Citation: XIA Shu-Biao, ZHANG Ying-Jie, DONG Peng, YANG Rui-Ming, ZHANG Yan-Nan. CeO₂ Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi_0.80Co_0.15Al_0.05O₂[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 529-535. doi: 10.11862/CJIC.2014.005 shu

CeO₂ Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi_0.80Co_0.15Al_0.05O₂

1.
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Received Date: 4 July 2013
Available Online: 6 August 2013
Fund Project: 云南省自然科学基金(No.200680048M) (No.200680048M)曲靖师范学院校级基金(No.2010003)资助项目。 (No.2010003)

LiNi_0.8Co_0.15Al_0.05O₂ cathode material was successfully fabricated by co-precipitation. CeO₂ coating use by sol-gel and subsequent heat treatment at 600 ℃ for 4 h, the CeO₂ surface modification can improve cycle and storage performance. When CeO₂ coating is 0.02% (molar ratio), contrast to pristine NCA, the CeO₂-coated LiNi_0.8Co_0.15Al_0.05O₂ cathode exhibits no decrease in its initial specific capacity of 182.44 mAh·g^-1 at 0.2C and excellent capacity retention (85.96% of its initial capacity) between 4.3 and 2.75 V at 0.5C after 100th cycles. The results indicate that the surface treatment should be an effective way to improve cycle properties due to CeO₂ inhibit the electrodes and the electrolyte side effects. CeO₂ coating layer with highly oxidability can react with the electrolyte in advance to consume trace amounts of water and HF in the electrolyte, and protect the internal active material.
- LiNi_0.8Co_0.15Al_0.05O₂ cathode;CeO₂-coating;cycle performance;electrolyte
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

CeO2 Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi0.80Co0.15Al0.05O2

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通讯作者: 陈斌, bchen63@163.com

CeO₂ Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi_0.80Co_0.15Al_0.05O₂