Citation: PAN Rui-Long, WANG Hui, ZOU Yan, ZHANG Jun, LI Sheng-Li, WU Jie-Ying, TIAN Yu-Peng. Synthesis, Optical and Electrical Properties of the Ferrocene-cyano-carboxylic Acid Ligand and Its Organotin Complex[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 251-256. doi: 10.11862/CJIC.2014.020 shu

Synthesis, Optical and Electrical Properties of the Ferrocene-cyano-carboxylic Acid Ligand and Its Organotin Complex

1.
College of Chemistry & Chemical Engineering, Key Laboratory of Functional Inorganic Material Chemistry of Anhui University, Hefei 230039, China

Corresponding author: LI Sheng-Li, WU Jie-Ying,
Received Date: 25 March 2013
Available Online: 7 September 2013
Fund Project:

A (D-π-A) ligand, ferrocene-cyano-carboxylic acid, was synthesized, and it was assembled with organotins, dibutyltin oxide (n-Bu₂SnO), to obtain a novel ferrocene organotin coordination compond. They have been characterized by ¹H NMR, ¹¹⁹Sn NMR, IR, FT-IR, UV-Vis and elemental analysis. The crystal structure of complex has been determined by X-ray single crystal diffraction. Their electrochemical and two-photon absorption properties were systematically studied using cyclic voltammetry and Z-scan determination method. The results indicated that the complex is more difficult to be oxidized and possess a larger two-photon absorption cross section than its ligand. CCDC: 921958.
- ferrocene-cyano-carboxylic acid;organotin complex;crystal structure;optical and electrical properties;two-photon absorption cross section
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沈阳化工大学材料科学与工程学院沈阳 110142