Citation: Jian XU, Zheng Yu ZHOU, Yan He GUO. Inner-Sphere Reorganization Eneregy For Metal Ion-Benzene Complex in Electron-Transfer Process[J]. Chinese Chemical Letters, ;1997, 8(8): 729-732. shu

Inner-Sphere Reorganization Eneregy For Metal Ion-Benzene Complex in Electron-Transfer Process

Department of Chemistry, Qufu Normal University, Qufu, Shandong, 273165

Received Date: 9 September 1997

Based on the capture force field potential model and the adiabatic invariant proposed by Bates,adopting improved average dipole orientation (IADO) theory,the force constants between transition metal ions and benzene (bz) and also a series of inner-sphere reoganization energy (RE_in) were calculated.The reasons for the differences between theoretical predictions and experimental results were discussed.
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