Citation: Zao Ying LI, Cong LI, Xu Ye WU, Yue Ning ZHANG. Synthesis of β-Cyclodextrin Bonded Metal Porphyrins[J]. Chinese Chemical Letters, ;2000, 11(6): 493-494. shu

Synthesis of β-Cyclodextrin Bonded Metal Porphyrins

Department of Chemistry, Wuhan University, Wuhan 430072

Received Date: 20 January 2000

Fund Project: This work was supported by the National Natural Science Foundation of China (projects No.29972035) and Natural Science Foundation of Hubei Province (projects No.98J043).

6-Deoxy-6-iodo-β-cyclodextrin (1) reacted with 5-(p-aminophenyl)-10,15,20-triphenyl porphyrin(2), 5-(p-aminophenyl)-10,15,20-triphenyl nickel(Ⅱ) porphyrin[Ni^ⅡTPP_NH2P] (3), 5-(p-aminophenyl)-10,15,20-triphenyl manganese(Ⅲ) porphyrin[Mn^ⅢTPP_NH2P] (4) and 5-(p-aminophenyl)-10,15,20-triphenyl carbonyl ruthenium porphyrin[Ru^Ⅱ(CO)TPP_NH2P] (5) to generate the compounds 6-9, respectively. Those new compound 5-9 have been identified by ¹H NMR, IR, MS and UV-visible spectra and elemental analysis.
- β-Cyclodextrin,
- metal porphyrins,
- synthesis
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