Citation: WANG Jing-Lin, JIAO Yong, YANG Bin-Sheng. Supramolecule Assembled from Sulfonyl Hydrazone Ni(Ⅱ) Complex via π…π and C-H…π Interactions[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 411-418. doi: 10.11862/CJIC.2014.030 shu

Supramolecule Assembled from Sulfonyl Hydrazone Ni(Ⅱ) Complex via π…π and C-H…π Interactions

1.
1 Department of Chemistry, Changzhi University, Changzhi, Shanxi 046011, China;

Corresponding author: YANG Bin-Sheng,
Received Date: 24 April 2013
Available Online: 28 July 2013
Fund Project:

An intriguing supramolecular complex NiL₂ (HL: (E)-4-methyl-N'-(pyridin-2-ylmethylene) benzenesul-fonohydrazide) with novel Ni-O (sulfonyl) coordination bond has been synthesized and characterized. The structural studies indicate that two types of dimers are assembled via intermolecular offset face-to-face π…π stacking (OFF) and edge-to-face C-H…π (EF) interactions between two pyridyl rings in the crystal structure of NiL₂. Each dimer exists in two enantiomeric forms. The DFTcalculation indicates that the parallel fourfold aryl embrace (P4AE) interactions, with one OFFinteraction and two EFinteractions, are stronger than that of only OFF, which can be called synergistic effects. The spectral studies show that the ratio of Ni(Ⅱ) to HLis 1:2 in this compound. CCDC: 773667.
- sulfonyl hydrazone;Ni(Ⅱ) complex;crystal structure;π…π interaction;DFT calculation
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