Citation: YIN Wen-Yu, MA Yun-Sheng, WANG Jun, TANG Xiao-Yan, YUAN Rong-Xin. Synthesis and Characterization of a Dinuclear Manganese(Ⅱ) Complex Supported by Cyclohexanecarboxylate and 2, 2’-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 671-676. doi: 10.11862/CJIC.2014.006 shu

Synthesis and Characterization of a Dinuclear Manganese(Ⅱ) Complex Supported by Cyclohexanecarboxylate and 2, 2’-Bipyridine Ligands

1.
Department of Chemistry & Materials Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500, China

Received Date: 22 March 2013
Available Online: 18 September 2013
Fund Project: 国家自然科学基金资助项目(No.21001018, No. 21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (BK2012643)。 (No.21001018, No. 21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (BK2012643)

[Mn₂(O₂CC₆H₁₁)₂(bipy)₄](ClO₄)₂(C₆H₁₁CO₂H=cyclohexanecarboxylic acid; bipy=2,2'-bipyridine) was synthesized under hydrothermal condition by reactions of Mn(ClO₄)₂·6H₂O, C₆H₁₁CO₂Na and bipy. In the dinuclear cation [Mn₂(O₂CC₆H₁₁)₂(bipy)₄]²⁺, adjacent Mn atoms are linked together through two cyclohexanecarboxylate ligands in syn-anti bridging mode. The molecules are packed together through π-π stacking of the pyridyl groups and weak hydrogen bonding interactions of C-H…O into three-dimensional supramolecular network. Magnetic study indicates there exists weak antiferromagnetic interactions between the adjacent Mn(Ⅱ) ions. CCDC: 748489.
- cyclohexanecarboxylate;dinuclear manganese complex;crystal structure;magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142