Citation: Hong Qi LI, Zhong Qi YAO. STUDIES ON SYNTHESIS AND PROPERTIES OF NEW TETRATHIFULVALENE DERIVATIVES[J]. Chinese Chemical Letters, ;1996, 7(7): 597-599. shu

STUDIES ON SYNTHESIS AND PROPERTIES OF NEW TETRATHIFULVALENE DERIVATIVES

Hong Qi LI ,
Zhong Qi YAO

Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received Date: 8 September 1995

Synthesis of three new tetrathiafulvalene (TTF) derivatives-tetrakis (p-halobenzylthio)-tetrathiafulvalene and their precursors 4, 5-bis (p-halobenzylthio)-1, 3-dithiole-2-thione is reported. The electronic absorption spectra of these TTF derivatives show that the energy differences between their π-orbitals are smaller than that between BEDT-TTF. The surface pressure-area isotherm for tetrakis (p-chlorobenzylthio) tetrathiafulvalene (TCBT-TTF) indicates that the new TTF derivatives may have good film-forming properties and may be used to prepare Langmuir-Blodgett films.
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