Citation: Sheng Lou DENG, Ru Yu CHEN, Dong Zhi LIU. Investigation of Isomerization of 2-Seleno-l, 3,2-diazaphospholidine Derivatives[J]. Chinese Chemical Letters, ;2002, 13(5): 398-401. shu

Investigation of Isomerization of 2-Seleno-l, 3,2-diazaphospholidine Derivatives

1.
School of Chemical Engineering, Tianjin University, Tianjin 300072;
2.
Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 17 August 2001

For the first time the isomerization of 1, 3, 2-diazaphospholidine-2-selenide derivatives in refluxing benzene in the presence of trace water was observed. The structures of isomerized products were determined by IR, ¹H NMR, ³¹P NMR, elemental analysis and X-ray crystallography. The mechanism of isomerization was also proposed.
- Isomerization,
- 2-sclcno-l,3,2-diazaphospholidinc derivatives,
- crystal struciurc,
- mcchanism
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