derivative 2,4-di(3,5-dimethyl pyrazole)-6-diethylamine-1,3,5-triazine (bpz^*eaT) in the anhydrous ethanol and anhydrous methanol system, respectively. The complexes were characterized by elemental analysis, IR spectroscopy, UV spectrum thermal gravimetric analyses and single crystal X-ray diffraction. The crystal of complex 1 belongs to triclinic system, Space group P1, a=0.994 9(2) nm, b=1.021 6(2) nm, c=1.148 0(2) nm, α=115.11(3)°, β=106.99(3)°, γ=100.39(3)°, V=0.9460(3) nm³, Z=1; The crystal of complex 2 belongs to Monoclinic, Space group P2_1/c, a=1.546 4(5) nm, b=1.400 8(5) nm, c=0.890 5(3) nm, β=103.227(5)°, V=1.877 9(10) nm³, Z=2. Structural analyses have revealed that the center copper atom is five-coordinated to form distorted pyramidic geometry. CCDC: 935290, 1; 935291, 2.
- copper complex;1,3,5-triazine derivative;synthesis;structure;spectrum
1. [1]
  [1] Svetlana M, Anthony V, Kunjal P, et al. Eur. J. Chem., 2012,3(1):1-9
2. [2]
  [2] Wang X, Xing Y H, Bai F Y, et al. RSC Adv., 2013,3(36): 16021-16033
3. [3]
  [3] WANG Xin-Yu(王欣羽), LI Zhen(李桢), SUN Qiao(孙巧), Chinese J. Inorg. Chem.(无机化学学报), 2012,28:483-490
4. [4]
  [4] WEI Dong-Ming(魏东明), DONG Bin(董斌), LI Zhang-Peng (李章鹏), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011,27:891-897
5. [5]
  [5] Potapov A S, Nudnova E A, Domina G A, et al. Dalton Trans., 2009,23:4488-4498
6. [6]
  [6] Dias H V R, Singh S, Campana C F. Inorg. Chem., 2008,47: 3943-3945
7. [7]
  [7] Xing Y H, Zhang Y H, Xu Y T, et al. Chin. Sci. Bull., 2006, 51:2189-2196
8. [8]
  [8] Fujimori T, Yamada S, Yasui H, et al. J. Biol. Inorg. Chem., 2005,10:831-841
9. [9]
  [9] Morimoto K M, Makino K, Yamamoto S, et al. Adv. Heterocycl. Chem., 1990,27:807-810
10. [10]
  [10] Mukherjee R. Coord. Chem. Rev., 2000,203:151-218
11. [11]
  [11] Gupta S, Barik A K, Pal S, et al. Polyhedron, 2007,26:133- 141
12. [12]
  [12] Carrion M C, Guerrero A, Jalon F A, et al. Inorg. Chem., 2003,42:885-895
13. [13]
  [13] Weng Y Q, Cao M L, Ye B H. Inorg. Chem. Commun., 2011,14:243-246
14. [14]
  [14] WANG Xin-Yu(王欣羽), XING Na(邢娜), SONG Ge(宋鸽), et al. Chem. J. Chinese Universities(高等学校化学学报), 2012,33(6):1151-1157
15. [15]
  [15] Guerrero A, Jalón F A, Manzano B R, et al. Eur. J. Inorg. Chem., 2004:549-556
16. [16]
  [16] Jorge M, Carolina A, Andrés V, et al. Inorg. Chim. Acta, 2011,374:637-642
17. [17]
  [17] BAI Feng-Ying(白凤英), LI Xiao-Tian(李晓天), ZHU Guang -Shan(朱广山), et al. Chem. J. Chinese Universities(高等学校化学学报), 2009,30(10):1919-1924
18. [18]
  [18] Quińonero D, Deyá P M, Carranza M P, et al. Dalton Trans., 2010,39:794-806
19. [19]
  [19] Sheldrick G M. SADABS, Program for Empirical Absorption Correction for Area Detector Data, University of Göttingen, Göttingen, Germany, 1996.
20. [20]
  [20] Sheldrick G M. SHELX-97, Program for Crystal Structure Analysis, University of Gottingen, Gottingen, Germany, 1997.
21. [21]
  [21] Fujisawa K, Iwamoto H, Tobita K, et al. Inorg. Chim. Acta, 2009,362:4500-4509
22. [22]
  [22] Addison A W, Rao T N, Reedijik J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
3. [3]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
4. [4]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
5. [5]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
6. [6]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
7. [7]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
8. [8]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
11. [11]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
12. [12]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
13. [13]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
14. [14]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
15. [15]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
16. [16]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
19. [19]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
20. [20]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075

Get Citation

PDF

XML

Metrics

PDF Downloads(381)
Abstract views(1121)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142