Advanced Search

Citation: YU Jian-Yan, SONG Shao-Fei, YE Su-Fang, XIAO Qiang, ZHONG Yi-Jun, YE Xiang-Rong, ZHU Wei-Dong. Selective Hydrogenation of Cinnamaldehyde on Magnetically Recyclable Pt/Fe3O4-MCNT Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 271-276. doi: 10.11862/CJIC.2014.025 shu

Selective Hydrogenation of Cinnamaldehyde on Magnetically Recyclable Pt/Fe3O4-MCNT Catalysts

  • 1.

    1 Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China;

  • Corresponding author: XIAO Qiang, 
  • Received Date: 4 May 2013
    Available Online: 15 July 2013

    Fund Project:

  • A multi-step method was adopted to prepare a magnetic Pt/Fe3O4-MCNT catalyst by loading as-prepared Fe3O4 and Pt nanoparticles onto multi-walled carbon nanotubes (MCNT). The structure and magnetic properties of the prepared Pt/Fe3O4-MCNT catalyst were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), superconducting quantum interference device (SQUID), and thermogravimetry-differential thermal analysis (TG-DTA). The results reveal that the as-prepared Fe3O4 and Pt nanoparticles are well dispersed on the MCNT. Additionally, the magnetic measurements show that both fresh and recycled magnetic Pt/Fe3O4-MCNT catalysts display excellent superparamagnetic properties at room temperature. The selective hydrogenation of cinnamaldehyde to cinnamyl alcohol was performed on the magnetic Pt/Fe3O4-MCNT catalyst, showing a superior activity in the hydrogenation of the C=O bond. A selectivity of 96% to cinnamyl alcohol can be achieved at a cinnamaldehyde conversion of about 50%. The reason of the good selectivity probably ascribes to the high dispersion of the uniformed Pt particles on the MCNT. Additionally, the catalyst can be easily recovered from the reaction medium under the external magnetic field and maintain its catalytic properties after used for several recycles.
  • 加载中
    1. [1]

      [1] XU Ke-Xun(徐克勋). Handbook of Fine Organic Industrial Chemicals and Intermediates(精细有机化工原料及中间体 手册). Beijing: Chemical Industry Press, 1998:110

    2. [2]

      [2] Rylander P N. Catalytic Hydrogenation in Organic Synthesis New York: Academic Press, 1979.

    3. [3]

      [3] Delbecq F, Sautet P. J. Catal., 1995,52:217-236

    4. [4]

      [4] Galvagno S, Capannelli G. J. Mol. Catal. A, 1991,64:237-246

    5. [5]

      [5] Gutierrez V, Alvarez M, Volpe M. Appl. Catal. A: Gen., 2012,437:72-78

    6. [6]

      [6] Neri G, Arrigo I, Corigliano F, et al. Catal. Lett., 2011,141: 1590-1597

    7. [7]

      [7] Plomp A J, Vuori H, Krause A O I, et al. Appl. Catal. A: Gen., 2008,351:9-15

    8. [8]

      [8] Zheng R Y, Porosoff M D, Weiner J L, et al. Appl. Catal. A: Gen., 2012,419:126-132

    9. [9]

      [9] WANG Hua-Yu(王华瑜), ZHANG Chang-Bin(张长斌), HE Hong(贺泓), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2010,26(7):1873-1878

    10. [10]

      [10] Abu-Reziq R, Wang D, Post M, et al. Adv. Synth. Catal., 2007,349:2145-2150

    11. [11]

      [11] WU Ding-Ping(伍定萍), XU Ling(徐玲), XIAO Qiang(肖强), et al. J. Mol. Catal.(China)(分子催化), 2012,26(4):308-313

    12. [12]

      [12] XU Ling(徐玲), SHEN Xiao-Xu(沈晓旭), XIAO Qiang(肖 强), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2011,27 (8):956-1960

    13. [13]

      [13] LIU Zi-Li (刘自力), LIU Qi-Hai (刘其海),WANG Peng-Hua (汪鹏华), et al. J. Mol. Catal.(China)(分子催化), 2007,21(2): 15-121

    14. [14]

      [14] MENG Qi(孟琦), LI He-Xing(李和兴). J. Mol. Catal.(分子 催化), 2009,23(1):56-61

    15. [15]

      [15] Dhanagopal M, Duraiswami D, Valentine R A, et al. J. Catal. (China)(催化学报), 2010,31:1200-1208

    16. [16]

      [16] Guo Z, Chen Y T, Li L S, et al. J. Catal., 2010,276:314-326

    17. [17]

      [17] Plomp A J, Schubert T, Storr U, et al. Top. Catal., 2009,52: 424-430

    18. [18]

      [18] Cao X M, Burch R, Hardacre C, et al. J. Phys. Chem. C, 2011,115:19819-19827

    19. [19]

      [19] ZHENG Hai-Ying(郑海影), XIE Guan-Qun(谢冠群), WANG Xiao-Xia(王晓霞), et al. Acta Phys.-Chim. Sin.(物理化学学 报), 2010,26(12):3273-3277

    20. [20]

      [20] ZHAO Lei(赵磊), XU Xiang-Sheng(许响生), ZHANG Kai- Chao(张凯超), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2012,28:923-927

    21. [21]

      [21] YU Tie-Ming(俞铁铭), LI Yan(李艳), XU Xiao-Ling(徐晓 玲), et al. J. Chem. Ind. Eng.(China)(化工学报), 2009,60: 1668-1672

    22. [22]

      [22] Wu B H, Huang H Q, Yang J, et al. Angew. Chem. Int. Ed., 2012,51:3440-3443

    23. [23]

      [23] Claus P, Bruckner A, Mohr C, et al. J. Am. Chem. Soc., 2000,122(46):11430-11439

    24. [24]

      [24] Zhou W J, Lee J Y. J. Phys. Chem. C, 2008,112(10):3789- 3793

    25. [25]

      [25] Ruta M, Semagina N, Kiwi-Minsker L. J. Phys. Chem. C, 2008,112(35):13635-13641

    26. [26]

      [26] TANG Ya-Wen(唐亚文), BAO Jian-Chun(包建春), ZHOU Yi-Ming(周益明), et al. Chinese J. Inorg. Chem.(无机化学 学报), 2003,19(8):905-908

    27. [27]

      [27] YAO Yan-Li(姚彦丽), ZHANG Dai(张岱), XIA Xing-Hua (夏兴华). Chinese J. Inorg. Chem.(无机化学学报), 2004,20 (5):905-908

    28. [28]

      [28] FU Xiao-Bo(傅小波), YU Hao(余皓), PENG Feng(彭峰), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006,22(6): 1148-1157

    29. [29]

      [29] Giroir-Fendler A, Richard D, Gallezot P. Catal. Lett., 1990, 5:175-182

    30. [30]

      [30] Cai W, Wan J Q. J. Colloid Interface Sci., 2007,305:366-370

    31. [31]

      [31] Mazumder V, Sun S H. J. Am. Chem. Soc., 2009,131(13): 4588-4589

  • 加载中
    1. [1]

      Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

    2. [2]

      Junjie Zhang ,  Yue Wang ,  Qiuhan Wu ,  Ruquan Shen ,  Han Liu ,  Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

    3. [3]

      Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

    4. [4]

      Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102

    5. [5]

      Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

    6. [6]

      Shihui Shi ,  Haoyu Li ,  Shaojie Han ,  Yifan Yao ,  Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002

    7. [7]

      Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

    8. [8]

      Wei Zhong ,  Dan Zheng ,  Yuanxin Ou ,  Aiyun Meng ,  Yaorong Su . K原子掺杂高度面间结晶的g-C3N4光催化剂及其高效H2O2光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

    9. [9]

      Shuang Yang ,  Qun Wang ,  Caiqin Miao ,  Ziqi Geng ,  Xinran Li ,  Yang Li ,  Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044

    10. [10]

      Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO2 cycloaddition over W18O49/NH2-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

    11. [11]

      Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

    12. [12]

      Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064

    13. [13]

      Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402

    14. [14]

      Qianqian Zhong ,  Yucui Hao ,  Guotao Yu ,  Lijuan Zhao ,  Jingfu Wang ,  Jian Liu ,  Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013

    15. [15]

      Yunhao Zhang ,  Yinuo Wang ,  Siran Wang ,  Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083

    16. [16]

      Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355

    17. [17]

      Xilin Zhao ,  Xingyu Tu ,  Zongxuan Li ,  Rui Dong ,  Bo Jiang ,  Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106

    18. [18]

      Weihan Zhang ,  Menglu Wang ,  Ankang Jia ,  Wei Deng ,  Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043

    19. [19]

      Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002

    20. [20]

      Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt3M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188

Get Citation
PDF
XML
Metrics
  • PDF Downloads(137)
  • Abstract views(694)
  • HTML views(6)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return