Citation: Bao Hai SHAO, Xiu Zhu XU, Jian De LU, Li ZOU, Xiao Yun FU. Influence of Mobile Phase Composition on the Enantioseparation of Methoxyl Flavanones with Self-prepared CDMPC Column and Chiral Recognition Mechanism[J]. Chinese Chemical Letters, ;2003, 14(4): 401-403. shu

Influence of Mobile Phase Composition on the Enantioseparation of Methoxyl Flavanones with Self-prepared CDMPC Column and Chiral Recognition Mechanism

Department of Chemistry, Zhejiang University, Hangzhou 310027

Received Date: 20 May 2002

The influence of different alcohol modifiers in mobile phase on the chiral separation of 4'-methoxyl flavanone, 5-methoxyl flavanone and 6-methoxyl flavanone on cellulose tris (3, 5-dimethylphenylcarbamate) (CDMPC) column was studied and the chiral recognition mechanism was discussed. Using hexane-tert-butanol (1.31 mol L^-1) as the mobile phase, those three methoxyl flavanones were excellently separated on CDMPC chiral column.
- Cellulose tris (3,5-dimethylphenylcarbamate),
- methoxyl flavanone,
- chiral stationary phase,
- enantioseparation
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