Citation: Ma Xiuzhen, Hu Bin. Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model[J]. Chemistry, ;2020, 83(5): 459-463. shu

Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model

Ma Xiuzhen ,
Hu Bin ^,

Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences; Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Xining, 810008

Corresponding author: Hu Bin, hubin@isl.ac.cn
Received Date: 5 November 2019
Accepted Date: 25 December 2019

Figures(3)

The densities of NaCl-KCl aqueous mixture were determined at temperatures from 288.15 to 323.15 K and over a range of composition at ionic strength of 0.1~4 mol·kg^-1. A high precision vibrating-tube densitometer was used in the measurement. The excess volumes of the mixed electrolytes calculated from the experimental data permitted a parameterization of the Pitzer model for mixtures with the entire range of temperatures and compositions covered by this study. In addition, using the Pitzer model, we determined the volume of mixing at constant ionic strength and at 298.15 K.
- Density,
- Pitzer ion-interaction Model,
- Salt lake brine,
- Volume of mixing
1. [1]
  Wang S. J. Salt Lake Res., 2000, 8(4): 44~49.
2. [2]
  Pitzer K. J. Phys. Chem., 1973, 77(2), 268~277.
3. [3]
  Pitzer K. Activity coefficients in electrolyte solutions, second edition, CRC, Ann Arbor, 1991.
4. [4]
  Harvie C, Weare J. Geochim. Cosmochim. Acta, 1980, 44(7): 981~997.
5. [5]
  Krumgalz B. J. Mol. Liq., 2001, 91(1/3): 3~19.
6. [6]
  Lassin A, Andre L, Lach A, et al. Calphad, 2018, 61: 126~139.
7. [7]
  Ruby C, Kawa J. J. Am. Chem. Soc., 1926, 48(5): 1119~1128.
8. [8]
  Wirth H. J. Am. Chem. Soc., 1937, 59(12): 2549~2554.
9. [9]
  Campbell A, Kartzmark E. Can. J. Chem., 1956, 34(5): 672~678.
10. [10]
  Fabuss B, Korosi A, Othmer D. J. Chem. Eng. Data, 1969, 14(2): 192~197.
11. [11]
  Kumar A. J. Chem. Eng. Data, 1988, 33(2): 198~199.
12. [12]
  Zezin D, Driesner T, Sanchez-Valle C. J. Chem. Eng. Data, 2014, 59(3): 736~749.
13. [13]
  Ghafri S, Maitland G, Trusler P. J. Chem. Eng. Data, 2012, 57(4): 1288~1304.
14. [14]
  Dedick E, Hershey J, Sotolongo S, et al. J. Solution. Chem., 1990, 19(4): 353~374.
15. [15]
  Hu B, Hnědkovsky L, Li W, et al. J. Chem. Eng. Data, 2016, 61(4): 1388~1394.
16. [16]
  Krumgalz B, Pogorelskii R, Pitzer K. J. Solution Chem., 1995, 24(10): 1025~1038.
17. [17]
  Krumgalz B, Pogorelskii R, Sokolov A, et al. J. Phys. Chem. Ref. Data, 2000, 29(5): 1123~1140.
18. [18]
  Wagner W, Pruss A. J. Phys. Chem. Ref. Data, 2002, 31(2): 387~535.
19. [19]
  Desnoyer J, Arel M, Perron G, et al. J. Phys. Chem., 1969, 73(10): 3346~3351.
20. [20]
  Lovera J, Hernandez-Luiz F, Galleguillos H. J. Chem. Eng. Data, 2008, 53(12): 2902~2906.
1. [1]
  Fei Nie , Xueru Liu , Zhuang Hui , Yan Li , Bin Cui . Curriculum Ideological and Political Design of Comprehensive Experiment of Soda Ash Preparation from Salt Lake Water. University Chemistry, 2024, 39(2): 121-126. doi: 10.3866/PKU.DXHX202308054
2. [2]
  Shu'e Song , Xiaokui Wang , Yongmei Liu , Wanchun Zhu , Hong Yuan , Fuping Tian , Yunshan Bai , Yunchao Li , Li Wang , Zhongyun Wu , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Viscosity, Density and Optical Properties. University Chemistry, 2025, 40(5): 148-156. doi: 10.12461/PKU.DXHX202503026
3. [3]
  Kai Guo , Jiating Li , Shiya Lin , Lu Chen , Neng Yu , Yiju Li . Dual-function additive for simultaneously boosting the stability and energy density of aqueous zinc ion hybrid capacitors. Chinese Chemical Letters, 2026, 37(4): 111175-. doi: 10.1016/j.cclet.2025.111175
4. [4]
  Xiaoling Qiu , Ruijie Chen , Keren Luo , Xiaoran Wang , Tuan Wang , Pengcheng Shi , Wenlong Cai , Hao Wu . A high-tap-density, particle-nested-bulk bismuth anode for fast-charging sodium-ion batteries. Chinese Chemical Letters, 2026, 37(4): 110792-. doi: 10.1016/j.cclet.2024.110792
5. [5]
  Qiang-Qiang Jia , Jia-Qi Luo , Zhi-Yu Xue , Jing-Song Tang , Wen-Qiang Qiu , Chang-Feng Wang , Zhi-Xu Zhang , Hai-Feng Lu , Yi Zhang , Da-Wei Fu . Enhanced output power density of PVDF/LM composite for piezoelectric sensor. Chinese Chemical Letters, 2025, 36(11): 110471-. doi: 10.1016/j.cclet.2024.110471
6. [6]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
7. [7]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
8. [8]
  Yunfei Shen , Long Chen . Gradient imprinted Zn metal anodes assist dendrites-free at high current density/capacity. Chinese Journal of Structural Chemistry, 2024, 43(10): 100321-100321. doi: 10.1016/j.cjsc.2024.100321
9. [9]
  Zhilong Xie , Guohui Zhang , Ya Meng , Yefei Tong , Jian Deng , Honghui Li , Qingqing Ma , Shisong Han , Wenjun Ni . A natural nano-platform: Advances in drug delivery system with recombinant high-density lipoprotein. Chinese Chemical Letters, 2024, 35(11): 109584-. doi: 10.1016/j.cclet.2024.109584
10. [10]
  Qingyun Hu , Wei Wang , Junyuan Lu , He Zhu , Qi Liu , Yang Ren , Hong Wang , Jian Hui . High-throughput screening of high energy density LiMn_1-xFe_xPO₄ via active learning. Chinese Chemical Letters, 2025, 36(2): 110344-. doi: 10.1016/j.cclet.2024.110344
11. [11]
  Longsheng Zhan , Yuchao Wang , Mengjie Liu , Xin Zhao , Danni Deng , Xinran Zheng , Jiabi Jiang , Xiang Xiong , Yongpeng Lei . BiVO₄ as a precatalyst for CO₂ electroreduction to formate at large current density. Chinese Chemical Letters, 2025, 36(3): 109695-. doi: 10.1016/j.cclet.2024.109695
12. [12]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
13. [13]
  Zhili Yang , Liqun Liu , Xuebi Rao , Zeyu Jin , Jialin Sun , Yongkang Zhu , Shiming Zhang . Deprotonation effect doubles active site density in Fe-N₄-C catalyst for oxygen reduction electrocatalysis. Chinese Chemical Letters, 2025, 36(11): 111440-. doi: 10.1016/j.cclet.2025.111440
14. [14]
  Dixing Ni , Jiarui Qi , Zhi Deng , Dong Ding , Rui Wang , Wenjie Zhou , Sisi Zhou , Yang Sun , Shuai Li , Zhaoxiang Wang . Voltage design and transport channel optimization of anti-perovskite cathode materials: A density functional theory study. Chinese Chemical Letters, 2025, 36(12): 110683-. doi: 10.1016/j.cclet.2024.110683
15. [15]
  Guanjun Chen , Jiayi Yang , Zheming Huang , Long Chen , Wenyuan Duan , Tong Wang , Xingang Kong , Haibo Yang . Engineering the interlayer sodium density in layered sodium cobalt oxide for boosted chlorine evolution reaction. Chinese Chemical Letters, 2025, 36(12): 111662-. doi: 10.1016/j.cclet.2025.111662
16. [16]
  Xindi Yang , Cunli Wang , Dongdong Wang , Haijuan Qin , Kuoxi Xu , Guangyan Qing . High efficiency detection of Zn²⁺ through the improved electron density of aromatic π-conjugated bridges. Chinese Chemical Letters, 2026, 37(4): 111215-. doi: 10.1016/j.cclet.2025.111215
17. [17]
  Zhihao Li , Zhiruo Zhou , Yuan Qin , Dan Huang , Meizhen Wang . Density functional theory assists in promoting advanced oxidation processes: Toward efficient antibiotic degradation in waters. Chinese Chemical Letters, 2026, 37(6): 112318-. doi: 10.1016/j.cclet.2025.112318
18. [18]
  Long-Qi Yang , Xiao-Ming Jiang , Fa-Kun Zheng , Guo-Cong Guo . Unconventional configuration of excimer in luminescent aggregates uncovered by in situ photo-difference electron density. Chinese Journal of Structural Chemistry, 2026, 45(4): 100846-100846. doi: 10.1016/j.cjsc.2025.100846
19. [19]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
20. [20]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1254)
HTML views(100)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Volumetric Properties of NaCl-KCl-H2O System and Their Correlation with Pitzer Model

Metrics

通讯作者: 陈斌, bchen63@163.com

Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model