Citation: YAN Li, SUN Ming-Zhe, REN Li, LIU Xiao-Meng, LIU Peng, WANG Yi-Hui. One₂D Mn(Ⅱ) Complex Constructed by Poly-Carboxylate and N-heterocyclic Ligands：Syntheses, Characterizations and Photoluminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 384-390. doi: 10.11862/CJIC.2014.015 shu

One₂D Mn(Ⅱ) Complex Constructed by Poly-Carboxylate and N-heterocyclic Ligands：Syntheses, Characterizations and Photoluminescent Properties

YAN Li ^1,, ,
SUN Ming-Zhe ² ,
REN Li ³ ,
LIU Xiao-Meng ¹ ,
LIU Peng ¹ ,
WANG Yi-Hui ¹

1.
1 Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;

Corresponding author: YAN Li,
Received Date: 24 February 2013
Available Online: 11 September 2013
Fund Project:

One coordination complex constructed from dicarboxylate acid and N-heterocyclic ligand as mixed ligands, namely, [Mn(mip)(NDC)]_n (1) (mip=2-(3-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, NDC= naphthalene-1,4-dicarboxylic acid) has been synthesized by hydrothermal reaction. Complex 1 was characterized by elemental analysis, infrared spectrum (IR), single crystal X-ray diffraction, UV-Vis spectrum, and thermogravimetric analysis (TGA). Complex 1 crystallizes in monoclinic, space group P2₁/n with a=1.24580(7) nm, b=1.47450(9) nm, c=1.36544(8) nm, β=97.6440(1)°. In₁, the metal ions Mn(Ⅱ) act as distorted octahedral geometry, being surrounded by four carboxylate oxygen atoms from three NDC ligands and two donor nitrogen atoms from one mip molecule. Complex 1 shows 2D (4,4) sheet topology. TGanalysis shows two clear courses of weight loss, which corresponds to the decomposition of different ligands. The structure-related solid-state uorescence spectra of free ligands and complex 1 have been determined, and the result displays that complex 1 should be acted as potential luminescent material. CCDC: 919758.
- crystal structures;thermal stability;fluorescence
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One2D Mn(Ⅱ) Complex Constructed by Poly-Carboxylate and N-heterocyclic Ligands：Syntheses, Characterizations and Photoluminescent Properties

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通讯作者: 陈斌, bchen63@163.com

One₂D Mn(Ⅱ) Complex Constructed by Poly-Carboxylate and N-heterocyclic Ligands：Syntheses, Characterizations and Photoluminescent Properties