Citation: Xi You LI, Guo Xiang XIONG, Hui Jun XU. The Synthesis and Film Forming Properties of Unsymmetrical Phthalocyanine Bearing One Crown Ether Void[J]. Chinese Chemical Letters, ;1997, 8(9): 815-818. shu

The Synthesis and Film Forming Properties of Unsymmetrical Phthalocyanine Bearing One Crown Ether Void

The Institute of Photographic Chemistry, Chinese Academy of Sciences, Beijing 100101

Received Date: 28 April 1997

Fund Project: We thank the National Natural Science Foundation of China for the financial support.

The synthesis of phthalocyanines bearing one crown ether macrocycle and three alkoxyl chains is described.They form stable monolayers and can be employed for the preparation of multilayer films by the Langmuir-Blogett technique.The orientations of the molecules in the film were affected by alkali metal ions in the subphase.It is suggested that a kind of "sandwich" dimer was formed in the film induced by potassium ions.
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