Citation: BAI Ming, ZHANG Yan, WAN Pei-Hong, ZHANG Chong-Xi. Six Phthalocyaninato Zinc(Ⅱ) Complexes：Synthesis via Cross-Condensation of Two Phthalonitriles, Spectroscopy and Electrochemistry[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 371-378. doi: 10.11862/CJIC.2014.029 shu

Six Phthalocyaninato Zinc(Ⅱ) Complexes：Synthesis via Cross-Condensation of Two Phthalonitriles, Spectroscopy and Electrochemistry

1.
Marine College, Shandong University, Weihai, 264209

Corresponding author: BAI Ming,
Received Date: 7 June 2013
Available Online: 2 September 2013
Fund Project:

Cross-condensation of two different phthalonitriles, namely 4,5-bis[(4-methyloxycarbonyl)phenoxy]phthalonitrile (1) and 4-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}phthalonitrile(2), in the presence of Zn(OAc)₂·2H₂Oand 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) followed by transesterification in refluxing n-pentanol afforded six phthalocyaninato zinc(Ⅱ) complexes modulated with different numbers of pentyloxycarbonyl and/or triethylene glycol monomethyl ether groups. Simple silica-gel column chromatography leads to the successful separation of all these six compounds, namely Zn[Pc(BP)₄](3), Zn[Pc(BP)₃(TEG)](4), Zn[Pc(BP)₂(TEG)₂]-opp(5), Zn[Pc(BP)₂(TEG)₂]-adj(6), Zn[Pc(BP)(TEG)₃](7), and Zn[Pc(TEG)₄](8). In addition, the six complexes have been characterized with elemental analysis, MALDI-TOFmass, UV-Vis spectroscopy, ¹H NMR, and 2D COSYspectroscopy. The electrochemical properties have also been investigated.
- cross-condensation;esterification;phthalocyanines;NMR spectroscopy;electrochemical property
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沈阳化工大学材料科学与工程学院沈阳 110142