Citation: HUANG Qing-Li, ZHU Xia-Shi. Synthesis and Characterization of SERS-Active Silver Nanomaterial[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 442-450. doi: 10.11862/CJIC.2014.019 shu

Synthesis and Characterization of SERS-Active Silver Nanomaterial

HUANG Qing-Li ,
ZHU Xia-Shi ^,

1.
College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225009, China

Corresponding author: ZHU Xia-Shi,
Received Date: 8 July 2013
Available Online: 12 September 2013
Fund Project:

Three-dimensional (3D) hierarchical silver nanomaterials (HSNs) were prepared by a simple surfactant-free wet-chemical method at room temperature. The as-prepared HSNs exhibit spherical morphologies and are constructed with many 2Dnanoflakes as building blocks. Field emission scanning electron microscopy (FESEM) studies show that diammonium 2-(carboxymethyl)-2-hydroxysuccinate (diammonium hydrogen citrate) (C₆H₁₄N₂O₇) plays a key role in the formation of such HSNs. X-ray diffraction (XRD) and transmission electron microscopy (TEM) results confirm the formation of HSNs. The optical properties and surface-enhanced Raman scattering (SERS) effect were also investigated by UV-Vis and Raman spectra. The HSNs could be served as highly sensitive surface-enhanced Raman scattering (SERS) substrates for chemical detection.
- wet-chemical method;silver;surface-enhanced Raman scattering (SERS);Rhodamine (R6G and RB)
1. [1]
  [1] Qiu R, Wang P, Zhang D, et al. Colloids Surf. A: Physico- chem. Eng. Aspects, 2011,377:144-149
2. [2]
  [2] CAO Xiao-Feng(曹霄峰), ZHANG Lei(张雷), LI Zhao-Qian (李兆乾), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(11):2373-2378
3. [3]
  [3] ZHANG Pei-Pei(张培培), HUANG Jian-Feng(黄剑锋), CAO Li-Yun(曹丽云), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(2):291-296
4. [4]
  [4] Cao H Q, Zheng H, Yin J F, et al. J. Phys. Chem. C, 2010, 114:17362-17368
5. [5]
  [5] ZHANG Jiang(章剑), ZHANG Yang(章燕), SHEN Yu-Hua (沈玉华), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(4):739-744
6. [6]
  [6] ZHANG Yu-Min(张玉敏), LIU Hai-Yan(刘海燕), SONG Wen-Bo(宋文波). Chem. J. Chinese Universities(高等学校化学学报), 2010,31(1):157-161
7. [7]
  [7] NING Xiao-Hua(宁晓华), XU Shu-Ping(徐抒平), DONG Feng-Xia(董凤霞). Chem. J. Chinese Universities(高等学校化学学报), 2009,30(1):159-163
8. [8]
  [8] LI Xiao-Ling(李小灵), XU Wei-Qing(徐蔚青), ZHANG Jun- Hu(张俊虎). Chem. J. Chinese Universities(高等学校化学学报), 2003,24(4):707-710
9. [9]
  [9] Si M Z, Kang Y P, Liu R M, Appl. Surf. Sci., 2012,258: 5533-5537
10. [10]
  [10] Li S, Liu P, Wang Q S. Appl. Surf. Sci., 2012,263:613-618
11. [11]
  [11] Zaki S, El Kady M F, Abd-El-Haleem D. Mater. Res. Bull., 2011,46:1571-1576
12. [12]
  [12] Zhang W Z, Qiao X L, Chen Q Y, et al. Appl. Surf. Sci., 2012,258:5909-5913
13. [13]
  [13] Zhang Y L, Wang J R, Yang P. Mater. Res. Bull., 2013,48: 461-468
14. [14]
  [14] Lee C L, Chang K C, Syu C M. Colloids Surf. A: Physico- chem. Eng. Aspects, 2011,381:85-91
15. [15]
  [15] Lee C L, Syu C M, Chiou H P, et al. Int. J. Hydrogen Energy, 2011,36:105021-110512
16. [16]
  [16] Lee B H, Hsu M S, Hsu Y C, et al. J. Phys. Chem. C, 2010, 114:6222-6227
17. [17]
  [17] Skrabalak S E, Au L, Li X D, et al. Nature Protocols, 2007, 2:2182-2190
18. [18]
  [18] Siekkinen A R, McLellan J M, Chen J Y, et al. Chem. Phys. Lett., 2006,432:491-496
19. [19]
  [19] Wei Y, Chen Y, Ye L, et al. Mater. Res. Bull., 2011,46:929 -936
20. [20]
  [20] Wang J, Huang L Q, Zhai L P, et al. Appl. Surf. Sci., 2012, 261:605-609
21. [21]
  [21] Zhou Q, Wang S, Jia N, et al. Mater Lett., 2006,60:3789- 3792
22. [22]
  [22] Tang S, Meng X, Lu H, et al. Mater Chem Phys., 2009,116: 464-468
23. [23]
  [23] Ren W, Guo S J, Dong S J, et al. J. Phys. Chem. C, 2011, 115:10315-10320
24. [24]
  [24] Zhang M F, Zhao A W, Sun H H, et al. J. Mater. Chem., 2011,21:18817-18824
25. [25]
  [25] Wang Y L, Camargo P H C, Skrabalak S E. Langmuir, 2008,24:12042-12046
26. [26]
  [26] Zhang G X, Sun S H, Banis M N, et al. Cryst. Growth Des., 2011,11:2493-2499
27. [27]
  [27] Pourjavadi A, Soleyman R. Mater. Res. Bull., 2011,46:1860- 1865
28. [28]
  [28] Yang J H, Dennis R C, Sardar D K. Mater. Res. Bull., 2011,46:1080-1084
29. [29]
  [29] Huang Q L, Zhu X S. Mater. Chem. Phys., 2013,138:689- 694
30. [30]
  [30] Hildebrandt P, Stockburger M. J. Phys. Chem., 1984,88: 5935-5944
31. [31]
  [31] Song Y H, Luo D, Ye S H, et al. Appl. Surf. Sci., 2012,258: 2584-2590
32. [32]
  [32] Huang J F, Vongehr S, Tang S C, et al. Langmuir, 2009,25: 11890-11896
33. [33]
  [33] Liu R J, Li S W, Yu X L, et al. Cryst. Growth Des., 2011, 11:3424-3431
1. [1]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
2. [2]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
3. [3]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
4. [4]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
5. [5]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
6. [6]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
7. [7]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
8. [8]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
9. [9]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
10. [10]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
11. [11]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
12. [12]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
13. [13]
  Chi Zhang , Suqi Wu , An Liu , Wei Zhang , Xiao Wei . Application of Team-Based Learning Teaching Method in Inorganic Chemistry Course: the Design Case of Inorganic Chemistry Teaching in Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 89-95. doi: 10.12461/PKU.DXHX202409135
14. [14]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
15. [15]
  Qizhi Yao , Gu Jin , Pingping Zhu . Modular Analytical Chemistry Experimental Teaching Based on “Comprehensive + Exploratory” Experiments: “One Student, One Plan”, Individualized Experimental Teaching Method. University Chemistry, 2024, 39(3): 143-148. doi: 10.3866/PKU.DXHX202309071
16. [16]
  Yinuo Wu , Jiantao Ye , Xie Zhou , Yu Qian , Lei Guo . Teaching Design of Basic Chemistry Based on PBL Methodology for Medical Undergraduates: A Case Study on “Osmotic Pressure of Solution”. University Chemistry, 2024, 39(3): 149-157. doi: 10.3866/PKU.DXHX202309077
17. [17]
  Shengyan Yang , Xiangzhen Meng , Xin Wang , Yang Zhang . Construction and Exploration of an Online-Offline Blended “Eight-Link” Teaching Method for Physical Chemistry Experiments Based on OBE Concept. University Chemistry, 2024, 39(11): 28-37. doi: 10.3866/PKU.DXHX202402019
18. [18]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
19. [19]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
20. [20]
  Honglian Liang , Xiaozhe Kuang , Fuping Wang , Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(526)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142