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Citation: WANG Ji-Jiang, HOU Xiang-Yang, GAO Lou-Jun, ZHANG Mei-Li, REN Yi-Xia, FU Feng. Hydrothermal Synthesis, Crystal Structure and Luminescence of a2D Bilayer Zn(Ⅱ) Coordination Polymer Based on Terphenyl-2,2’,4,4’-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 379-383. doi: 10.11862/CJIC.2014.018 shu

Hydrothermal Synthesis, Crystal Structure and Luminescence of a2D Bilayer Zn(Ⅱ) Coordination Polymer Based on Terphenyl-2,2’,4,4’-tetracarboxylic Acid

  • 1.

    Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

  • Corresponding author: WANG Ji-Jiang, 
  • Received Date: 22 January 2013
    Available Online: 6 September 2013

    Fund Project:

  • Acomplex based on Zn (Ⅱ) and terphenyl-2,2',4,4'-tetracarboxylic acid, namely, [Zn2(tpta)0.5(H2tpta)(dpe)(H2O)2]n (H4tpta=terphenyl-2,2',4,4'-tetracarboxylic acid, dpe=1,2-di(4-pyridyl)ethylene) has been hydrother-mally synthesized and characterized by elemental analysis, IRspectroscopy, single-crystal X-ray diffraction analysis, thermal stability analysis and fluorescent analysis. The complex crystallizes in triclinic system, space group P1 with a=1.0174(2) nm, b=1.0341(2) nm, c=1.8831(4) nm, α=96.147(4)°, β=96.866(4)°, γ=98.023(4)°, V=1.9322(7) nm3, Z=2, Dc=1.640 g·cm-3, μ=1.320 mm-1, F(000)=974, and the final R1=0.0669, wR2=0.1332 for I>2σ(I). Complex 1 features an unusual 2Dbilayer motif with ring dinuclear Zn2 units, which is further linked to each other by O-H…Ohydrogen bonds to complete the final 3Dsupramolecular architecture. In additional, complex 1 shows good thermal stability and luminescent property. CCDC: 913522.
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