Citation: LIU Ming-Ming, LÜ Wen-Miao, SHI Xiu-Feng, FAN Bin-Bin, LI Rui-Feng. Characterization and Catalytic Performence of Zeolitic Imidazolate Framework-8 (ZIF-8) Synthesized by Different Methods[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 579-584. doi: 10.11862/CJIC.2014.009 shu

Characterization and Catalytic Performence of Zeolitic Imidazolate Framework-8 (ZIF-8) Synthesized by Different Methods

1.
Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Received Date: 27 May 2013
Available Online: 8 October 2013
Fund Project: 国家自然科学基金(No.20971095) (No.20971095)山西省回国留学人员科研(No.2013-047)资助项目。 (No.2013-047)

A series of Zeolitic Imidazolate Framework-8(ZIF-8) samples was synthesized in a mixture of methanol and aqueous ammonia, methanol, and DMF, respectively (denoted as ZIF-8(NH₄OH), ZIF-8(MeOH) and ZIF-8(DMF)) with 2-methylimidazole as an organic linker and Zn(OH)₂ or Zn(NO₃)₂·6H₂O as Zn source. The physicochemical properties and catalytic performance of the samples were characterized by XRD, FTIR, N₂ adsorption, SEM, TPD and Knoevenagel reaction. The results show that ZIF-8 can be synthesized by three methods and the samples synthesized by different methods have similar morphologies, but different particle sizes and acid-base properties. ZIF-8(MeOH) has much narrower particle size distribution, smaller particle size as well as more acid and base centers than those of ZIF-8(NH₄OH) and ZIF-8(DMF). The ZIF-8 samples exhibit significant difference in catalytic performance for Knoevenagel reaction from benzaldehyde and malononitrile. ZIF-8(MeOH) is the most effective catalyst. The higher catalytic activity of the ZIF-8(MeOH) sample is closely related with its higher external surface area and acid-base properties.
- metal-organic frameworks;ZIF-8;heterogeneous catalysis;knoevenagel condensation reaction;benzaldehyde;malononitrile
1. [1]
  [1] Ma S, Zhou H C. Chem. Commun., 2010,46(1):44-53
2. [2]
  [2] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112(2):869-932
3. [3]
  [3] Dhakshinamoorthy A, Garcia H. Chem. Soc. Rev., 2012,41 (15):5262-5284
4. [4]
  [4] Phan A, Doonan C J, Uribe-Romo F J, et al. Acc. Chem. Res., 2010,43(1):58-67
5. [5]
  [5] Venna S R, Carreon M A. J. Am. Chem. Soc., 2010,132(1): 76-78
6. [6]
  [6] Venna S R, Jasinski J B, Carreon M A. J. Am. Chem. Soc., 2010,132(51):18030-18033
7. [7]
  [7] Park K S, Ni Z, Cté A P, et al. Proc. Natl. Acad. Sci. USA, 2006,103(27):10186-10191
8. [8]
  [8] Luebbers M T, Wu T, Shen L, et al. Langmuir, 2010,26(19):15625-15633
9. [9]
  [9] Bux H, Chmelik C, Krishna R, et al. J. Membrane. Sci., 2011, 369(1):284-289
10. [10]
  [10] Jiang H L, Akita T, Ishida T, et al. J. Am. Chem. Soc., 2011,133(5):1304-1306
11. [11]
  [11] Jiang H L, Liu B, Akita T, et al. J. Am. Chem. Soc., 2009, 131(32):11302-11303
12. [12]
  [12] Zahmakiran M. Dalton Trans., 2012,41(41):12690-12696
13. [13]
  [13] Nguyen L T L, Le K K A, Phan N T S. Chin. J. Catal.(催化学报), 2012,33(4):688-696
14. [14]
  [14] Miralda C M, Macias E E, Zhu M, et al. ACS Catal., 2011,2 (1):180-183
15. [15]
  [15] Chizallet C, Lazare S, Bazer-Bachi D, et al. J. Am. Chem. Soc., 2010,132(35):12365-12377
16. [16]
  [16] Tran U P N, Le K K A, Phan N T S. ACS Catal., 2011,1(2): 120-127
17. [17]
  [17] Sinhamahapatra A, Pal P, Tarafdar A, et al. ChemCatChem., 2013,5(1):331-338
18. [18]
  [18] Zhou X, Zhang H P, Wang G Y, et al. J. Mol. Catal. A: Chem., 2013,366:43-47
19. [19]
  [19] Zhu M Q, Srinivas D, Bhogeswararao S, et al. Catal. Commun., 2013,32:36-40
20. [20]
  [20] Phan N T S, Jones C W. J. Mol. Catal. A: Chem., 2006,253 (1/2):123-131
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沈阳化工大学材料科学与工程学院沈阳 110142