Citation: DING Long-Fei, WANG Ting, WU Li-Guang. Synthesis of AgCl Nanoparticles in Ionic Liquid Microemulsion and Regulation of AgCl/poly(MMA-co-St) Hybrid Membranes[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 323-330. doi: 10.11862/CJIC.2014.002 shu

Synthesis of AgCl Nanoparticles in Ionic Liquid Microemulsion and Regulation of AgCl/poly(MMA-co-St) Hybrid Membranes

1.
College of Environment Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012, China

Corresponding author: WU Li-Guang,
Received Date: 18 June 2013
Available Online: 25 September 2013
Fund Project:

To obtain high performance membranes of polymer-silver salt complexes for the separation of aromatic/aliphatic hydrocarbons, a novel preparation method of AgCl/polymer hybrid membranes has been reported. AgCl nanoparticles were first synthesized in a water-in-oil (W/O) microemulsion, AgCl/polymer hybrid membranes are subsequently prepared via microemulsion in-situ polymerization. In the preparation of AgCl/polymer hybrid membranes, the composition of the microemulsion could not only affect the morphology of AgCl nanoparticles, but also regulate the performance of the hybrid membranes. In this paper, AgCl nanoparticles were synthesized in W/Omicroemulsion using the ionic liquid 1-dodecyl-3-methyl imidazoium chloride (C₁₂mimCl) as the surfactant and methyl methacrylate-styrene (MMA-St) mixture as the oil phase. Aqueous AgNO₃ solution was added to the microemulsion as the source of Ag⁺ ions. Then, AgCl/poly(MMA-co-St) hybrid membranes were prepared by microemulsion in situ polymerization. The influence of the ratio of St to MMAin the oil phase and molar ratio of water to surfactant (ω) on the morphology of AgCl nanoparticles in the microemulsion were characterized by UV-visible spectroscopy (UV-Vis) and transmission electron microscopy (TEM). The scanning electron microscopy (SEM) and the swelling-sorption experiments of the hybrid membranes were employed to explore the relationship between the composition of the microemulsion and the membrane performance. The results showed that the increase in the ratio of St to MMAin the oil phase depressed the polarity of the oil phase, which led to the formation of more AgCl nanoparticles with good dispersion in the hybrid membrane. And these increased significantly the equilibrium swelling-sorption degree in benzene (A_∞,b) and the swelling-sorption selectivity of benzene to cyclohexane (α_s,b/c) of AgCl/poly(MMA-co-St) hybrid membranes. While the ratio of St to MMAin the oil phase was 1:3, A_∞,b and α_s,b/c reached 330 mg·g^-1 and 19.21. When excess styrene was added to the oil phase, the stability of W/Omicroemulsion was reduced and large AgCl particles generated in the microemulsion, which significantly decreased A_∞,b and α_s,b/c of AgCl/poly(MMA-co-St) hybrid membranes. The increase of ω resulted in the formation of more AgCl nanoparticles in the microemulsion, which enhanced A_∞,b and α_s,b/c of AgCl/poly(MMA-co-St) hybrid membranes. When ω was more than₅, A_∞,b and α_s,b/c of AgCl/poly(MMA-co-St) hybrid membranes decreased because of the aggregation of AgCl particles.
- C₁₂mimCl;ionic liquid microemulsion;AgCl nanoparticles;hybrid membrane;swelling-sorption performance
1. [1]
  [1] Khraishen M, Benyahia F, Adham S, et al. Desalin. Water Treat., 2013,51(7-9):1769-1775
2. [2]
  [2] LI Long(李龙), ZHAN Han-Hui(湛含辉). Membr. Sci. Technol.(膜科学与技术), 2012,32(3):112-116
3. [3]
  [3] Ahmad J, Hagg M B. J. Membr. Sci., 2013,427:73-84
4. [4]
  [4] Pan C C, Zhang B J, Yang F W, et al. Acta Chim Sinica, 2009,67(22):2559-2565
5. [5]
  [5] Yan N T, Kathiraser Y, Kawi S, et al. J. Membr. Sci., 2013, 428:78-85
6. [6]
  [6] Zhang X X, Wang L H, Yun Y B, et al. Acta Chim Sinica, 2012,70(2):170-176
7. [7]
  [7] WU Li-Guang(吴礼光), XIANG Wen(项雯), DU Chun-Hui (杜春慧). Chinese J. Inorg. Chem.(无机化学学报), 2011, 27(1):61-65
8. [8]
  [8] WU Li-Guang(吴礼光), ZHOU Y(周勇), GAO Cong-Jie(高从堦). Membr. Sci. Technol.(膜科学与技术), 2004,24(1):20-22
9. [9]
  [9] WANG Jian(王健), WANG Ting(王挺), WU Li-Guang(吴礼光). Chinese J. Inorg. Chem.(无机化学学报), 2012,28(5): 989-994
10. [10]
  [10] LIU Yun-Quan(刘云泉), CHEN Xiao-Hua(陈小华), ZHANG Ke(张科). J. Inorg. Mater.(无机材料学报), 2009,24(5):993- 997
11. [11]
  [11] GUO Wen-Jing(郭文静), SUN Lei(孙磊), ZHANG Ping-Yu (张平余). Acta Phys.-Chim. Sin.(物理化学学报), 2007,23 (3):367-372
12. [12]
  [12] Hamer M, Carballo R R, Rezzano I N, et al. Sensor. Actuat. B, 2010,145(1):250-253
13. [13]
  [13] Sun B, Guo Y, Xu L, et al. Acta Chim Sinica, 2012,70(23): 2419-2424
14. [14]
  [14] Zhang R W, Moon K S, Lin W, et al. Compos. Sci. Technol., 2011,71(4):528-534
15. [15]
  [15] XU Wang-Hua(徐汪华), SHEN Yu-Hua(沈玉华), XIE An- Jian(谢安建), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006,22(2):258-262
16. [16]
  [16] ZHONG Wen-Ying(钟文英), YANG Shuo(杨硕), HUANG Bin(黄斌), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(11):2321-2328
17. [17]
  [17] Guo W J, Sun L, Wu Z S, et al. J. Inorg. Mater., 2008,23(5): 960-964
18. [18]
  [18] Chen Y J, Xu G Y, Yuan L S, et al. Colloids Surfaces A: Physicochem. Eng., 2006,273:174-178
19. [19]
  [19] TENG Yan (滕燕), WANG Ting(王挺), DU Chun-Hui(杜春慧). Acta Mater. Composi. Sin.(复合材料学报), 2012,29 (6):42-49
20. [20]
  [20] Wang L M, Wang F J, Chen D J. Mater. Lett., 2008,62(14): 2153-2156
21. [21]
  [21] XU Hua-Ming(徐华明), LI Dan(李聃), LIANG Ji(梁吉). Chinese J. Inorg. Chem.(无机化学学报), 2005,21(9):1354- 1356
22. [22]
  [22] SONG Ya-Jiao(宋亚娇), SUN Jing(孙晶), ZHU Peng(朱鹏), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(6): 1171-1175
23. [23]
  [23] Zienkiewicz S M, Pikus S. Appl. Surf. Sci., 2013,265:904- 911
24. [24]
  [24] Sang H C, Dae W L, Min S K. J. Colloid Inter. Sci., 2011, 355:70-75
25. [25]
  [25] Wu L G, Wang T, Jiang Z. J. Membr. Sci., 2013,429:95- 102
1. [1]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
2. [2]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
5. [5]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
6. [6]
  Gaofeng Zeng , Shuyu Liu , Manle Jiang , Yu Wang , Ping Xu , Lei Wang . Micro/Nanorobots for Pollution Detection and Toxic Removal. University Chemistry, 2024, 39(9): 229-234. doi: 10.12461/PKU.DXHX202311055
7. [7]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
8. [8]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
9. [9]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
10. [10]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
11. [11]
  Cuicui Yang , Bo Shang , Xiaohua Chen , Weiquan Tian . Understanding the Wave-Particle Duality and Quantization of Confined Particles Starting from Classic Mechanics. University Chemistry, 2025, 40(3): 408-414. doi: 10.12461/PKU.DXHX202407066
12. [12]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
13. [13]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
14. [14]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
15. [15]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
16. [16]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
17. [17]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
18. [18]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
19. [19]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
20. [20]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339

Get Citation

PDF

XML

Metrics

PDF Downloads(442)
Abstract views(947)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142