Citation: LIU Ming-Ming, LÜ Wen-Miao, SHI Xiu-Feng, FAN Bin-Bin, LI Rui-Feng. Characterization and Catalytic Performence of Zeolitic Imidazolate Framework-8 (ZIF-8) Synthesized by Different Methods[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 579-584. doi: 10.11862/CJIC.2014.009 shu

Characterization and Catalytic Performence of Zeolitic Imidazolate Framework-8 (ZIF-8) Synthesized by Different Methods

1.
Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Received Date: 27 May 2013
Available Online: 8 October 2013
Fund Project: 国家自然科学基金(No.20971095) (No.20971095)山西省回国留学人员科研(No.2013-047)资助项目。 (No.2013-047)

A series of Zeolitic Imidazolate Framework-8(ZIF-8) samples was synthesized in a mixture of methanol and aqueous ammonia, methanol, and DMF, respectively (denoted as ZIF-8(NH₄OH), ZIF-8(MeOH) and ZIF-8(DMF)) with 2-methylimidazole as an organic linker and Zn(OH)₂ or Zn(NO₃)₂·6H₂O as Zn source. The physicochemical properties and catalytic performance of the samples were characterized by XRD, FTIR, N₂ adsorption, SEM, TPD and Knoevenagel reaction. The results show that ZIF-8 can be synthesized by three methods and the samples synthesized by different methods have similar morphologies, but different particle sizes and acid-base properties. ZIF-8(MeOH) has much narrower particle size distribution, smaller particle size as well as more acid and base centers than those of ZIF-8(NH₄OH) and ZIF-8(DMF). The ZIF-8 samples exhibit significant difference in catalytic performance for Knoevenagel reaction from benzaldehyde and malononitrile. ZIF-8(MeOH) is the most effective catalyst. The higher catalytic activity of the ZIF-8(MeOH) sample is closely related with its higher external surface area and acid-base properties.
- metal-organic frameworks;ZIF-8;heterogeneous catalysis;knoevenagel condensation reaction;benzaldehyde;malononitrile
1. [1]
  [1] Ma S, Zhou H C. Chem. Commun., 2010,46(1):44-53
2. [2]
  [2] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112(2):869-932
3. [3]
  [3] Dhakshinamoorthy A, Garcia H. Chem. Soc. Rev., 2012,41 (15):5262-5284
4. [4]
  [4] Phan A, Doonan C J, Uribe-Romo F J, et al. Acc. Chem. Res., 2010,43(1):58-67
5. [5]
  [5] Venna S R, Carreon M A. J. Am. Chem. Soc., 2010,132(1): 76-78
6. [6]
  [6] Venna S R, Jasinski J B, Carreon M A. J. Am. Chem. Soc., 2010,132(51):18030-18033
7. [7]
  [7] Park K S, Ni Z, Cté A P, et al. Proc. Natl. Acad. Sci. USA, 2006,103(27):10186-10191
8. [8]
  [8] Luebbers M T, Wu T, Shen L, et al. Langmuir, 2010,26(19):15625-15633
9. [9]
  [9] Bux H, Chmelik C, Krishna R, et al. J. Membrane. Sci., 2011, 369(1):284-289
10. [10]
  [10] Jiang H L, Akita T, Ishida T, et al. J. Am. Chem. Soc., 2011,133(5):1304-1306
11. [11]
  [11] Jiang H L, Liu B, Akita T, et al. J. Am. Chem. Soc., 2009, 131(32):11302-11303
12. [12]
  [12] Zahmakiran M. Dalton Trans., 2012,41(41):12690-12696
13. [13]
  [13] Nguyen L T L, Le K K A, Phan N T S. Chin. J. Catal.(催化学报), 2012,33(4):688-696
14. [14]
  [14] Miralda C M, Macias E E, Zhu M, et al. ACS Catal., 2011,2 (1):180-183
15. [15]
  [15] Chizallet C, Lazare S, Bazer-Bachi D, et al. J. Am. Chem. Soc., 2010,132(35):12365-12377
16. [16]
  [16] Tran U P N, Le K K A, Phan N T S. ACS Catal., 2011,1(2): 120-127
17. [17]
  [17] Sinhamahapatra A, Pal P, Tarafdar A, et al. ChemCatChem., 2013,5(1):331-338
18. [18]
  [18] Zhou X, Zhang H P, Wang G Y, et al. J. Mol. Catal. A: Chem., 2013,366:43-47
19. [19]
  [19] Zhu M Q, Srinivas D, Bhogeswararao S, et al. Catal. Commun., 2013,32:36-40
20. [20]
  [20] Phan N T S, Jones C W. J. Mol. Catal. A: Chem., 2006,253 (1/2):123-131
1. [1]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
2. [2]
  Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
3. [3]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
4. [4]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
7. [7]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
8. [8]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
11. [11]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
12. [12]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
13. [13]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
14. [14]
  Xin Zhang , Junyu Chen , Xiang Pei , Linxin Yang , Liang Wang , Luona Chen , Guangmei Yang , Xibo Pei , Qianbing Wan , Jian Wang . Drug-loading ZIF-8 for modification of microporous bone scaffold to promote vascularized bone regeneration. Chinese Chemical Letters, 2024, 35(6): 108889-. doi: 10.1016/j.cclet.2023.108889
15. [15]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
16. [16]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
17. [17]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
18. [18]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
19. [19]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
20. [20]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(6065)
HTML views(3028)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142