Citation: XIA Shu-Biao, ZHANG Ying-Jie, DONG Peng, YANG Rui-Ming, ZHANG Yan-Nan. CeO₂ Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi_0.80Co_0.15Al_0.05O₂[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 529-535. doi: 10.11862/CJIC.2014.005 shu

CeO₂ Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi_0.80Co_0.15Al_0.05O₂

1.
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Received Date: 4 July 2013
Available Online: 6 August 2013
Fund Project: 云南省自然科学基金(No.200680048M) (No.200680048M)曲靖师范学院校级基金(No.2010003)资助项目。 (No.2010003)

LiNi_0.8Co_0.15Al_0.05O₂ cathode material was successfully fabricated by co-precipitation. CeO₂ coating use by sol-gel and subsequent heat treatment at 600 ℃ for 4 h, the CeO₂ surface modification can improve cycle and storage performance. When CeO₂ coating is 0.02% (molar ratio), contrast to pristine NCA, the CeO₂-coated LiNi_0.8Co_0.15Al_0.05O₂ cathode exhibits no decrease in its initial specific capacity of 182.44 mAh·g^-1 at 0.2C and excellent capacity retention (85.96% of its initial capacity) between 4.3 and 2.75 V at 0.5C after 100th cycles. The results indicate that the surface treatment should be an effective way to improve cycle properties due to CeO₂ inhibit the electrodes and the electrolyte side effects. CeO₂ coating layer with highly oxidability can react with the electrolyte in advance to consume trace amounts of water and HF in the electrolyte, and protect the internal active material.
- LiNi_0.8Co_0.15Al_0.05O₂ cathode;CeO₂-coating;cycle performance;electrolyte
1. [1]
  [1] Liu Z C, Zhen H H, Kim Y G, et al. J. Power Sources, 2011, 196:10201-10206
2. [2]
  [2] Ju S H, Jang H C, Kang Y C. Electrochim. Acta, 2007,25: 7286-7292
3. [3]
  [3] JIANG Wei-Jun(江卫军), QI Lu(其鲁), KE Ke(柯克), et al. Chinese J. Inorg. Chem.(无机化学学报), 2003,19(12):1279-1284
4. [4]
  [4] Li J L, Daniel C, Wood D. J. Power Sources, 2011,196:2452 -2460
5. [5]
  [5] HUANG Yuan-Qiao(黄元乔), GUO Wen-Yong(郭文勇), LI Dao-Cong(李道聪), et al. Chinese J. Inorg. Chem.(无机化学学报), 2005,21(5):736-740
6. [6]
  [6] Hu G R, Liu W M, Peng Z D, et al. J. Power Sources, 2012, 198:258-263
7. [7]
  [7] YUAN Chao-Qun(袁超群), LI Dao-Cong(李道聪), SHEN Yu-Fang(沈玉芳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006,22(9):1645-1650
8. [8]
  [8] Fu L J, Liu H, Li C, et al. Solid State Science, 2006,8:113-128
9. [9]
  [9] Croguennec L, Horn Y S, Gloter A, et al. Chem. Mater., 2009,21:1051-1059
10. [10]
  [10] Wang J, Yuan G X, Zhang M H, et al. Electrochim. Acta, 2012,66:61-66
11. [11]
  [11] Cho Y Y, Lee Y S, Park S A, et al. Electrochim. Acta, 2010,56:333-339
12. [12]
  [12] LIU Hao-Han(刘浩涵), ZHANG Jian(张建), LOU Yu-Wan (娄豫皖), et al. Acta Chimica Sinica(化学学报), 2012,70: 1055-1058
13. [13]
  [13] Sun Y K, Yoon C S, Myung S T, et al. J. Electrochem. Soc., 2009,156:1005-1010
14. [14]
  [14] Cho Y, Cho J. J. Electrochem. Soc., 2010,157:A625-A629
15. [15]
  [15] Yoon W S, Nam K W, Jang D, et al. J. Power Sources, 2012,217:128-134
16. [16]
  [16] Bak Y R, Chung Y M, Ju J H, et al. J. New Mat. Electr. Sys., 2011,14:203-207
17. [17]
  [17] Zhang Y J, Xia S B, Zhang Y N, et al. Chin. Sci. Bull., 2012,57:4181-4187
18. [18]
  [18] Wang M, Wu F, Su Y F. Sci. China Ser. E, 2009,39:809813
19. [19]
  [19] Kalyani P, Kalaiselvi N. Sci. Technol. Adv. Mat., 2005,6: 689-703
20. [20]
  [20] Ha H W, Yun N J, Kim M H, et al. Electrochim. Acta, 2006,51:32973302
21. [21]
  [21] Guulmard M, Pouillerie C, Croguennec L. Solid State Ionics, 2003,160:39-50
22. [22]
  [22] JIN Le(金乐), TANG Xin-Cun(唐新村), PAN Chun-Yue(潘春跃), et al. Chinese J. Inorg. Chem.(无机化学学报), 2007, 23(7):1238-1241
23. [23]
  [23] Bloom I, Jones S A, Battaglia V S, et al. J. Power Sources, 2003,124:538-550
24. [24]
  [24] Kim J M, Chung H T. Electrochim. Acta, 2004,49:3573-3580
25. [25]
  [25] Reddy M V, Rao G V S, Chowdari B V R. J. Phys. Chem. C, 2007,111:11712-11720
26. [26]
  [26] Lee D J, Scrosati B, Sun Y K. J. Power Sources, 2011,196: 7742-7746
27. [27]
  [27] HU Guo-Rong(胡国荣), LIU Qiang(刘强), DU Ke(杜柯), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(6): 1171-1176
28. [28]
  [28] Lee Y S, Ahn D, Cho Y H, et al. J. Electrochem. Soc., 2011,158:A1354-A1360
29. [29]
  [29] Liu H L, Li L, Yao T T, et al. Surf. Coat. Tech., 2013,219: 88-93
30. [30]
  [30] DU Ke(杜柯), LIU Yan(刘燕), HU Guo-Rong(胡国荣), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(7):1235-1239
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

CeO2 Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi0.80Co0.15Al0.05O2

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通讯作者: 陈斌, bchen63@163.com

CeO₂ Surface Modification to Improve Cycle and Storage Performance on Lithium Ion Battery Cathode Material LiNi_0.80Co_0.15Al_0.05O₂