Citation: CHEN Chuanfu, SUN Yifei, SU Quan, LIU Weihong, CHEN Yongming, XI Fu. POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST[J]. Chinese Journal of Polymer Science, ;1998, 16(2): 126-132. shu

POLYMERIZATION MECHANISM OF N-VINYLCARBAZOLE WITH CHIRALLY ORGANIC SALT AS CATALYST

Received Date: 2 November 1996

The polymerization mechanism is described by the conductance changewith the time during the polymerization. The mechanism can be explained by the equi-librium feature (i.e. main ion-pairs) between the free ions and the ion-pairs dissociated bythe organic salt (-) Sp*+ (+) CSA*- (An asterisk represents the chirality) and the schemeof the polymerization process is described mainly by the charge transfer complexes havingchiral induction power.
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