Citation: LIU Ming-Ming, LÜ Wen-Miao, SHI Xiu-Feng, FAN Bin-Bin, LI Rui-Feng. Characterization and Catalytic Performence of Zeolitic Imidazolate Framework-8 (ZIF-8) Synthesized by Different Methods[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 579-584. doi: 10.11862/CJIC.2014.009 shu

Characterization and Catalytic Performence of Zeolitic Imidazolate Framework-8 (ZIF-8) Synthesized by Different Methods

1.
Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Received Date: 27 May 2013
Available Online: 8 October 2013
Fund Project: 国家自然科学基金(No.20971095) (No.20971095)山西省回国留学人员科研(No.2013-047)资助项目。 (No.2013-047)

A series of Zeolitic Imidazolate Framework-8(ZIF-8) samples was synthesized in a mixture of methanol and aqueous ammonia, methanol, and DMF, respectively (denoted as ZIF-8(NH₄OH), ZIF-8(MeOH) and ZIF-8(DMF)) with 2-methylimidazole as an organic linker and Zn(OH)₂ or Zn(NO₃)₂·6H₂O as Zn source. The physicochemical properties and catalytic performance of the samples were characterized by XRD, FTIR, N₂ adsorption, SEM, TPD and Knoevenagel reaction. The results show that ZIF-8 can be synthesized by three methods and the samples synthesized by different methods have similar morphologies, but different particle sizes and acid-base properties. ZIF-8(MeOH) has much narrower particle size distribution, smaller particle size as well as more acid and base centers than those of ZIF-8(NH₄OH) and ZIF-8(DMF). The ZIF-8 samples exhibit significant difference in catalytic performance for Knoevenagel reaction from benzaldehyde and malononitrile. ZIF-8(MeOH) is the most effective catalyst. The higher catalytic activity of the ZIF-8(MeOH) sample is closely related with its higher external surface area and acid-base properties.
- metal-organic frameworks;ZIF-8;heterogeneous catalysis;knoevenagel condensation reaction;benzaldehyde;malononitrile
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