Citation: HUANG Cheng, CHANG Ting, ZHANG Yue, KANG Shi-Zhao, LI Xiang-Qing, MU Jin. Photocatalytic Activity and Optoelectronic Property of Porphyrin Tin-Sensitized TiO₂ Nanotubes[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 331-336. doi: 10.11862/CJIC.2014.007 shu

Photocatalytic Activity and Optoelectronic Property of Porphyrin Tin-Sensitized TiO₂ Nanotubes

1.
1 School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;

Corresponding author: MU Jin,
Received Date: 3 July 2013
Available Online: 2 September 2013
Fund Project:

TiO₂ nanotubes sensitized with trans-dihydroxo[5,10,15,10-tetraphenyl porphyrin] tin(Ⅳ) (abbreviated to SnTPP) were prepared. The photocatalytic activity of SnTPP-sensitized TiO₂ nanotubes were evaluated by using p-nitrophenol as a model contaminant under visible light irradiation. Meanwhile, SnTPP-sensitized TiO₂ nanoparticles were selected as a reference substance to explore the effect of morphology on the photocatalytic activity of catalysts. The experimental results show that introduction of SnTPP can significantly enhance the visible light photocatalytic activity of TiO₂ nanotubes. And TiO₂ nanotubes show higher sensitizing effect of SnTPP than TiO₂ nanoparticles, indicating that the morphology of a catalyst plays an important role in the photocatalytic process. In addition, the photoelectrochemical behavior of SnTPP-sensitized TiO₂ nanotubes was examined and related with the photocatalytic activity. Finally, the sensitizing mechanism of SnTPP was discussed preliminarily.
- porphyrin tin;sensitization;TiO₂ nanotubes;photocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142

Photocatalytic Activity and Optoelectronic Property of Porphyrin Tin-Sensitized TiO2 Nanotubes

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通讯作者: 陈斌, bchen63@163.com

Photocatalytic Activity and Optoelectronic Property of Porphyrin Tin-Sensitized TiO₂ Nanotubes