Citation: HU Jin-Song, ZAHNG Xu-Jiao, CAI Xiao-Wei, SUN Lin-Xiao, ZAHNG Wen-Hao, SHI Jian-Jun, ZHANG Xaio-Mei, XING Hong-Long, HE Jie. Structure and Fluorescence Property of 2D Interlocked Zn(Ⅱ) Coordination Polymer Constructed by V-Shaped Imidazolyl Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 654-658. doi: 10.11862/CJIC.2014.014 shu

Structure and Fluorescence Property of 2D Interlocked Zn(Ⅱ) Coordination Polymer Constructed by V-Shaped Imidazolyl Ligand

1.
1 School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China;

Received Date: 30 January 2013
Available Online: 18 September 2013
Fund Project: 国家自然基金(No.21301005,21271008,51173002) (No.21301005,21271008,51173002)安徽省教育厅自然科学基金 (No.KJ2011A091) (No.KJ2011A091)江苏省新型环保重点实验室开放课题基金(No.AE201107)资助项目。 (No.AE201107)

A new interlocked 2D_achiral coordination polymers {[Zn(BIDPE)(pim)]·(H₂O)}_n (1) was prepared under hydrothermal conditions based on V-shaped ligand 4,4'-bis(imidazol-1-yl)diphenyl ether (BIDPE) with aliphatic pimelic acid (H₂pim). The complex was characterized by IR spectroscopy, TGA, X-ray powder and single-crystal diffraction. It crystallizes in the monoclinic system, space group P2₁/c. The neighboring Zn(Ⅱ) ions are linked by BIDPE and pim^2-anions to form infinitely 2D_chiral layer, two identical 2D_chiral layers interlocked each other to give 2D_chiral+2D_chiral→2D_chiral sheet. The helical directions of adjacent interlocked 2D_chiral sheets are reverse, which stacked in ABAB mode to form 2D_achiral network. In addition, the solid-state photoluminescent property of 1 was also studied. CCDC: 933583.
- coordination polymer;V-shaped ligand;photoluminescent
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沈阳化工大学材料科学与工程学院沈阳 110142