Citation: WANG Dong-zhe, FENG Xu, ZHANG Jian, CHEN Lin, ZHANG Lei, WANG Hong-hao, BAI Jin, ZHANG Cai-shun, ZHANG Zheng-yi. Effect of promoter M(M=Cr, Zn, Y, La) on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(10): 1251-1257. shu

Effect of promoter M(M=Cr, Zn, Y, La) on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol

1.
College of Chemistry, Chemical Engineering, and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Department of Chemistry and Materials Engineering, Yingkou Institute of Technology, Yingkou 115014, China
3.
Plastic Factory of Petro China Daqing Petrochemical Company, Daqing 163000, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com
Received Date: 17 June 2019
Revised Date: 3 September 2019

Fund Project: Scientific Research Funds Project of Liaoning Education Department L20190338The project was supported by the National Natural Science Foundation of China (21376237), Scientific Research Funds Project of Liaoning Education Department (L20190338) and Natural Science Fund in Liaoning Province (2019-MS-221)Natural Science Fund in Liaoning Province 2019-MS-221the National Natural Science Foundation of China 21376237

Figures(8)

M/CuO/CeO₂ (M=Cr, Zn, Y, La) catalyst was prepared by sequential impregnation method. The catalysts were characterized by XRF, XRD, BET, H₂-TPR and XPS. The effects of different promoters on the structure and properties of CuO/CeO₂ catalysts were investigated.The results show that the doping of promoters mainly affects the dispersion of CuO, the reduction properties of the catalyst, the interaction between CuO and CeO₂, and the oxygen hole content on the surface of the catalyst. After doping additives Cr and Zn, improving the dispersion of CuO on catalysts, and the interaction between CuO and CeO₂ strengthens, the surface oxygen holes increase, which in turn increases the catalytic activity. After doping the additives Y and La, decreasing the dispersion of CuO on catalysts, the interaction between CuO and CeO₂ is weakened, and the surface oxygen holes are reduced, thus the catalytic activity is reduced. Among them, the catalyst doped with promoter Cr has better catalytic activity. When the reaction conditions are 260℃, n(CH₃OH):n(H₂O)=1:1.2 and the space velocity of methanol vapor gas is 1760 h^-1, the final conversion can reach 100%, the CO content in reforming tail gas is 0.15%. Compared with CuO/CeO₂ catalyst, the conversion rate is increased by 10%, and the CO content in reforming tail gas is reduced by 0.34%.
- auxiliaries,
- methanol steam reforming,
- hydrogen,
- carbon monoxide
1. [1]
  HOU H J M. Hydrogen energy production using manganese/semiconductor system inspired by photosynthesisInt[J]. J Hydrogen Energy, 2017,42(12):8530-8538. doi: 10.1016/j.ijhydene.2017.01.100
2. [2]
  WEI Z, KE Y, PEI P, YU W, CHU X Y, LI S L, YANG K. Hydrogen production from cylindrical methanol steam reforming microreactor with porous Cu-Al fiber sintered felt[J]. Int J Hydrogen Energy, 2018,43(7):3643-3654. doi: 10.1016/j.ijhydene.2017.12.118
3. [3]
  XI H, HOU X, LIU Y, QING S J, GAO Z X. Cu-Al spinel oxide as an efficient catalyst for methanol steam reforming[J]. Angew Chem, 2015,53(44):11886-11889.
4. [4]
  HAO C, ANDOLINA C M, LI J, CURNAN M T, SAIDI W A, ZHOU G W, YANG J C, VESER G. Dependence of H₂ and CO₂ selectivity on Cu oxidation state during partial oxidation of methanol on Cu/ZnO[J]. Appl Catal A: Gen, 2018,556:64-72. doi: 10.1016/j.apcata.2018.02.028
5. [5]
  JAMPA S, JAMIESON A M, CHAISUWAN T, LUENGNARUEMITCHAI A, WONGKASEMJIT S. Achievement of hydrogen production from autothermal steam reforming of methanol over Cu-loaded mesoporous CeO₂ and Cu-loaded mesoporous CeO₂-ZrO₂ catalysts[J]. Int J Hydrogen Energy, 2017,42(22):15073-15084. doi: 10.1016/j.ijhydene.2017.05.022
6. [6]
  LIU Y, HAYAKAWA T, TSUNODA T, SUZUKI K, HAMAKAWA S, MURATA K, SHIOZAKI R, ISHⅡ T, KUMAGAI M. Steam reforming of methanol over Cu/CeO₂ catalysts studied in comparison with Cu/ZnO and Cu/Zn(Al)O catalysts[J]. Top Catal, 2003,22(3/4):205-213. doi: 10.1023/A:1023519802373
7. [7]
  LI Y F, DONG X F, LIN W M. Effects of ZrO₂-promoter on catalytic performance of CuZnAlO catalysts for production of hydrogen by steam reforming of methanol[J]. Int J Hydrogen Energy, 2004,29(15):1617-1621. doi: 10.1016/j.ijhydene.2004.03.001
8. [8]
  PAPAVASILIOU J, AVGOUROPOULOS G, IOANNIDES T. Effect of dopants on the performance of CuO-CeO₂ catalysts in methanol steam reforming[J]. Appl Catal B: Environ, 2007,69(3/4):226-234.
9. [9]
  ZAHEDI T O, MAJID T, DEHGHANI K A. Methanol steam reforming in a microchannel reactor by Zn-, Ce- and Zr- modified mesoporous Cu/SBA-15 nanocatalyst[J]. Int J Hydrogen Energy, 2018,43(31):14103-14120. doi: 10.1016/j.ijhydene.2018.06.035
10. [10]
  YANG S Q, ZHOU F, LIU Y J, ZHANG L, YU C, WANG H H, TIAN Y, ZHANG C S, LIU D S. Morphology effect of ceria on the performance of CuO/CeO₂ catalysts for hydrogen production by methanol steam reforming[J]. Int J Hydrogen Energy, 2019,44(14):7252-7261. doi: 10.1016/j.ijhydene.2019.01.254
11. [11]
  LIU Yu-juan, WANG Dong-zhe, ZHANG Lei, WANG Hong-hao, CHEN Lin, LIU Dao-sheng, HAN Jiao, ZHANG Cai-shun. Effect of support calcination atmospheres on the activity of CuO/CeO₂ catalysts for methanol steam reforming[J]. J Fuel Chem Technol, 2018,46(8):992-999. doi: 10.3969/j.issn.0253-2409.2018.08.011
12. [12]
  YANG Shu-qian, HE Jian-ping, ZHANG Na, SUI Xiao-wei, ZHANG Lei, YANG Zhan-xu. Effect of rare-earth element modification on the performance of Cu/ZnAl catalysts derived from hydrotalcite precursor in methanol steam reforming[J]. J Fuel Chem Technol, 2018,46(2):179-188. doi: 10.3969/j.issn.0253-2409.2018.02.007
13. [13]
  YANG Shu-qian, ZHANG Na, HE Jian-ping, ZHANG Lei, WANG Hong-hao, BAI Jin, ZHANG Jian, LIU Dao-sheng, YANG Zhan-xu. Effect of impregnation sequence of Ce on the performance of Cu/ Zn-Al catalysts derived from hydrotalcite precursor in methanol steam reforming[J]. J Fuel Chem Technol, 2018,46(4):479-488. doi: 10.3969/j.issn.0253-2409.2018.04.014
14. [14]
  HE J P, YANG Z X, ZHANG L, LI Y, PAN L W. Cu supported on ZnAl-LDHs precursor prepared by in-situ synthesis method on γ-Al₂O₃ as catalytic material with high catalytic activity for methanol steam reforming[J]. Int J Hydrogen Energy, 2017,42(15):9930-9937. doi: 10.1016/j.ijhydene.2017.01.229
15. [15]
  DAI B, ZHOU G, GE S, XIE H M, JIAO Z J, ZHANG G Z, XIONG K. CO₂ reverse water-gas shift reaction on mesoporous M-CeO₂ catalysts[J]. Can J Chem Eng, 2017,95(4):634-642. doi: 10.1002/cjce.22730
16. [16]
  HE Jian-ping, ZHANG Lei, CHEN Lin, YANG Zhan-xu, TONG Yu-fei. Effect of CeO₂ on Cu/Zn-Al catalysts derived from hydrotalcite precursor for methanol steam reforming[J]. Chem J Chin Univ, 2017,38:1822-1828. doi: 10.7503/cjcu20170158
17. [17]
  ZHANG L, PAN L W, NI C J, SUN T J, ZHAO S S, WANG S D, WANG A J, HU Y K. CeO₂-ZrO₂-promoted CuO/ZnO catalyst for methanol steam reforming[J]. Int J Hydrogen Energy, 2013,38(11):4397-4406. doi: 10.1016/j.ijhydene.2013.01.053
18. [18]
  SHE W, QI T, CUI M, YAN P, NG S. W, LI W, LI G. Catalytic performance of CeO₂-supported Ni catalyst for hydrogenation of nitroarenes fabricated via coordination-assisted strategy[J]. ACS Appl Mater Inter, 2018,10(17):14698-14707. doi: 10.1021/acsami.8b01187
19. [19]
  ZHANG Y, ZHOU Y, PENG C, SHI J, WANG Q, HE L, SHI L. Enhanced activity and stability of copper oxide/γ-alumina catalyst in catalytic wet-air oxidation: Critical roles of cerium incorporation[J]. Appl Surf Sci, 2018,436:981-988. doi: 10.1016/j.apsusc.2017.12.036
20. [20]
  PENG X, OMASTA T J, ROLLER J M, MUSTAIN W E. Highly active and durable Pd-Cu catalysts for oxygen reduction in alkaline exchange membrane fuel cells[J]. Frontiers Energy, 2017,11(3):299-309. doi: 10.1007/s11708-017-0495-1
21. [21]
  BENNICI S, GERVASINI A, RAVASIO N, ZACCHERIA F. Optimization of tailoring of CuO_x species of silica alumina supported catalysts for the selective catalytic reduction of NO_x[J]. J Phys Chem B, 2003,107(22):5168-5176. doi: 10.1021/jp022064x
22. [22]
  FANG Z, REHMAN S U, SUN M, YUAN Y P, JIN S W, HONG B. Hybrid NiO-CuO mesoporous nanowire array with abundant oxygen vacancies and a hollow structure as a high-performance asymmetric supercapacitor[J]. J Mater Chem A, 2018,6:21131-21142. doi: 10.1039/C8TA08262F
23. [23]
  AFONASENKO T N, TSYRULNIKOV P G, GULYAEVA T I, LEONTEVA N N, SMIRNOVA N S, KOCHUBEI D I, SUPRUN E A, SALANOV A N. (CuO-CeO₂)/glass cloth catalysts for selective CO oxidation in the presence of H₂: The effect of the nature of the fuel component used in their surface self-propagating high-temperature synthesis on their properties[J]. Kinet Catal, 2013,54(1):59-68. doi: 10.1134/S0023158412060018
24. [24]
  KULKARNI G U, RAO C N R. EXAFS and XPS investigations of Cu/ZnO catalysts and their interaction with CO and methanol[J]. Top Catal, 2003,22(3):183-189.
25. [25]
  ESPINOS J P, MORALES J, BARRANCO A, CABALLERO A, HOLGADO J P, GONZALES-ELIPE A R. Interface effects for Cu, CuO, and Cu₂O deposited on SiO₂ and ZrO₂. XPS determination of the valence state of copper in Cu/SiO₂ and Cu/ZrO₂ catalysts[J]. J Phys Chem B, 2002,106(27):6921-6929. doi: 10.1021/jp014618m
26. [26]
  NATILE M M, GALENDA A, GLISENTI A. CuO/CeO₂ nanocomposites: An XPS study[J]. Surf Sci Spectra, 2009,16(1):13-26. doi: 10.1116/11.20061005
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of promoter M(M=Cr, Zn, Y, La) on CuO/CeO2 catalysts for hydrogen production from steam reforming of methanol

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通讯作者: 陈斌, bchen63@163.com

Effect of promoter M(M=Cr, Zn, Y, La) on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol