Citation: TIAN Ai-Xiang, HOU Xue, SUN Na, XIAO Ru, YING Jun, YANG Yang, NING Ya-Li, LI Tian-Jiao, WANG Xiu-Li. Syntheses, Structures and Properties of Two POM-based Compounds Modified by Biimidazole and Its Derivative[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 839-847. doi: 10.11862/CJIC.114 shu

Syntheses, Structures and Properties of Two POM-based Compounds Modified by Biimidazole and Its Derivative

TIAN Ai-Xiang ^1,, ,
HOU Xue ¹ ,
SUN Na ² ,
XIAO Ru ¹ ,
YING Jun ¹ ,
YANG Yang ¹ ,
NING Ya-Li ¹ ,
LI Tian-Jiao ¹ ,
WANG Xiu-Li ^1,,

1.
1 Department of Chemistry, Bohai University, Jinzhou, Liaoning 121000, China;
2.
2 Department of Chemical and Environmental Engineering, Hebei Chemical & Pharmaceutical Vocational Technology College, Shijiazhuang 050026, China

Corresponding author: TIAN Ai-Xiang, WANG Xiu-Li,
Received Date: 10 November 2014
Available Online: 22 January 2015
Fund Project: 国家自然科学基金(No.21101015,21471021,21201021)资助项目。 (No.21101015,21471021,21201021)

Through using two kinds of ligands (biimidazole and its derivative), two polyoxometalate-based compounds, [Ag₄(biz)₄][H₂P₂Mo₅O₂₃]·2H₂O (1) and [Ag₄(bbiz)₄][HPW₁₀^ⅥW₂^ⅤO₄₀] (2) (biz=2,2-biimidazole, bbiz=5-butyl-2,2-biimidazole), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, elemental analyses and IR spectra. Compound 1 contains bi-nuclear [Ag₂(biz)₂]²⁺ clusters, which are linked by [P₂Mo₅O₂₃]^6- anions through terminal O atoms to construct a 1D chain. In compound 2, each Keggin anion offers four bridging O atoms to link four bi-nuclear [Ag₂(bbiz)₂]²⁺ clusters and a 2D layer of 2 is constructed. Additionally, the electrochemical, photocatalytic and fluorescent properties of the title compounds have been studied. CCDC: 1027614, 1; 1027615, 2.
- POM-based compounds;2,2-biimidazole;5-butyl-2,2-biimidazole;electrochemical property;photocatalytic property; fluorescent property
1. [1]
  [1] (a) Manna K, Zhang T, Carboni M, et al. J. Am. Chem. Soc., 2014,136(38):13182-13185;
2. [2]
  (b) Ahmed A, Forster M, Clowes R, et al. Chem. Commun., 2014,50:14314-14316;
3. [3]
  (c) Phang W J, Lee W R, Yoo K, et al. Angew. Chem. Int. Ed., 2014,53(32):8383-8387
4. [4]
  [2] (a) Kikukawa Y J, Kuroda Y, Yamaguchi K, et al. Angew. Chem. Int. Ed., 2012,124(10):2484-2487;
5. [5]
  (b) Miao H, Xu X, Ju W W, et al. Inorg. Chem., 2014,53(6): 2757-2759;
6. [6]
  (c) Zhang Z Y, Lin Q P, Kurunthu D, et al. J. Am. Chem. Soc., 2011,133(18):6934-6937;
7. [7]
  (d) Fu H, Qin C, Lu Y, et al. Angew. Chem. Int. Ed., 2012,51:7985-7989
8. [8]
  (e) Wang X L, Bi Y F, Chen B K, et al. Inorg. Chem., 2008, 47(7):2442-2448
9. [9]
  [3] (a) Balula S S, Cunha-Silva L, Santos I C M S, et al. New J. Chem., 2013,37:2341-2350;
10. [10]
  (b) Tian A X, Ying J, Peng J, et al. Inorg. Chem., 2009,48(1): 100-110;
11. [11]
  (c) Wang X L, Li N, Tian A X, et al. Inorg. Chem., 2014,53(14):7118-7129
12. [12]
  [4] (a) Nagazi, I, Haddad A. J. Cluster Sci., 2014,25:627-638
13. [13]
  (b) Jin H J, Zhou B B, Yu Y, et al. Chem. Eng. Commun., 2011,13,585-590
14. [14]
  (c) Shi J, Wang C X, Yu K, et al. J. Coord. Chem., 2014,67(13):2229-2237
15. [15]
  [5] Li Z L, Wang Y, Zhang L C, et al. Dalton Trans., 2014,43: 5840-5846
16. [16]
  [6] (a) Wang L M, Wang Y, Fan Y, et al. Chem. Eng. Commun., 2014,16:430-440
17. [17]
  (b) Yang H X, Guo S P, Tao J, et al. Cryst. Growth Des., 2009,9:4735-4744
18. [18]
  (c) Sun J W, Li M T, Sha J Q, et al. Chem. Eng. Commun., 2013,15:10584-10589
19. [19]
  [7] (a) Wang Y, Zhang L C, Zhu Z M, et al. Transition Met. Chem., 2011,36:261-267
20. [20]
  (b) Xu Y L, Zhou B B, Su Z H, et al. J. Coord. Chem., 2011,64:3670-3678
21. [21]
  [8] Tian A X, Yang Y, Ying J, et al. Dalton Trans., 2014,43: 8405-8413
22. [22]
  [9] (a) Wang L, Yang W T, Zhu W, et al. Inorg. Chem., 2014, 53(21):11584-11588
23. [23]
  (b) Zhou K, Qin C, Wang X L, et al. Chem. Eng. Commun., 2014,16:10376-10379
24. [24]
  (c) Li M T, Sha J Q, Zong X M, et al. Cryst. Growth Des., 2014,14(6):2794-2802
25. [25]
  [10] (a) Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution. University of Göttingen, Germany, 1997.
26. [26]
  (b) Sheldrick G M. Acta Crystallogr. Sect. A, 2008,64:112
27. [27]
  [11] Brown I D, Altermatt D. Acta Crystallogr., Sect. B, 1985,41: 244-247
28. [28]
  [12] Jr Evans H T, Popev M T. Inorg. Chem., 1984,23:501-504
29. [29]
  [13] Liu C M, Zhang D Q, Zhu D B. Cryst. Growth Des., 2006,6: 524-529
30. [30]
  [14] (a) Wang X L, Li N, Tian A X, et al. Dalton Trans., 2013, 42:14856-14865
31. [31]
  (b) Zhai Q G, Wu X Y, Chen S M, et al. Inorg. Chem., 2007,46:5046-5058
32. [32]
  (c) Zhang P P, Peng J, Pang H J, et al. Chem. Eng. Commun., 2011,13:3832-3841
33. [33]
  [15] (a) Dobrick M S, Jansen M. Eur. J. Inorg. Chem., 2006,22: 4498-4502
34. [34]
  (b) Liu H Y, Wu H, Yang J, et al. Cryst. Growth Des., 2011,11(5):1786-1797
35. [35]
  [16] Guo H X, Li X Z, Weng W. Inorg. Chem. Commun., 2010,13:909-913
36. [36]
  [17] (a) Li T H, Li Q G, Yan J, et al. Dalton Trans., 2014,43: 9061-9069
37. [37]
  (b) Tian A X, Yang Y, Sun N, et al. J. Coord. Chem., 2014, 67(9):1550-1561
38. [38]
  [18] Wang X, Peng J, Liu M G, et al. Chem. Eng. Commun., 2012,14:3220-3226
1. [1]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
2. [2]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
3. [3]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
4. [4]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
7. [7]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
8. [8]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
9. [9]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
10. [10]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
11. [11]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
12. [12]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
13. [13]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
14. [14]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
15. [15]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
16. [16]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
17. [17]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
18. [18]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
19. [19]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
20. [20]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(369)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142